• Title/Summary/Keyword: Chemical Risk

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Development of the Cost-Benefit Analysis System for the Investment of Safety Facilities in Chemical Plant (화학공장의 안전 설비 투자를 위한 비용$\cdot$편익 분석 시스템 개발)

  • Ko J. W.;Seo J. M.;Kim D. H.
    • Journal of the Korean Institute of Gas
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    • v.7 no.4 s.21
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    • pp.61-66
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    • 2003
  • The objective of this study is to develop a Cost-Benefit analysis system which would help us to make optimal decision among safety investment alternatives, calculating and comparing costs and benefits for facilities in chemical plants. So, the accident frequency analysis module and the accident damage prediction module were developed for estimating quantitative risks in chemical facilities, and domestic societal risk criterion was presented after the comparative analysis of major industrial cases and societal risk criteria of advanced countries like the Netherlands, Australia, U.S.A., U.K., and Germany. Also, the Cost-Benefit Analysis System which compares the safety investment alternatives based on their deduced net present values was developed through the selection of proper cost and benefit items by field studies

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Process Risk Assessment for a Batch Condensation Reaction of Polyester Resin using K-PSR Technique (K-PSR 기법을 활용한 회분식 폴리에스터 축합반응에서의 공정 위험성 평가 연구)

  • Park, Kyung-Min;Lee, Dong-Kyu;Lee, Haakil;Lee, Joon-Man;Ahn, Won-Sool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.35-42
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    • 2019
  • Risk assessment and analysis for a medium-to-small sized chemical plant that manufactures a polyester resin by the process of batch-type condensation reaction was conducted using K-PSR technique which is one of the risk assessment methods used to implement the Process Safety Management System (PSM). K-PSR is a risk assessment technique developed by KOSHA to compensate for difficulties caused by the lack of infrastructure of medium-to-small sized chemical plants in the re-evaluation. To apply the K-PSR technique, the entire process of a selected chemical palnt was classified in two review sections, i.e., the condensation reaction process and the dilution/filtration process, and the potential risks of the process about these review sections were identified and classified based on the four guide-words (release, fire.explosion, process trouble, and injury). As the results of the research, refer to recommend of risk rating has been confirmed that non-destructive testing of old facilities and the preparation of LOTO procedures for the electrical equipments are necessary as specific measures to prevent the risk of release and fire.explosion. It was also shown that pressure gauges and thermometers should be installed on the hot-oil supply piping to minimize the process trouble, and exhausting hood should be installed to prevent potential injury.

Development of Fire and Explosion Index Estimation Program for Risk Assessment in Chemical Processes (화학공정의 위험성 평가를 위한 화재 폭발 지수 산정 프로그램의 개발)

  • 김기수;백종배;고재욱;노삼규
    • Journal of the Korean Society of Safety
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    • v.8 no.2
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    • pp.58-63
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    • 1993
  • Recently, a large amount of flammable or explosive materials have been handled or stored in chemical industries. H the equipments fail or the materials release in consequence of operation errors, fire and explosion could occur to them. Thus, risk assessment using quantification of risks is very important when design of processes and modifications of installed processes are performed. The purpose of this study is to develop the program for fire and explosion index in order to quantify the expected damage of fire and explosion incidents in chemical plants, to identify equipment that would be likely to contribute to the creation or escalation of an incident, to comunicate the potential fire and explosion risk to management and to account of damage cost.

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Ecotoxicity Test of Wastewater by a Battery of Bioassay and Toxicity Identification Evaluation (다양한 시험생물종을 이용한 산업폐수 생태독성 평가 및 원인물질 탐색)

  • Ryu, Tae-Kwon;Cho, Jae-Gu;Kim, Kyung-Tae;Yang, Chang-Yong;Joung, Ki-Eun;Yoon, Jun-Heon;Choi, Kyung-Hee
    • Environmental Analysis Health and Toxicology
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    • v.25 no.3
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    • pp.207-214
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    • 2010
  • Toxicity identification and quantification are important factors to evaluate the effect of industrial effluent on the aquatic environment. In order to measure the potential and real toxicity of mixed chemicals in the effluents, the biological method (i.e., WET test) should be used as well as chemical analysis method. In this study, we conducted WET test for various kinds of industrial effluents using aquatic organisms such as water flea (Daphnia magna), algae (Pseudokirchneriella subcapitata), fish (Oryzias latipes, Danio rerio), and microorganism (Vibrio fisheri). In addition, we carried out chemical analysis and TIE (Toxicity Identification Evaluation) for effluents in order to identify the substances causing toxicity. Among the 30 kinds of wastewater, S13 showed the highest eco-toxicity and $Ca^{2+}$ and $Cl^-$ ion were suspected as major compounds causing toxicity for aquatic organisms. In order to confirm these suspected compounds, various confirmation procedures need to be carried out.

Adverse Outcome Pathways for Prediction of Chemical Toxicity at Work: Their Applications and Prospects (작업장 화학물질 독성예측을 위한 독성발현경로의 응용과 전망)

  • Rim, Kyung-Taek;Choi, Heung-Koo;Lee, In-Seop
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.29 no.2
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    • pp.141-158
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    • 2019
  • Objectives: An adverse outcome pathway is a biological pathway that disturbs homeostasis and causes toxicity. It is a conceptual framework for organizing existing biological knowledge and consists of the molecular initiating event, key event, and adverse output. The AOP concept provides intuitive risk identification that can be helpful in evaluating the carcinogenicity of chemicals and in the prevention of cancer through the assessment of chemical carcinogenicity predictions. Methods: We reviewed various papers and books related to the application of AOPs for the prevention of occupational cancer. We mainly used the internet to search for the necessary research data and information, such as via Google scholar(http://scholar.google.com), ScienceDirect(www.sciencedirect.com), Scopus(www.scopus. com), NDSL(http: //www.ndsl.kr/index.do) and PubMed(http://www.ncbi.nlm.nih.gov/pubmed). The key terms searched were "adverse outcome pathway," "toxicology," "risk assessment," "human exposure," "worker," "nanoparticle," "applications," and "occupational safety and health," among others. Results: Since it focused on the current state of AOP for the prediction of toxicity from chemical exposure at work and prospects for industrial health in the context of the AOP concept, respiratory and nanomaterial hazard assessments. AOP provides an intuitive understanding of the toxicity of chemicals as a conceptual means, and it works toward accurately predicting chemical toxicity. The AOP technique has emerged as a future-oriented alternative to the existing paradigm of chemical hazard and risk assessment. AOP can be applied to the assessment of chemical carcinogenicity along with efforts to understand the effects of chronic toxic chemicals in workplaces. Based on these predictive tools, it could be possible to bring about a breakthrough in the prevention of occupational and environmental cancer. Conclusions: The AOP tool has emerged as a future-oriented alternative to the existing paradigm of chemical hazard and risk assessment and has been widely used in the field of chemical risk assessment and the evaluation of carcinogenicity at work. It will be a useful tool for prediction, and it is possible that it can help bring about a breakthrough in the prevention of occupational and environmental cancer.

Risk Analysis of Ammonia Leak in the Refrigeration Manufacturing Facilities (냉동제조 시설의 암모니아 누출사고 위험 분석)

  • Kang, Su-Jin;Lee, Ik-Mo;Moon, Jin-Young;Chon, Young-Woo
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.43-51
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    • 2017
  • Recently, ammonia leak occurred frequently in the domestic refrigeration manufacturing facilities. Ammonia caused great damage to the environment and human health in the event of an accident as combustible gases and toxic gases. After considering the types of ammonia accidents of domestic refrigeration manufacturing facilities and selected accident scenarios and to analyze the risk analysis through Impact range estimates and frequency analysis and there was a need to establish measures to minimize accident damage. In this study, depending on the method of analysis quantitative risk assessment we analyzed the risk of the receiver tank of ammonia system. Scenario analysis conditions were set according to the 'Technical guidelines for the selection of accident scenario' under the chemicals control act and 'Guidelines for chemical process quantitative risk analysis' of center for chemical process safety. The risk estimates were utilized for consequence analysis and frequency analysis by SAFETI program of DNV, event tree analysis methodology and part count methodology. The individual risk of ammonia system was derived as 7.71E-04 / yr, social risk were derived as 1.17E-03 / yr. The derived risk was confirmed to apply as low as reasonably practicable of the national fire protection association and through risk calculation, it can be used as a way to minimize accidents ammonia leakage accident damage.

Review of Qualitative Approaches for the Construction Industry: Designing a Risk Management Toolbox

  • Zalk, David M.;Spee, Ton;Gillen, Matt;Lentz, Thomas J.;Garrod, Andrew;Evans, Paul;Swuste, Paul
    • Safety and Health at Work
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    • v.2 no.2
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    • pp.105-121
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    • 2011
  • Objectives: This paper presents the framework and protocol design for a construction industry risk management toolbox. The construction industry needs a comprehensive, systematic approach to assess and control occupational risks. These risks span several professional health and safety disciplines, emphasized by multiple international occupational research agenda projects including: falls, electrocution, noise, silica, welding fumes, and musculoskeletal disorders. Yet, the International Social Security Association says, "whereas progress has been made in safety and health, the construction industry is still a high risk sector." Methods: Small- and medium-sized enterprises (SMEs) employ about 80% of the world's construction workers. In recent years a strategy for qualitative occupational risk management, known as Control Banding (CB) has gained international attention as a simplified approach for reducing work-related risks. CB groups hazards into stratified risk 'bands', identifying commensurate controls to reduce the level of risk and promote worker health and safety. We review these qualitative solutions-based approaches and identify strengths and weaknesses toward designing a simplified CB 'toolbox' approach for use by SMEs in construction trades. Results: This toolbox design proposal includes international input on multidisciplinary approaches for performing a qualitative risk assessment determining a risk 'band' for a given project. Risk bands are used to identify the appropriate level of training to oversee construction work, leading to commensurate and appropriate control methods to perform the work safely. Conclusion: The Construction Toolbox presents a review-generated format to harness multiple solutions-based national programs and publications for controlling construction-related risks with simplified approaches across the occupational safety, health and hygiene professions.

Assessment of Semi-Quantitative Health Risks of Exposure to Harmful Chemical Agents in the Context of Carcinogenesis in the Latex Glove Manufacturing Industry

  • Yari, Saeed;Asadi, Ayda Fallah;Varmazyar, Sakineh
    • Asian Pacific Journal of Cancer Prevention
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    • v.17 no.sup3
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    • pp.205-211
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    • 2016
  • Excessive exposure to chemicals in the workplace can cause poisoning and various diseases. Thus, for the protection of labor, it is necessary to examine the exposure of people to chemicals and risks from these materials. The purpose of this study is to evaluate semi-quantitative health risks of exposure to harmful chemical agents in the context of carcinogenesis in a latex glove manufacturing industry. In this cross-sectional study, semi-quantitative risk assessment methods provided by the Department of Occupational Health of Singapore were used and index of LD50, carcinogenesis (ACGIH and IARC) and corrosion capacity were applied to calculate the hazard rate and the biggest index was placed as the basis of risk. To calculate the exposure rate, two exposure index methods and the actual level of exposure were employed. After identifying risks, group H (high) and E (very high) classified as high-risk were considered. Of the total of 271 only 39 (15%) were at a high risk level and 3% were very high (E). These risks only was relevant to 7 materials with only sulfuric acid placed in group E and 6 other materials in group H, including nitric acid (48.3%), chromic acid (6.9%), hydrochloric acid (10.3%), ammonia (3.4%), potassium hydroxide (20.7%) and chlorine (10.3%). Overall, the average hazard rate level was estimated to be 4 and average exposure rate to be 3.5. Health risks identified in this study showed that the manufacturing industry for latex gloves has a high level of risk because of carcinogens, acids and strong alkalisand dangerous drugs. Also according to the average level of risk impact, it is better that the safety design strategy for latex gloves production industry be placed on the agenda.

The Different Growth Rate by Predation Risk in Larval Salamander, Hynobius leechii (한국산 도롱뇽의 포식압 유, 무에 따른 성장률의 변화)

  • Hwang, Ji-Hee;Chung, Hoon
    • Korean Journal of Environment and Ecology
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    • v.25 no.5
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    • pp.666-672
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    • 2011
  • This study examined the different growth rate of larval salamander Hynobius leechii by the predation risk. We collected salamander's eggs from Mountain Inwang. Eggs were treated by two different conditions: (1) cue - which had a predation risk three times a day; (2) no cue - which had no predation risk. Predation risk was conducted by using chemical cue from Chinese minnows. The chemical cue treatment started from the next day after the collection and ended one week after the hatching. Between the first week and the second week after the hatching we fed salamander larvae with tubifex ad. libitium. After the treatment phase, we measured snout - vent length of the each larva on the first week and the second week after the hatching. The results showed that there was a significant difference in the growth rate by the predation risk. From these results we found that predation risk can cause the different growth rate to the larval salamander and these changes could be affect their mortality.

A Study on Fire Protection of Chemical Plants Using FRA (Fire Risk Assessment) Method (FRA(Fire Risk Assessment)기법을 이용한 화학공장의 Fire Protection에 관한 연구)

  • Han, Seung-Hoon;Yoo, Byung-Tae;Tae, Chan-Ho;Chae, Chung Keun;Ko, Jae Wook
    • Journal of the Korean Institute of Gas
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    • v.20 no.5
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    • pp.17-26
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    • 2016
  • Chemical plants and oil gas refinery facilities are intrinsically vulnerable to industrial hazards, such as explosion or fire. Especially, the fire is extremely dangerous to facility structures and plant personnel because of direct flame, radiant heat and smoke. In addition, it has the ripple effect of destroying infra-structures and polluting the environment. In an effort to tackle these potential industrial risks, the procedure of FRA techniques in chemical plants were investigated. The main focus was put on the time variation of physical properties of the main building, i.e. control rooms, warehouses and electrical substations, from a direct flame contact and radiant heat. The deformation of a building due to fire was monitored and modeled with respect to time variable. A variety of case studies, domestic and abroad, was tested in the model to verify the FRA procedure. The developed model was proven to be highly effective to reduce the possible risks at chemical plants. An accurate accident frequency prediction and damage quantification was made by the developed model.