• Title/Summary/Keyword: Chemical Ratio

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Genesis and Mineralogical Characteristics of Acid Sulfate Soil in Gimhae Plain -II. Genesis and Distribution of the Soil Clay Minerals (김해평야(金海平野)에 분포(分布)한 특이산성토(特異酸性土)의 생성(生成)과 광물학적(鑛物學的) 특성(特性) -II. 점토광물(粘土鑛物)의 분포(分布) 및 생성(生成))

  • Jung, Pil-Kyun;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.3
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    • pp.168-178
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    • 1994
  • Acid sulfate soils occur extensively in Gimhae area where they have been formed from the brackish alluvial sediments along the sea coast and river estuary. The strong acid environment enhances silicate weathering and thus affects the soil clay minerals. The minerals were identified through chemical, X-ray diffraction and thermal methods. The ratio of $SiO_2$ and $Al_2O_3$ in the clay fractions ranged from 3.14 to 3.77, indicating that the distribution of the clay minerals were 1 : 1 and 2 : 1 minerals. Cation exchange capacity in the clay fractions was low due to high contents of 1 : 1 minerals and hydroxy interlayered vermiculite(HIV). The B and C horizon rich in jarosite have large amounts of yellow streaks which reflect high content of $Fe_2O_3$ and $K_2O$. Vermiculite and illite were quantified from thermogravimetry(TG), kaolin minerals from both TG and differential thermal analysis(DTA), and HIV from X-ray diffraction analysis. The dominant clay minerals were kaolin minerals, vermiculite, illite and HIV. HIV considered to be formed, especially, in acid soil environments. The minor minerals were quarts, feldspar, jarosite, pyrite, hematite and goethite. Kaolin minerals were the most abundant clay minerals throughout the acid sulfate soil. Kaolin minerals, however, increased towards the top of horizons throughout the soils and HIV decreased towards the top of horizons in the soil of Gimhae series and Haecheog series. Alteration of HIV to kaolin minerals during weathering of low pH condition in deep soil horizons may explain the high quantities of kaolin minerals and the relatively low quantities of HIV in the soil at top horizons.

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Effects of Intraoperative Doxycycline Pleurodesis with Concomitant Video-assisted Thoracoscopic Bullectomy (흉강경을 이용한 폐기포절제 수술과 동시에 시행한 Doxycycline Pleurodesis의 효과)

  • Kim, Hyeong-Guk;Han, Jae-Yeol;Kim, Gwang-Ho;Kim, Jeong-Taek
    • Journal of Chest Surgery
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    • v.29 no.1
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    • pp.59-62
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    • 1996
  • Chemical pleurodesis with doxycycline has been used during video-assisted thoracoscopic surgery (VATS) as an auxiliary method to enhance therapeutic goal in patients with pneumothorax. However, the therapeutic effect of doxycycline pleurodesis (DP) has not been clearly defined yet. To evaluate the effect of DP, we compared two groups of patients who were given VATS bullectomy from October 1993 to June 1995. Group I composed of 21 patients who received DP and group II composed of 20 patients who did not received DP Doxycycline 500mg with saline 200ml were instilled into the pleural cavity upon a completion of bullec omy, and retained there for 0.5-1 hour and then drained out. The age of group I was 30.9 $\pm$ 20.0 and that of group II was 24.3 $\pm$ 9.49 years. Male to female ratio was 20: I in group I and 20 : 0 in group II. The postoperative indwelling time of chest tube was 5.86 $\pm$ 4.69 days in group I and 3.80 $\pm$ 2.28 days in group II. Seven patients had more than 100m1/day of chest tube drainage on the postoperative third day in group I compared to one patient in group II. Five patients had postoperative indwelling time of chest tube greater than 7 days in group I compared to two in group II. The number of patients who had postoperative fever were 3 in both group, analgesic requirements were 2.19 $\pm$ 2.77 amples in group I and 2.30 $\pm$ 1.95 ambles in group II. Follow-up was done from 2 months to 16 months after surgery. During the follow up periods, four patients had recurrence 2 (9.5%) in group I and 2 (10%) in group II. We conclude that concomitant doxycycline pleurodesis with video-assisted thor coscopic bullectomy In patients with pneumothorax is not necessary.

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A Comparative Study on Enhanced Phytoremediation of Pb Contaminated Soil with Phosphate Solubilizing Microorganism(PSM) and EDTA in Column Reactor (칼럼 반응조에서 Phosphate Solubilizing Microorganism(PSM)과 EDTA에 의한 납 오염토양의 식물상 복원 증진에 관한 비교연구)

  • Nam, Yoon-Sun;Park, Young-Ji;Lee, In-Sook;Bae, Bum-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.5
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    • pp.500-506
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    • 2008
  • Enhanced phytoremediation with EDTA or PSM(Phosphate solubilizing microorganism) was studied using green foxtail (Setaria viridis) in columns packed with 1,200 mgPb/kg contaminated soil to investigate the effects of EDTA or PSM on the plant uptake and vertical migration of Pb. EDTA, equimolar amount of total Pb in the column soil, was administered in two methods: the one was treated with 1/6 aliquots of the equimolar EDTA every week for 6 weeks and the other was treated with single dose of the equimolar EDTA before 14 days of harvest. The results showed that higher concentrations of Pb accumulated in the biomass of green fowtail after the chemical or biological treatment. The plant-root Pb concentration in PSM treatment(M), EDTA aliquot treatment(ES), and single dose treatment(E) was 2.6, 3.0, and 3.3 times higher, respectively, than that in the plant-root of control(164.7 mg/kg). The plant-stem Pb concentration in the M, ES and E treatment was 27, 37, and 40 times higher than that in the stem of control(8.1 mg/kg). The translocation factor, the ratio of shoot/root Pb concentration, was 0.6 in the two EDTA treatment, 0.5 in the M treatment, and 0.05 in the control, respectively. The largest amount of Pb was phyto-extracted in the E treatment whereas vertical migration of EDTA was significant in the ES treatment. This result showed that a single large dose of EDTA before harvest serves better for enhanced phytoremediation of Pb. Although, treatment with PSM showed less Pb phytoextraction by the plant but enhanced both the growth of plants in the column and microbial dehydrogenase activity in the soils. Therefore, enhanced phytoextraction of Pb with PSM treatment can be an alternative option for EDTA treatment, which is toxic to plants and soil ecosystem.

Effect of Fly Ash Fertilizer on Paddy Soil Quality and Rice Growth (비산재로 제조한 비료가 논토양 질과 벼 생육에 미치는 영향)

  • Oh, Se Jin;Yun, Hyun Soo;Oh, Seung Min;Kim, Sung Chul;Kim, Rog Young;Seo, Yung Ho;Lee, Kee Suk;Ok, Yong Sik;Yang, Jae E.
    • Journal of Applied Biological Chemistry
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    • v.56 no.4
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    • pp.229-234
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    • 2013
  • Coal ash can be added to agricultural soils to increase the chemical properties of soil such as pH, cation exchange capacity and nutrient availability of - B, Ca, Mo etc-. Therefore, the main purpose of this study was to evaluate the feasibility of fly ash as a soil amendment in paddy soils. Selected fly ash was mixed with bentonite and calcium hydroxide at the ratio of 80:15:5 (w/w) and manufactured as a pellet type at the size of 10 mm. Field experiments were conducted to evaluate the effects of fly ash fertilizer on the soil quality and crop growth compare to the control (no fertilizer) and, - traditional fertilizer. Results showed that soil pH and organic matter in paddy soils after applying the manufactured fly ash fertilizer were not increased compared to the other two treatments. However, the concentration of available phosphate and silicate in paddy soils were higher than those of the control and traditional fertilization. With regard to crop growth, no significant difference was observed between three different treatments. However, the content of protein in the rice grain cultivated with the fly ash fertilizer was higher than in the rice cultivated by other two treatments. Overall, fly ash fertilizer could increase the concentration of available silicate and phosphate in the paddy soil and improve the rice quality. In conclusion, fly ash can be utilized in agricultural soils as soil amendment, especially in the rice paddy soil.

Effects of Feeding Dehulled Soybean Meal on Growth Performance, Carcass Characteristics and Meat Quality Parameters in Berkshire Pigs (탈피대두박 급여가 흑돼지의 생산성, 도체 및 육질 특성에 미치는 영향)

  • Song, Y.M.;Kim, H.Y.;Sin, I.S.;Lee, H.S.;Lee, S.D.;Jung, H.J.;Park, J.C.;Moon, H.K.
    • Journal of Animal Science and Technology
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    • v.50 no.1
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    • pp.69-78
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    • 2008
  • A total of 360 Berkshire(hog) weighing 25kg were fed experimental diets containing either dehulled soybean meal(DSBM) or non-dehulled soybean meal(NDSBM) as a major protein source until they reach 80kg. The pigs were then fed the finisher diets either high(3,265 kcal/kg) or low(2,940 kcal/kg) in ME to evaluate the effects of dietary energy level for finisher phase on the growth performances, carcass and meat quality parameter. In growth performance, daily weight gain(kg/day) was higher(P<0.05) in T1 than in other groups. Feed conversion(feed/gain) was lower(P<0.05) in other groups. In carcass parameter, carcass percentage was higher(P<0.05) in T2 than in T1 and T4. Backfat thickness was lower(P<0.05) in T2 than in T1 and T3. The ratio of up B grade in carcass grade tender to be higher in T2 than in other groups. In meat quality, chemical composition was similar between groups. WHC was slighter higher in T1 than in other groups. Shear force was tender to be higher in T1 than in other groups. Hunter L and a in meat color were tender to be higher in T2 than in other groups. Hunter L in backfat color was thender to be higher in T1 than in other groups. The results indicate that growth performance and carcass parameter of Berkshire were improved by the dehulled soybean meal as comparison with non-dehulled soybean meal during growing and finishing periods.

Origin and Hydrochemical Characteristics of Natural Carbonated Water at Seoqwipo, Jeju Island (제주도 서귀포지역 천연탄산수의 기원과 수리화학특성)

  • Jeong, Chan Ho;Lee, Yong Cheon;Lee, Yu Jin;Choi, Hyeon Young;Koh, Gi Won;Moon, Duk Chul;Jung, Cha Youn;Jo, Si Beom
    • The Journal of Engineering Geology
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    • v.26 no.4
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    • pp.515-529
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    • 2016
  • In this study, geochemical composition, CFCs (Chlorofluorocarbons), ${\delta}^{18}O$, ${\delta}D$, ${\delta}^{13}C$ isotopes and noble gases isotopes (He, Ne) were analyzed to determine their recharge age, source of $CO_2$ gas and noble gases of carbonated hot spring water and carbonated-water samples collected in the Seoqwipo of the Jeju. The pH of the carbonated waters ranges from 6.21 to 6.84, and the high electrical conductivity range ($1,928{\sim}4,720{\mu}S/cm$). Their chemical composition is classified as $Mg(Ca,\;Na)-HCO_3$ and $Na(Ca,\;Mg)-HCO_3$ types. As a result of the calculation of groundwater age using CFCs concentrations as an environmental tracer, the carbonated water and groundwater were estimated to be about 47.5~57.2 years and about 30.3~49.5 years, respectively. The ${\delta}^{13}C$ values of carbonated water range from -1.77 to -7.27‰, and are plotted on thr deep-seated field or the mixing field of the deep-seated and inorganic origin. Noble gases isotopic ($^3He/^4He$, $^4He/^{20}Ne$) ratio shows that helium gas of carbonated hot waters comes from deep-seated magma origin.

Environmental Characteristics of Seawater and Sediment in Mariculture Management Area in Ongjin-gun, Korea (옹진군 어장관리해역의 수질 및 퇴적물 환경 특성)

  • Kim, Sun-Young;Kim, Hyung-Chul;Lee, Won-Chan;Hwang, Dong-Woon;Hong, Sok-Jin;Kim, Jeong-Bae;Cho, Yoon-Sik;Kim, Chung-Sook
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.6
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    • pp.570-581
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    • 2013
  • To improve productivity of aquaculture animals with management of culturing grounds, survey of mariculture management area in Ongjin-gun about water quality and sedimentary environment had been conducted on June, August and November in 2011. Water temperature in surface and bottom waters ranged from 9.49 to $24.14^{\circ}C$. Salinity and dissolved oxygen concentrations were in the range of 23.19~31.49 and 5.48~9.36 mg/L, respectively, depending on the variation of water temperature. The average concentration of COD was 1.57 mg/L and the concentrations of DIN and DIP showed entirely low level. As the result of grain size analysis, sand(56.66 %) and silt(34.60 %) were predominated. The Mz of sediment showed a variation of 2.59 to $6.62{\O}$ and sorting appeared to be poorly sorted. The concentrations of COD and IL in surface sediment ranged from 1.00 to $11.03mg/g{\cdot}dry$ and 0.72 to 5.29 %, respectively, which showed relatively good positive correlations. On the environmental assessment of trace metals in surface sediment, geoaccumulation index ($I_{geo}$) class indicated that sediments were not contaminated by most of metallic elements except Cr and As. Our result implies that this study area showed good water quality and sediments were not polluted by organic matters and metallic elements.

Community Structure and Distribution of Natural Seaweed Beds on the Eastern Coast of Korea (동해안 천연 해조장의 군집구조와 분포 특성)

  • Park, Gyu Jin;Ju, Hyun;Choi, Ok In;Choi, Chang Geun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.4
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    • pp.338-346
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    • 2017
  • Natural seaweed beds and habitat environments were investigated using quantitative and qualitative methods from May to December 2015 at 3 sites in Gangneung, Uljin, and Busan along the eastern coast of Korea. In total, 9 green, 23 brown, and 64 red algal taxa were identified. The biomass of the seaweed at Gangneung was 173.2 to $613.8wet\;wt.g/m^2$ of Dictyota divaricata, 360.8 to $520.4wet\;wt.g/m^2$ of Symphyocladia linearis, and 25.9 to $470.8wet\;wt.g/m^2$ of Undaria pinnatifida. At Uljin, these numbers were 5.5 to $256.2wet\;wt.g/m^2$ of Plocamium telfarirae and 46.8 to $241.5wet\;wt.g/m^2$ of Agarum clathratum. The biomass of Sargassum coreanum and Ecklonia cava were 388.1 to $6,972.4wet\;wt.g/m^2$ and 194.9 to $958.5wet\;wt.g/m^2$, respectively, at Busan. S. coreanum and E. cava showed higher biomass compared to other seaweed at Busan. The biomass rate represented an average of 19.2 percent of the total population, ranging from 0.0 to 55.5 percent in Gangneung. In Uljin, the average was calculated as 63.8 percent, and this figure was 48.5 percent in Busan. The percentage of barren ground averaged 46.7 percent in Gangneung and 91.1 percent in Uljin. Uljin showed the highest percentage of barren ground compared to other regions. Sea urchin density appeared to be $6.0ind./m^2$ in Gangneung, $7.0ind./m^2$ in Uljin, and $2.0ind./m^2$ in Busan, with the lowest sea urchin density being that of Busan. In conclusion, the composition of species, appearance ratio, and abundance of vegetation found were similar to previous studies, but it is thought that continuous monitoring is needed due to concerns about physical and chemical pollution caused by global warming, climate change, and coastal development.

Demonstration and Operation of Pilot Plant for Short-circuit Nitrogen Process for Economic Treatment of High Concentration Nitrogen Wastewater (고농도 질소함유폐수의 경제적 처리를 위한 단축질소공정 파일럿플랜트 실증화 및 운영 결과)

  • Lee, Jae Myung;Jeon, Ji-hyeong;Choi, Hong-bok
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.1
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    • pp.53-64
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    • 2020
  • A 2㎥/d combined wastewater treatment pilot plant containing the multi-stage vertical stacking type nitrification reactor was installed and operated for more than 1 year under the operating conditions of the short-circuit nitrogen process (pH 8, DO 1mg/L and Internal return rate 4Q from nitrification to denitrification reactor). For economically the combination treatment of food wastewater and the leachate from a landfill, the optimal combination ratio was operated by adjusting the food wastewater with the minimum oil content to 5-25% of the total throughput. The main treatment efficiency of the three-phase centrifugal separator which was introduced to effectively separate solids and oil from the food wastewater was about 52% of SS from 116,000mg/L to 55,700mg/L, and about 48% of normal hexane (NH) from 53,200mg to 27,800 mg/L. During the operational period, the average removal efficiency in the combined wastewater treatment process of BOD was 99.3%, CODcr 94.2%, CODmn 90%, SS 70.1%, T-N 85.8%, and T-P 99.2%. The average concentrations of BOD, CODcr, T-N, and T-P of the treated water were all satisfied with the discharge quality standard for landfill leachate ("Na" region), and SS was satisfied after applying the membrane process. On-site leachate had a relatively high nitrite nitrogen content in the combined wastewater due to intermittent aeration of the equalization tanks and different monthly discharges. Nevertheless nitrite nitrogen was accumulated, denitrification from nitrite nitrogen was observed rather than denitrification after complete nitrification. The average input of anti-forming chemical during the operation period is about 2L/d, which seems to be economical compared to the input of methanol required to treat the same wastewater.

Uronic Acid Composition, Block Structure and Some Related Properties of Alginic Acid (4) On Alginic Acid from Myagropsis myagroides Fensholt and Sargassum horneri C. Agardh (알긴산의 화학적 조성 및 그 물성에 관한 연구 (4) 외톨개모자반 및 괭생이모자반의 알긴산)

  • KIM Dong-Soo;PARK Yeung-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.18 no.2
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    • pp.124-130
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    • 1985
  • In the previous papers (Kim and Park, 1984 a, b; 1985 a), we have reported on alginic acid from Ecklonia cava and Sargassum ringgoldianum. The seasonal variation in the composition of uronic acids and their block structures of alginic acid from Myagropsis myagroides Fensholt and Sargassum horneri C. Agardh (collected from Iee Chun village on the coast of Ilgwang-myon, Yansan-gun, Kyungnam, Korea, in the period of January to December in 1982) are investigated, and their relationship between the chemical composition and some related properties are discussed in this study. One year average contents of alginic acid were $25.2\%$ in the M. myagroides and $26.5\%$ in the S. horneri, and one year average values of M/G ratios were 1.97 in the M. myagroides and 1.38 in the S. horneri. The value of M. myagroides was largest in the period of December to April, and smallest in May to June and October to November. The value of S. horneri was largest in January and smallest in March to April. The proportion of alternating, M and G block in M. myagroides were $18.4\%,\;40.4\%$, and $41.2\%$, and those in S. horneri $9.8\%,\;33.3\%$ and $56.9\%$, respectively. The higher viscosity showed the value of 45.3 cP in M. myagroides (in November), and 26.0 cP in S. horneri(in January), respectively. Furthermore, the dependence on temperature of M. myagroides alginic acid was also larger in November, that of S. horneri alginic acid in June. Ion exchange ability of M. myagroides alginic acid was highest in November and the exchange amounts were $Pb^{2+}\;4.4,\;Cu^{2+}\;1.8,\;Zn^{2+}\;2.5$ and $Co^{2+}\;2.0\;meq/g$. Na-Alg., and the ability of S. horneri alginic acid was highest in June and the amounts were $Pb^{2+}\;4.5,\;Cu^{2+}\;2.2,\;Zn^{2+}\;2.4$ and $Co^{2+}\;2.1\;meq/g.$ Na-Alg. The affinity with metallic ions appeared higher in order of $Pb^{2+}>Cu^{2+}>Zn^{2+}>Co^{2+}$, and the exchange ability assumed to relate with the block ratio of uronic acid.

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