• Title/Summary/Keyword: Chemical Oceanography

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Regeneration Processes of Nutrients in the Polar Front Area of the East Sea 1. Relationships between Water Mass and Nutrient Distribution Pattern in Autumn (동해 극전선역의 영양염류 순환과정 1. 추계 수괴와 영양염 분포와의 관계)

  • Moon Chang-Ho;YANG Han-Soeb;LEE Kwang Woo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.4
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    • pp.503-526
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    • 1996
  • A synoptic survery of chemical characteristics in the last Sea of Korea was carried out at the 11 stations near Ullungdo in November, 1994 on board R/V Tam-Yang. On the basis of the vortical distribution patterns of temperature, salinity and dissolved oxygen, water masses in the study area are divided into five groups; 1) Tsushima Surface Water (TSW), 2) Tsushima Middle Water (TMW), 3) East Sea Intermediate Water (ESIW), 4) last Sea Proper Water (ESPW), 5) Mixed Water (MW). In the vertical profiles of nutrients, the concentrations were very low in the surface layer and increased rapidly near the thermocline. There was a slight decrease in the ESIW and the concentrations were constant with the depth below 300m except dissolved silicate which still increased with depth. Relatively high value of Si/P ratio (25.2) in ESPW, whick is the oldest water mass, suggests that Si is regenerating more slowly compared to other nutrients. The relatively high value of N/P ratio (18.6) in the surface layer might be related to high vertical eddy diffusivity $(K_z)$ of $1.19\;cm^{2}/sec$ and high nitrate upward flux of $103.7\;{\mu}g-at/m^{2}/hr$, compared to the values reported in other areas. Apparent Oxygen Utilization (AOU) was very low in the surface layer and increased in the TMW, but there was a slight decrease in the ESIW. The highest value of AOU occurred in the ESPW. The slpoe of P/AOU was 0.50. The study on the relationship between water masses and nutrient distribution patterns is important in understanding the regeneration processes of nutrients in the polar region of the last Sea.

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The Study on the Seasonal Variation of Microbial Community in Kyeonggi Bay, Korea 1. Bacteria and Heterotrophic nanoflagellates (경기만 수역에서 미세생물 군집의 계절적 변동 연구 I. 박테리아와 종속영양 미소 편모류)

  • 양은진;최중기;현정호
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.8 no.1
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    • pp.44-57
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    • 2003
  • Seasonal variations of bacterial abundance and production, heterotrophic nanoflagellate (HNF) abundance and HNF ingestion rates on bacteria using FLB together with environmental variables were investigated at intervals of a month in Kyeonggi Bay from December 1991 to November 1998. Bacterial abundance and production ranged from 0.38$\times$10$^{9}$ ~ 3.25$\times$10$^{9}$ cells 1$^{-1}$ (average 1.19$\pm$0.69$\times$10$^{9}$ cells 1$^{-1}$ ) and from 1.51 to 20.4 cells 1$^{-1}$ h$^{-1}$ (average 6.04$\pm$ 1.88$\times$10$^{6}$ cells 1$^{-1}$ h$^{-1}$ ), respectively. Bacterial abundance and production showed no differences at the high tide and low tide, and bacterial abundances were not different with depth, but bacterial production decreased with depth. Seasonal variation of bacterial abundance showed almost similar fluctuation pattern to those of DOC (dissolved organic carbon). HNF abundances ranged from 388 to 4,374 cells ml$^{-1}$ (average 1,344$\pm$130 cells ml$^{-1}$ ), were high in March, April, July and August. HNF abundance showed no difference between the high tide and low tide, and was not different with depth. The ingestion rates of HNF on bacteria were 1.0 to 6.3$\pm$10$^{6}$ bacteria 1$^{-1}$ h$^{-1}$ (average 3.12$\pm$0.55$\times$10$^{6}$ bacteria 1$^{-1}$ h$^{-1}$ ), resulting ingestion rates of HNF removed 19.4 to 141.4 %(average 62.3$\pm$12.0%) of bacterial production. Ingestion rates and grazing pressure of HNF on bacteria showed high correlation with HNF abundance. Although we cannot exactly discussion about seasonal variation of bacteria community in this study area where physical and chemical parameters were very complex, the results indicate that bacterial abundance and production were mainly controlled by resources supply as dissolved organic carbon and chlorophyll-a(bottom-up) except March which bacterial abundance and production uncoupled chlorophyll-a because of low dissolved organic carbon and low temperature, and were controlled by HNF grazing pressure(top-down) in the warm seasons except the winter.

Change of Blooming Pattern and Population Dynamics of Phytoplankton in Masan Bay, Korea (마산만 식물플랑크톤의 대발생 양상의 변화와 군집 동태)

  • Lee, Ju-Yun;Han, Myung-Soo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.12 no.3
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    • pp.147-158
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    • 2007
  • To clarify the bloom pattern and species succession in phytoplankton community, the population dynamics with the determination of physico-chemical factors have been studies in Masan Bay, the south sea of Korea, for the periods November 2003-October 2004. Concentration of $NH_4-N$ was always higher than that of $NO_3-N$, which was similar level as compared to other costal areas. $PO_4-P$ concentration was lower than those in other coastal areas but similar to oligotrophic environments. Thus, phosphate seems the limiting nutrient rather than nitrogen. $SiO_2-Si$ concentration was also low as compared to other costal areas. Si:P ratio was low from autumn to winter, suggesting silicate and/or phosphate limitation during this period. The cell density of phytoplankton was high in winter 2003 and early autumn 2004. The carbon biomass was high in winter 2003 and summer 2004. And chlorophyll-a concentration was high in late autumn 2003 and summer 2004. Among 78 species of phytoplankton found in the bay during the investigated period, dominant species were two diatoms of Cylindrotheca closterium, Skeletonema costatum, and three dinoflagellates of Heterocapsa triquetra, Prorocentrum minimum, P. triestinum, and one raphidophyte of Heterosigma akashiwo. P. minimum dominated from late autumn to winter, but it was replaced by H. triquetra in late winter. P. triestinum dominated from late spring to early summer. Simultaneously, H. akashiwo cell density steadily increased, and it became dominant with C. closterium in late summer. With decreasing of H. akashiwo and C. closterium, S. costatum became the most dominant species in autumn. The canonical analyses showed that total phytoplankton cell density related to diatom cell density and it was affected by temperature, and concentrations of $NO_3-N\;and\;PO_4-P$. The carbon bio-mass and $chlorophyll-{\alpha}$ concentration related to diatom- and dinoflagellate cell densities and these were affected by flagellate cell density, salinity, and concentrations of $SiO_2-Si\;and\;PO_4-P$. Last six years monitoring data in Masan city obtained from Korean Meteorological Agency indicates gradual increase in air temperature. And the precipitation decreased especially in spring season. The winter bloom found in 2003 may be caused by the increase in the temperature and this bloom subsequently induced the nutrients depletion, which continued until next spring probably due to no precipitation. Therefore, the spring bloom, which had been usually observed in the bay, might disappear in 2004.

A Study of Variation Characteristics of the Phytoplankton Community by UPLC Located in the Jinju Bay, Korea (UPLC를 이용한 남해 진주만 식물플랑크톤 군집 변동특성 연구)

  • Lee, Eugene;Son, Moonho;Kim, Jeong Bea;Lee, Won Chan;Jeon, Ga Eun;Lee, Sang Heon
    • Korean Journal of Environmental Biology
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    • v.36 no.1
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    • pp.62-72
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    • 2018
  • In order to provide important information for the efficient management of the identified farm ecosystem in Jinju Bay, we investigated the spatial and temporal distribution of the phytoplankton community using a UPLC pigment analysis and a CHEMTAX program from the timeframe of February 2013 to January 2014. In addition, we measured the available physical and chemical parameters controlling the distribution of the phytoplankton communities. As a result of this comprehensive pigment analysis, it was noted that the Diatoms were the predominant species with an average of 77.1% as noted located in Jinju Bay. It was discovered that during the summer season, the phytoplankton community composition was changed by a reduction of diatoms and noted increases of the Cryptophytes, Prasinophytes, and Dinoflagellates. Especially, it was noted that the Cryptophytes and Prasinophytes were shown with an average of 18.8% and 17.8% in June, respectively. However, it was revealed that the Cryptophytes and Prasinophytes were not shown by a microscopic observation. The phytoplankton community composition was correlated with the temperature and salinity variations as noticed in the Jinju Bay. Therefore, the water temperature and freshwater inputs in the Jinju Bay were important environmental factors for controlling the phytoplankton community composition and the varying Cryptophytes and the noted amounts of Prasinophytes as well.

Analysis of Oceanographic Condition in the Cheju Strait, the Korea Strait and the Mixed water area Between the two Regions in Early June in 1995 (1995년 6월 초순 제주해협과 대한해협 입구 해역에서의 해황 분석)

  • CHOI Young-Chan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.2
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    • pp.296-301
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    • 1998
  • The physical and chemical characteristics were examined in the southern sea of Korea including the Cheju Strait, and the entrance of the Korea Strait in the period of May 30 to June 8, 1995. The results are as follows. Firstly, the variation ranges of the temperature and salinity at the Cheju Stratit during 24 hours observation were larger in the surface layer than that in the deep layers. Secondly, daily variations of nutrients show that total inorganic nitrogen, phosphate phosphorous, and silicate silicon concentration are higher at night than at day. Thirdly, water temperature and salinity distributions show highest values at the entrance of Korea Strait, which is thought to be influenced directly by Tsushima Warm Current, while they show the lowest values in Cheju Strait. This means that the surface waters in Korea Strait are greatly influenced from the entrance of Korea Strait and bottom waters is greatly influenced from Cheju Strait. Fourthly, nutrients distribution shows highest values in Korea Strait but dissolved oxygen shows lowest values in the area. These seem to be caused by the oxygen consumption used in the inorganization of nutrients to decompose organisms and the liquidation of nutrients.

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Environmental Characteristics of the Seawater and Surface Sediment in the vicinity of Pusan Harbor Area in Winter (겨울철 부산항 주변해역의 수질과 표층퇴적물 환경특성)

  • PARK Young-Chul;YANG Han-Soeb;LEE Pil-Yong;KIM Pyoung-Joong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.28 no.5
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    • pp.577-588
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    • 1995
  • The chemical constituents for the seawater and sediment were measured to evaluate pollution in the sea around Pusan Harbor in winter, n992. The average value of trophic state index (TSI) was 19.4 at the outside of Buk Harbor, 50,4 at the inside of Buk Harbor, 56,3 at the Nam Harbor and 5,0 at the Kamchun Harbor. The high correlation found in salinity-nutrients diagram with AOU suggested that the enrichment of nutrients in Pusan Harbor during winter was mainly due to the influx of terrestrial effluents and partially by regenerated nutrients from suspended organic matters in the water column. The mean values of total ignition loss (TIL), COD and total sulfide in the surface sediments were$12.1\%$, 17.5 mg/g.dry wt. and 1.18 mg/g.dry wt. respectively. The highest level of those parameters was shown mostly at the inside of Buk Harbor. The mean concentration of total organic carbon (TOC), total organic nitrogen (TON), and total phosphorus were 24.9 mg/g.dry wt., 1.3mg/g.dry wt. and 0.69 mg/g. dry wt., respectively, Both of the highest level for TOC and total phosphorus have found at the Nam Harbor. On the other hand, the Highest level for TON was found at the inside of Buk Harbor. The TOC/TON atomic ratio with a range of 10.2-60.2 (mean value of 22.5) strongly indicated the active role of the input from the terrestrial organic pollutants.

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Formation and Behavior of Sedimentary Inorganic Sulfides in Banweol Intertidal Flat, Kyoung-gi Bay, West Coast of Korea (황해 경기만 반월조간대 퇴적물 내의 황화물 형성과 행동에 관한 연구)

  • 김범수;이창복
    • 한국해양학회지
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    • v.28 no.3
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    • pp.229-240
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    • 1993
  • This study investigated the behaviour of sulfur species after the early diegenetic reduction of sulfate from pore solution in an anoxic intertidal flat deposit in the Banweol area of Kyeong-gi Bay, west coast of Korea. A total of seven sediment cores were collected during 1990∼1992 and were analyzed for their solid-phase sulfur species (acid-volatile sulfur, element sulfur, pyrite sulfur) as well as for chemical components in the pore solution, such as sulfate, ammonium, hydrogen sulfide, phosphate and Fe ion. The pore water sulfate oncentration was found to decrease rapidly downward from the sediment surface, while that of hydrogen sulfide, ammonium and phosphate showed and increase. The dissolved iron concentration in pore water, on the other hand, was found high in the surface layer of sediment, but fell sharply below this layer. these characteristic profiles of pore water sulfide and iron concentrations suggest that some reaction occurs between dissolved iron and sulfide ions, leading to the formation of various sulfide minerals in the sedimentary phase. The amount of inorganic sulfur species in the sediment increased downward, and showed a maximum of up to 7.9 mg/g. among the three species analyzed, acid-volatile sulfur (AVS) was dominant comprising more than 50% of the total. The amount of pyrite sulfur was greater than that of element sulfur. This implies that the formation of pyrite was restricted in this environment. the limited amount of element sulfur in this deposit may have discouraged the active formation of pyrite.

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Investigation of Water Quality in the Laver Bed at Yongwon Ri, Changwon Gun During the Spring and Neap Tide in March 1970 (경남 창원군 능동면 용원리 김밭의 수질에 대하여)

  • Won, Chong Hun
    • 한국해양학회지
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    • v.5 no.1
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    • pp.30-36
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    • 1970
  • The water quality of the laver bed at Yongwon Ri, Changwon Gun was investigated during the spring and neap tide in March 1970. The effect of tide on the contents of various chemical constituents was irregular and the variation ranges of the contents were narrow. The pH value during flood and ebb tide was a constant of 8.2. The chlorosity range varied from 19.15 to 19.33g/l, the difference of 0.18g/l being comparatively small for coastal waters. The nutrient salts contents varied irregulary with the change in tide, but nitrite and soluble iron were not detected. In local distribution, chlorosity and silicate- silicon contents were found to be more at Sts. 1, 2 and 3 in the eastern area than at Sts. 4, 5 and 6 in the western area, wheras nitrate and ammonia contents were found to be more at Sts. 4, 5 and 6. The nitrate content was especially high, being twice as much as that at Sts. 1, 2 and 3 in the eastern area. In the spring tide, chlorosity was found, on the average, to be as much as 0.06g/l higher than in the neap tide, but the contents of nutrient salts were higher in the neap tide, especially the nitrate content was twice as much. When compared with other selected local laver beds, i.e., the tidal flats of the Nackdong and Somjin rivers, and of Wan Do Gun, the chlorosity level was highest but the nutrient salts contents level was, in general, slightly lower and the variation ranges narrow in the laver bed at Yongwon ri. The nitrate content, in particular was one tenth smaller than the others.

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Mineralogy, Geochemistry, and Formation of Ferromanganese Nodules from the KONOD-1 Site, Northeastern Equatorial Pacific (북동(北東) 적도(赤道) 태평양(太平洋)(KONOD-1) 망간 단괴(団塊)의 은물조성(銀物組成), 화학분석(化學成分)과 성인(成因))

  • Kang, Jung-Keuk;Han, Sang-Joon
    • 한국해양학회지
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    • v.23 no.3
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    • pp.110-122
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    • 1988
  • Between the Clarion and Clipperton fracture zones of the Northeastern Pacific, nodules and crusts were collected from abyssal plain and hills by the Korea Ocean Research and Development Institute in December, 1983 aboard the R/V KANA KEOKI of the Hawaii Institute of Geophysics. Mineralogical and geochemical data of bulk nodules are obtained and compared with analyses of other studies. Mechanisms of nodule formation are discussed based on these data. Generally, the nodules of the KONOD-1 site are composed of todorokite and ${\delta}-MnO_2$. The contents of Mn, Fe, Ni, and Cu of the bulk nodules are variable and the average contents of metals are slightly lower (Mn, 21.40%; Ni, 0.9%; Cu, 0.8%) than those of nodules from other abyssal plains between the Clarion and Clipperton fracture zones. High Mn/Fe (average 3.9; maximum 5.9) and Cu/Ni (average 0.8; maximum 1.0) ratios are similar to the nodules that were formed diagenetically in the northeast Pacific. The chemical characteristics of the KONOD-1 nodules reflect their sedimentary environments; nodules with higher diagenetic signatures occur in areas of thin Quaternary siliceous ooze, and nodules of lower diagenetic influence occur in topographically irregular abyssal hill areas.

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Studies on Chemical and Biological Processes in the Keum River Estuary, Korea 2. Factors controlling chlorophyll-a distribution (금강 하구에서의 화학적, 생물학적 제과정에 관한 연구 II. Chlorlphyll-a 분포 결정 요인에 관하여)

  • 기준학;김정렬
    • 한국해양학회지
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    • v.22 no.3
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    • pp.207-215
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    • 1987
  • The Keum River Estuary was investigated two times in April and July, 1986, to study process controlling chlorophyll distribution in estuarine waters. During the surveys, distribution patterns were studied for chlorophyll-a, nutrients, ph, SPM (Suspended Particulate Matter), DO (Dissolved Oxygen), temperature, salinity, etc. During April survey(low-discharge period), sea water penetrated to Kangkyung, about 35km upstream from the constructing weir, while in July (high-discharge period) only to 3 km upstream from the weir,In April SPM showed very high concentrations (500mg/l)on the average. But very low concentrations(about10mg/l)were observed in July due to high discharge of fresh water.Chlorophyll-a concentrations showed large variations both in time and space :much higher concentraations in July than in April and sharp decrease in concentrations at the fresh water-sea water interface (April:$6.5\mu\textrm{g}/{\ell}$ for fresh waters and 41.4\mu\textrm{g}/{\ell}$ forestuarine waters). Differebce ub chlorophyll-a concentrations for these two surveys appear to be caused mainly by the difference in effectiveness of penetrating lights controlled by SPM in the waters. Sharp decrease in chlorophll-a at the fresh water-sea water interface is believed to be resulted from mass mortality of fresh water phytoplankton caused by changes in osmotic pressure in the region. Observations in the same regions such as increase in AOU(Apparent Oxygen Utilization)and ammonia, decrease in PH,probably resulted through decomposition processes of dead planktons,furtuer support the idea.

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