• Title/Summary/Keyword: Chemical Mixing

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A Study on Internal Flow of Mixing Tank by CFD (CFD를 이용한 가향 탱크 내부 유동에 관한 연구)

  • Chung, Han-Joo;Cho, Sung-Eel;Yang, Jin-Chul
    • Journal of the Korean Society of Tobacco Science
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    • v.32 no.2
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    • pp.63-69
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    • 2010
  • In the chemical, mineral and electronics, mechanically stirred tanks are widely used for complex liquid mixing processes. The paper present results from a computational fluid dynamics (CFD) model for the mixing tank in casing process. We used CFD software, FLUENT(Fluent, Inc, Lebanon, NH, version 6.2). A species transport model was used to model the problem. The flow patterns in a mixing tank, 1.6 m in diameter and 2.0 m in height, were studied using CFD. Numerical analysis results show that improved mixing tank was reduced low speed flow region and turbulent region in internal flow of mixing tank.

Investigations on the Optimum Design of Chemical Addition System for Nuclear Power Plants

  • Chang, Byong-Hoon;Chung, Chang-Kyu;Park, Han-Rim;Kim, Eun-Kee;Ro, Tae-Sun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.369-374
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    • 1997
  • Mixing characteristics of tire chemical additives in the chemical injection tank of the chemical and volume control system(CVCS) were investigated for the Yonggwang Nuclear units 5&6. Numerical calculations were performed with a low-Reynolds number turbulence model. Studies were also conducted for the injection tank with a disk located at 1/4H, 2/4H, and 3/4H from the inlet in order to see the effect in the enhancement of chemical mixing. Results show that the optimum arrangement is to locate a disk close to the inlet.

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Compatibilization of Immiscible Poly(l-lactide) and Low Density Polyethylene Blends

  • Kim Young Fil;Choi Chang Nam;Kim Young Dae;Lee Ki Young;Lee Moo Sung
    • Fibers and Polymers
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    • v.5 no.4
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    • pp.270-274
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    • 2004
  • Blends of poly(l-lactide) (PLA) and low density polyethylene (LDPE) were prepared by melt mixing in order to improve the brittleness of PLA. A reactive compatibilizer with glycidyl methacrylate (GMA), PE-GMA, was required as a compatibilizer due to the immiscibility between PLA and LDPE. It contributes to reduce the domain size of dispersed phase and enhance the tensile properties of PLA/LDPE blends, especially for PLA matrix blends. A reaction product between PLA and PE-GMA, which was formed during melt-mixing and considered to act as a reactive compatibilizer, was characterized using $ ^1H-NMR$ spectroscopy.

Mixing Characteristics of Sequential Blending with DME and LPG in Mixing Drum (DME-LPG 순차 혼합시 저장탱크 내의 혼합특성)

  • Cheon, Suk Hoon;Kim, Cha Hwan;Shin, Dong Woo;Kim, Lae Hyun;Lee, Hyun Chan;Baek, Young Soon
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.464-470
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    • 2012
  • To study characteristics of DME and Propane blended fuel in mixing drum as time passed, mixing experiment of two components was performed. After 20 wt% of DME and 80 wt% of Propane were injected into mixing drum sequentially, and the mixture ratio of blended fuel was analyzed at several sampling ports. Consequently, DME and Propane were not easily mixed and DME was sunk to the bottom of the mixing drum by the density difference. The daily rate of DME ingredient increase was 0.2-0.3 wt%, and it took over 500 hours until two of them were mixed uniformly. And after recirculation of blended fuel in mixing drum, DME and Propane were mixed immediately and uniformly.

Simulation of Air Quality Over South Korea Using the WRF-Chem Model: Impacts of Chemical Initial and Lateral Boundary Conditions (WRF-Chem 모형을 이용한 한반도 대기질 모의: 화학 초기 및 측면 경계 조건의 영향)

  • Lee, Jae-Hyeong;Chang, Lim-Seok;Lee, Sang-Hyun
    • Atmosphere
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    • v.25 no.4
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    • pp.639-657
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    • 2015
  • There is an increasing need to improve the air quality over South Korea to protect public health from local and remote anthropogenic pollutant emissions that are in an increasing trend. Here, we evaluate the performance of the WRF-Chem (Weather Research and Forecasting-Chemistry) model in simulating near-surface air quality of major Korean cities, and investigate the impacts of time-varying chemical initial and lateral boundary conditions (IC/BCs) on the air quality simulation using a chemical downscaling technique. The model domain was configured over the East Asian region and anthropogenic MICS-Asia 2010 emissions and biogenic MEGAN-2 emissions were applied with RACM gaseous chemistry and MADE/SORGAM aerosol mechanism. Two simulations were conducted for a 30-days period on April 2010 with chemical IC/BCs from the WRF-Chem default chemical species profiles ('WRF experiment') and the MOZART-4 (Model for OZone And Related chemical Tracers version 4) ('WRF_MOZART experiment'), respectively. The WRF_MOZART experiment has showed a better performance to predict near-surface CO, $NO_2$, $SO_2$, and $O_3$ mixing ratios at 7 major Korean cities than the WRF experiment, showing lower mean bias error (MBE) and higher index of agreement (IOA). The quantitative impacts of the chemical IC/BCs have depended on atmospheric residence time of the pollutants as well as the relative difference of chemical mixing ratios between the WRF and WRF_MOZART experiments at the lateral boundaries. Specifically, the WRF_MOZART experiment has reduced MBE in CO and O3 mixing ratios by 60~80 ppb and 5~10 ppb over South Korea than those in the WRF-Chem default simulation, while it has a marginal impact on $NO_2$ and $SO_2$ mixing ratios. Without using MOZART-4 chemical IC, the WRF simulation has required approximately 6-days chemical spin-up time for the East Asian model domain. Overall, the results indicate that realistic chemical IC/BCs are prerequisite in the WRF-Chem simulation to improve a forecast skill of local air quality over South Korea, even in case the model domain is sufficiently large to represent anthropogenic emissions from China, Japan, and South Korea.

Evaluation of the Prediction Performance of FDS Combustion Models for the CO Concentration of Gas Fires in a Compartment (구획실 내 가스연료 화재의 CO 농도에 대한 FDS 연소모델의 예측성능 평가)

  • Baek, Bitna;Oh, Chang Bo;Hwang, Chel-Hong;Yun, Hong-Seok
    • Fire Science and Engineering
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    • v.32 no.1
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    • pp.7-15
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    • 2018
  • The prediction performance of combustion models in the Fire Dynamics Simulator (FDS) were evaluated by comparing with experiment for compartment propane gas fires. The mixture fraction model in the FDS v5.5.3 and Eddy Dissipation Concept (EDC) model in the FDS v6.6.3 were adopted in the simulations. Four chemical reaction mechanisms, such as 1-step Mixing Controlled, 2-step Mixing Controlled, 3-step Mixing Controlled and 3-step Mixed (Mixing Controlled + finite chemical reactions) reactions, were implemented in the EDC model. The simulation results with each combustion model showed similar level for the temperature inside the compartment. The prediction performance of FDS with each combustion model showed significant differences for the CO concentration while no distinguished differences were identified for the $O_2$ and $CO_2$ concentrations. The EDC 3-step Mixing Controlled largely over-predicted the CO concentration obtained by experiment and the mixture fraction model under-predicted the experiment slightly. The EDC 3-step Mixed showed the best prediction performance for the CO concentration and the EDC 2-step Mixing Controlled also predicted the CO concentration reasonably. The EDC 1-step Mixing Controlled significantly under-predict the experimental CO concentration when the previously suggested CO yield was adopted. The FDS simulation with the EDC 1-step Mixing Controlled showed difficulties in predicting the $CO_2$ concentration when the CO yield was modified to predict the CO concentration reasonably.

Effects of Quality of Alfalfa Silage by Different Wheat Bran Mixing Levels (밀기울 첨가수준이 알팔파 Silage 품질에 미치는 영향)

  • 신재순;차영호;이혁호;김정갑;진현주;정기영
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.3
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    • pp.225-229
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    • 1996
  • To find out the optimum mixing level of wheat bran to improve the quality of 1st cut Alfalfa silage, this trial was canied out at two-year's Alfalfa monoculture field of the National Livestock Research Institute, Suwon, Korea, from May 1955 to Oct. 1995. The results are as follows. I. According to the increase of wheat bran mixing level, DM content was high from 23.19%(nil) to 35.70%(40% mixing), pH of silage were low from 5.51(nil) to 4.45(40% mixing). but there were not significant at 20% mixing or more(P>0.05). 2. Also it was appeared to the same trend at Lactic acid content and in the Flieg's score of silage it was highest as 59 in the 20% mixing level. 3. In chemical component of silages there were not significant at 20% mixing or more in crude protein, crude fiber and ashes content, 30% mixing or more in ether extract and 10% or less in NFE content(P>0.05). 4. TDN, NEL and StE contents were low as adding level was increased. respectively, but there were not significant(P>O.OS). As mentioned above the results, desirable mixing level of wheat bran to lstcut Alfalfa to improve the quality of silage was 20% of fresh weight.

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Synthesis and Characterization of Tin-Pyrolyzed Carbon Composites as Anode Material for Lithium Ion Secondary Batteries (리튬이온이차전지 음극활물질로써 주석을 첨가한 열분해탄소의 합성과 특성평가)

  • Hwang, Yun-Ju;Park, Sang-Ho;Kim, Ae-Rhan;Jisha, M.R.;Christy, Maria;Suh, Eun-Kyung;Nahm, Kee-Suk
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.16-20
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    • 2010
  • In present work, tin-carbon mixtures by using carbon from pyrolyzed coffee seeds were synthesized. Synthesis methods includes simple mixing and chemical mixing. X-ray diffraction pattern indicated carbon and tin mixture peaks and scanning electron microscope images showed particles size of $12{\sim}85\;{\mu}m$ and shape. Charge discharge test were carried out. Tin-carbon mixture by chemical mixing indicated higher discharge capacity of 191 mAh/g than commercial carbon black(105 mAh/g) for 15cycles. Tin-carbon mixture by simple mixing indicated similar performance to carbon black.

Liquefaction Characteristics of Polypropylene-Polystyrene Mixture by Pyrolysis at Low Temperature (Polypropylene-Polystyrene 혼합물의 저온 열분해에 의한 액화특성)

  • Cho, Sung-Hyun;Kim, Chi-Hoi;Kim, Su-Ho;Lee, Bong-Hee
    • Clean Technology
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    • v.16 no.1
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    • pp.26-32
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    • 2010
  • The low temperature pyrolysis of polypropylene (PP), polystyrene (PS) and polypropylene-polystyrene (PP-PS) mixture in a batch reactor at the atmospheric pressure and $450^{\circ}C$ was conducted to investigate the synergy effect of PP-PS mixture on the yield of pyrolytic oil. The pyrolysis time was varied from 20 to 80 mins. The products formed during pyrolysis were classified into gas, gasoline, kerosene, gas oil and heavy oil according to the petroleum product quality standard of Ministry of Knowledge Economy. The analysis of the product oils by GC/MS(Gas chromatography/Mass spectrometry) showed that new components were not detected by mixing of PP and PS. There was no synergy effect according to the mixing of PP and PS. Conversions and yields of PP-PS mixtures were linearly dependent on the mixing ratio of samples except for heavy oil yields. Heavy oil yields showed almost constant regardless of the mixing ratio.

Ultrasonic degradation of polypropylene and its application for the development of PP based copolymer and nanocomposite

  • Ryu, Joung-Gul;Lee, Pil-Soo;Kim, Hyungsu;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.13 no.2
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    • pp.61-65
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    • 2001
  • Thermoplastic nanocomposites based on the copolymers of polypropylene (PP)-polystyrene (PS) and organically modified montmorillonite (org-MMT) were produced by using power ultrasonic wave in an intensive mixer. Owing to the unique action of the ultrasonic wave, free radicals of styrene monomers and macroradicals of PP were generated, by which copolymers of PP and PS were formed. Another important aspect of using ultrasonic wave during the mixing process was to enhance nano-scale dispersion of org-MMT by destructing the agglomerates of org-MMT in the polymer matrix. Optimum conditions for the in-situ copolymerization and melt intercalation were studied with various concentrations of styrene monomer, sonication time and different kinds of clay. It was found that a novel attempt carried out in this study yielded further improvement in the mechanical performance of the nanocomposites compared to those produced by the conventional melt mixing process.

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