• Title/Summary/Keyword: Chemical Mixing

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Microstructure and Magnetic Properties of Nanostructured Fe-Co Alloy Powders Produced by Chemical Solution Mixing and Hydrogen Reduction Methods (화학용액혼합과 수소환원법으로 제조된 나노 구조 Fe-Co 합금분말의 미세구조 및 자성 특성)

  • 박현우;이백희;이규환;김영도
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.333-336
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    • 2003
  • The purpose of this study is the fabrication of nano-sized Fe-Co alloy powders with soft magnetic properties by the slurry mixing and hydrogen reduction (SMHR) process. $FeCl_2$0 and $CoCl_2$ powders with 99.9% purities were used for synthesizing nanostructured Fe-Co alloy powder. Nano-sized Fe-Co alloy powders were successfully fabricated using SMHR, which was performed at 50$0^{\circ}C$ for 1 h in H$_2$ atmosphere. The fabricated Fe-Co alloy powders showed $\alpha$' phase (ordered body centered cubic) with the average particle size of 45 nm. The SMHR powder exhibited low coercivity force of 32.5 Oe and saturation magnetization of 214 emu/g.

A Study on CFD Simulation of Rotational Flow in Stirred Tanks (교반 탱크 내 회전 유동의 CFD 해석 연구)

  • Cho, Chan-Young;Nam, Jin-Hyun;Shin, Dong-Hoon;Chung, Tae-Yong
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1406-1411
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    • 2009
  • Stirred tanks are widely used in various industries for mixing operations and chemical reactions for single- or multi-phase fluid systems. In this study, a numerical study was conducted to predict the mixing characteristics in a simple stirred tank. The flow in the model stirred tank was calculated utilizing the multiple reference frame (MRF) and the sliding mesh (SM) capabilities of a commercial CFD code (Fluent 6.2). The results of the flow simulation were analyzed in terms of the mixing efficiency, and the applicability of MRF and SM methods was also discussed.

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The Effects of Sputtering conditions in Pre Sputtering on the Formation Behavior of Nitride Layer in the Ion Nitriding of Stainless Steel (초기 스퍼터링조건이 스테인리스강의 이온질화시 지로하층 형성거동에 미치는 영향)

  • 최상진
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1999.10a
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    • pp.197-203
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    • 1999
  • Stainless steels in general has passive film having strong corrosion resistance on surface. Therefore it must be necessarily removed by etching in mixing solution of sulfuric and chloric acid before Nitriding treatment. But in the ion nitriding, nitride layer was easily formed because passive film was removed without difficult by sputtering effect. The removal extent of these passive films was greatly effected by gas mixing ratios and pressure and holding times of pre sputtering factors in pre sputtering stage. As a results of experiment it has been known that pre sputtering pressure and holding time was not nearly effective on the formation behavior of nitride layer. But when A/H2 gas mixing ratios was 1/2 (vol%) was the most effective of the all pre sputtering conditions. It was resulted from the combination of mechanical reaction byArgon bombardment and chemical reaction by reduction of hydrogen on the passive film.

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Characterization of Mixing in Reaction Modules for the Production of Chemical Materials (화학소재 생산용 반응 모듈의 혼합 성능 해석)

  • Seo J.H.;Kim Y.S.;Choe J.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.537-538
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    • 2006
  • Split and recombine type reaction module was made by electrical discharge machining. The reaction module has special features to well mix the two reactants which have high flow ratio or high concentrations difference. It could be achieved by deviding one flow equally by two and inserting second flow in between. The mixing performance was measured by a parallel competing reaction with iodide-iodate system. The result shows that the developed three inlets micromixer has better mixing efficiency than comercialized Y type micromixer.

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Dry Etch Characteristics of TiN Thin Film for Metal Gate Electrode (Metal 게이트 전극을 위한 TiN 박막의 건식 식각 특성)

  • Um, Doo-Seung;Woo, Jong-Chang;Park, Jung-Soo;Kim, Chang-Il
    • Journal of Surface Science and Engineering
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    • v.42 no.4
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    • pp.169-172
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    • 2009
  • We investigated the dry-etching mechanism of the TiN thin film using a $Cl_2$/Ar inductively coupled plasma system. To understand the effect of the $Cl_2$/Ar gas mixing ratio, we etched the TiN thin film by varying $Cl_2$/Ar gas mixing ratio. When the gas mixing ratio was 100% $Cl_2$, the highest etch rate was obtained. The chemical reaction on the surface was investigated with X-ray photoelectron spectroscopy (XPS). Scanning electron microscopy (SEM) was used to examine etched profiles of the TiN thin film.

Relationships between Morphologies and Properties of PA 6,6/EPM/EPM-g-MA Blends (PA 6,6/EPM/EPM-g-MA 블렌드물의 특성과 Morphology 관계)

  • Lee, Yoong;Lee, Chang-Woo;Chang, Yoon-Ho;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.682-689
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    • 1999
  • In this study, binary PA 6,6/EPM(or EPM-g-MA) blends and ternary PA 6,6/EPM/EPM-g-MA blends were fabricated according to the variation in elastomer content and composition ratio of blend, and mixing temperature and rate so as to investigate the degree of influence of elastomer content and average particle size, morphology, and distribution of dispersed elastomer on properties of blends. As results, under the constant mixing rate(250 rpm) and different five section temperature profiles(270-265-265-255-$255^{\circ}C$) in extruder, high notched Izod impact strength was the property of PA 6,6/EPM-g-MA(70/30) blend among binary blends. Notched Izod impact strength of this blend was 25 times improvement compared with that of polyamide 6,6. In addition, elastomer average particle size of ternary PA 6,6/EPM/EPM-g-MA(70/15/15) blend was $0.56{\mu}m$, which was fine distribution, and notched Izod impact strength of that blend was the highest of all blends prepared with the variation in elastomer content. But the properties of this ternary blend were decreased remarkably at the diverse mixing temperatures and mixing rates.

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A Study on the Factors for Improvement of Chemical and Physical Properties in Fluoric Rubber Coating for Use of the Extremely Acidic Environments

  • Chang, Hyun Young;Jin, Tae Eun;So, Il Soo;Lee, Byung Seung;Kang, Min Soo
    • Corrosion Science and Technology
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    • v.7 no.5
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    • pp.269-273
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    • 2008
  • It is known that the fluoric resin has the most outstanding properties in the extremely acidic environment of high temperature. However, this resin is the thermal hardening type that needs long time heat treatments above $250^{\circ}C$. It's impossible to use in situ in the extremely acidic environment such as a huge FGD ductworks or industrial chemical tanks. Furthermore, even the natural hardening type fluoric coatings which can be hardened less than $120^{\circ}C$ can not be applied to the highly acidic environmental plants because of its chemical resistance. In this study, new fluoric coatings that has excellent thermal resistance, chemical resistance and corrosion resistance has been developed in order to solve above problems and to be applied to the large plant structures in the field. These newly developed coatings are organic and inorganic composite type that have fluoric rubber(100 wt%), fluoric resin(5~50 wt%), oxalates(5~30 wt%), inorganic fillers mixed with plate-type and bulk-type solids(20~150 wt%), hardeners(0.5~5 wt%), and hardening hasteners(0.1~3 wt%). The best chemical and physical properties of these coatings are acquired by variation of adhesive reinforcement agents, dispersants, leveling agents. Mixing ratios of plate-type and bulk-type inorganic fillers influence the thermal properties, abrasive resistance and chemical infiltration properties of coatings. The mixing control is also very important to have homogeneous surface and removing inner voids of coatings.

Geochemical Evolution of Mixing Zone with Freshwater and Seawater near the Coast Area during Underground Space Construction (지하공간건설 시 해안인근 담수-해수 혼합대의 지화학적 진화)

  • Kim, Jiyeon;Kim, Byung-Woo;Kwon, Jang-Soon;Koh, Yong-Kwon
    • Journal of Soil and Groundwater Environment
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    • v.20 no.7
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    • pp.90-102
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    • 2015
  • To understand the hyrogeochemical variation of bedrock aquifer during underground space construction, various graphical methods including multiple-component plots and chemical trends were used to estimate the mixing rate between seawater and freshwater and to investigate the evolution of water quality. The water chemistry and mixing rate between fresh and sea waters, which are generally localized in the construction area (MW-7, in land), shows typical characteristics of freshwater that doesn’t affect its validity as seawater intrusion. Especially, the water chemistry of a MW-4 (coastline) was classified as Na-Cl type, Na-HCO3 type, and Ca-Cl type due to the influence of the seawater intrusion. And hydrogeochemical and isotopic data show that local freshwater is subjected to geochemical processes, such as reverse ion-exchange. Throughout the Chadha’s diagrams, four different case histories with the temporal and spatial variation of groundwaters in the study area were proposed, which is recommended to interpret the hydrogeochemical reactions effectively.

Eulerian Two-Phase Flow Analysis for Solid-Liquid Mixing in a Industrial Mixer (산업용 교반기의 고체-액체 혼합에 대한 Eulerian Two-Phase 유동해석)

  • Song, Ae-Kyung;Hur, Nahm-Keon;Won, Chan-Shik;Ahn, Ick-Jin
    • 유체기계공업학회:학술대회논문집
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    • 2006.08a
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    • pp.471-474
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    • 2006
  • The Mixer is apparatus that help precipitation or an inhomogeneous distribution of various phases to be mixed and that user makes necessary material mixing one or the other. Mainly the mixer which is used from chemical and food industry is very important system in engineering that mixes the material. The inside flow of the mixer under the actual states which put a basis in flow of the fluid is formed rotation of the impeller. The inside flow of impeller will be caused by various reasons change with shape of impeller, number of rotation, mixing material and flow pattern of free surface etc. Also mixer study depended in single-phase flow and experimental research. So the numerical analysis of flow mixing solid-fluid particle is simulated. It is become known, that the case where agitator inside working fluid includes the solid particle the sinkage reverse which the solid particle has decreases an agitation efficiency. From the research which it sees the hazard solid which examines the effect where the change of the sinkage territory which it follows agitation number of revolution and diameter of the particle goes mad to an agitator inside flow distribution - numerical analysis the inside flow distribution of liquid state with Eulerian Two-Phase Method.

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Extended Unmixing-Mixing Scheme for Prediction of 3D Behavior of Porous Composites (다공성 복합재료의 삼차원 거동 예측을 위한 분리-혼합 기법의 확장)

  • Choi, Hoi Kil;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.2
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    • pp.91-97
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    • 2013
  • Pyrolysis and surface recession of charring composites are progressed primarily in the thickness direction. The unmixing-mixing scheme is applied to describe the in-plane and through-thickness behaviors of porous composites. The extended unmixing-mixing equations are based on transverse isotropy of unidirectionally fiber-reinforced composites. The strain components of gas pressure in pores, thermal expansion, and chemical shrinkage are included in the constitutive model. By analyzing micromechanical representative volume elements of porous composites, the validity of the derived equations are examined.