• Title/Summary/Keyword: Chemical Method

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Universal Plasma-chemical Module for Carbon-containing Raw Materials Treatment

  • Park, Hyun-Seo;Zasypkin, I.M.
    • Resources Recycling
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    • v.13 no.1
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    • pp.59-67
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    • 2004
  • A universal plasma-chemical module (PChM) for the industrial processing of different hydrocarbon raw material pyrolysis was designed and tested. Laboratory investigations for the plasma-chemical method of acetylene production from natural gas and different coals were made. Similar laboratory tests on the industrial production of acetylene as a raw material for organic syn-thesis were developed using the PChM. A comparison of the suggested plasma-chemical method with the traditional process of acetylene production were carried out. The outlook of the plasma-chemical method was shown.

Effect of Stem Drying Method during Curing Process on Physico-chemical Properties in Bulk Cured Leaves (Bulk건조에서 주맥건조방법이 잎담배 이화학성에 미치는 영향)

  • 이철환;이병철;진정의
    • Journal of the Korean Society of Tobacco Science
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    • v.22 no.2
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    • pp.133-137
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    • 2000
  • The bulk curing experiment to improve the quality of flue-cured leaves were carried out to evaluate relationship between the modified(3 step-up) drying and conventional drying method in bulk curing process. Modified drying method was somewhat higher values in yellowing color index of cured leaves, and less brittle than those in conventional drying program. As to the chemical properties, there was no difference in chemical component levels in cured leaves between the modified and the conventional methods, while the major chemical compounds in relation to aromatic essential oil of cured leaves showed mostly higher level in the modified method than that in conventional drying method. Additionally 3 step-up drying method increased the tobacco quality by 2 % in price per kg compared with conventional drying method.

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A New Pseudoinverse Matrix Method For Balancing Chemical Equations And Their Stability (화학반응식 균형과 안정성을 위한 새로운 유사 역행렬법)

  • Risteski, Ice B.
    • Journal of the Korean Chemical Society
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    • v.52 no.3
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    • pp.223-238
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    • 2008
  • this work is given a new pseudoniverse matrix method for balancing chemical equations. Here offered method is founded on virtue of the solution of a Diophantine matrix equation by using of a Moore-Penrose pseudoinverse matrix. The method has been tested on several typical chemical equations and found to be very successful for the all equations in our extensive balancing research. This method, which works successfully without any limitations, also has the capability to determine the feasibility of a new chemical reaction, and if it is feasible, then it will balance the equation. Chemical equations treated here possess atoms with fractional oxidation numbers. Also, in the present work are introduced necessary and sufficient criteria for stability of chemical equations over stability of their extended matrices.

A Preconditioned Time Method for Efficient Calculation of Reactive Flow (예조건화 시간차분을 통한 화학반응유동의 효율적 계산)

  • Kim, Seong-Lyong;Jeung, In-Seuck;Choi, Jeong-Yeol
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.219-230
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    • 1999
  • The Equations of Chemical kinetics are very stiff, which forces the use of an implicit scheme. The problem of implicit scheme, however, is that the jacobian must be solved at each time step. In this paper, we examined the methodology that can be stable without full chemical jacobian, This method is derived by applying the different time steps to the chemical source term. And the lower triangular chemical jacobian is derived. This is called the preconditioned time differencing method and represents partial implicit method. We show that this method is more stable in chemical kinetics than the full implicit method and that this is more efficient in supersonic combustion problem than the full jacobian method with same accuracy.

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A Study on Hazard Identification Method for Small and Medium Chemical Industries (중·소 화학공장에 적합한 위험성 평가 기법 개발에 관한 연구)

  • Lee, Jae Min;Yoo, Jin Hwan;Ko, Jae Wook
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.103-108
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    • 2007
  • HAZOP analysis is a systematic method on the basis of the experts' experience and knowledge and is used for hazard identification and risk assessment by using brainstorming method. So, HAZOP analysis has been applied to major chemical industries efficiently. But it does not apply to small and midium chemical industries because of the insufficiency of the experts. Hence, in this study a new hazard identification method is proposed by modifying complexity and expertise of the HAZOP analysis and will be contributed to improve risk management for small and midium chemical industries.

Improvement of Histopathological Sample Preparation by Employing Microwave Heating Method on Frozen Section Specimens

  • Ahn, Seung-Ju
    • Biomedical Science Letters
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    • v.13 no.4
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    • pp.361-368
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    • 2007
  • Biological samples can be fixed either by chemical method by using chemical solution or physical methods by using heat treatment. The problem in traditional heat fixation is unsatisfactory quality due to uneven heat conduction in specimen and loss of inner cell contents. Chemical fixation method also bears several intrinsic problems like the limit in specimen size, time consumption in fixative impregnation, and loss of low molecular weight cell components. These factors deteriorate the quality of fixed specimen, thus limit the magnification and contrast of tissue pictures. Microwave heat has been reported to be a good alternative to current chemical methods to overcome these problem. In this study, we tried to introduce the microwave energy method to routine fixation work in hospital. We replaced chemical fixative with saline to provide moderate reaction condition, and used frozen section to reduce time for sample preparation. Temperature was measured at each experiment. The fixation of rat kidney tissue with 2.45 GHz electromagnetic wave and saline showed similar result to the control group fixed with traditional chemical method. Human tumor tissue fixed with 2.45 GHz electromagnetic in frozen section was improved in terms of histochemistry of PAS and immunohistochemistry of tumor marker like cytokeratin. Total turnaround time was reduced from $24\sim38$ h to to $2\sim4$ h. In conclusion, the quality of samples prepared by microwave heating method was at least as good as that of traditional method. If the condition for the fixation of different specimens is standardized, this new method could be applied to routine work in hospital, and could save working time as well.

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Rovibrational Energy Transitions and Coupled Chemical Reaction Modeling of H+H2 and He+H2 in DSMC

  • Kim, Jae Gang
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.3
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    • pp.347-359
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    • 2015
  • A method of describing the rovibrational energy transitions and coupled chemical reactions in the direct simulation Monte Carlo (DSMC) calculations is constructed for $H(^2S)+H_2(X^1{\Sigma}_g)$ and $He(^1S)+H_2(X^1{\Sigma}_g)$. First, the state-specific total cross sections for each rovibrational states are proposed to describe the state-resolved elastic collisions. The state-resolved method is constructed to describe the rotational-vibrational-translational (RVT) energy transitions and coupled chemical reactions by these state-specific total cross sections and the rovibrational state-to-state transition cross sections of bound-bound and bound-free transitions. The RVT energy transitions and coupled chemical reactions are calculated by the state-resolved method in various heat bath conditions without relying on a macroscopic properties and phenomenological models of the DSMC. In nonequilibrium heat bath calculations, the state-resolved method are validated with those of the master equation calculations and the existing shock-tube experimental data. In bound-free transitions, the parameters of the existing chemical reaction models of the DSMC are proposed through the calibrations in the thermochemical nonequilibrium conditions. When the bound-free transition component of the state-resolved method is replaced by the existing chemical reaction models, the same agreement can be obtained except total collision energy model.

A Quantitative Method of Measuring Color Expression Power in Eye shadow

  • Kim, Sangjune;Lee, Jaeuk;Kim, Hyungjin;Kim, Jinjun;Kang, Seh-hun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.233-238
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    • 2000
  • We developed a quantitative method for evaluating CEP(color expression power) in eye shadow. This method enables the cosmetic industry to measure CEP on an interval scales, so it is more accurate and reproducible than previous panel tests. Oil, colorants, Pigments and pearls are major factors affecting CEP in eye shadow formulas. We studied the oil effect on CEP using our unique method so CEP could be improved. We believe this method can be applied to other color cosmetics as well. In conclusion, we expected this method to be useful to formulator who want to improve the color expression power in color cosmetics. Additionally, we hope it will contribute toward developing the experiential know-how about color to scientific knowledge.

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An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part4: The Application of the JIS Rapid Test Method to the Several Domestic Reactive Aggregates) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제4보: 국내산 반응성 골재에 JIS 신속법 적용가능성))

  • 차태환;조원기;조일호;노재호;이양수;정재동;윤재환
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.447-450
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    • 1994
  • The chemical method and mortar-bar method for identification of the susceptibility to Alkali-Aggregate Reaction (AAR) was established as KS method by referencing the ASTM methods. However, the chemical method requires skilled chemical engineers and aggregates are tested in very severe condition, and on the other hand, the mortar-bar method needs a long time of 3 or 6 months. Judging from this circumstance that the use of crushed stones are increased due to the shortage of natural aggregates, the development and standardization of a new rapid test method is considered essential. The purpose of this paper is to research for the possibility to apply the rapid method, instead of the chemical method and the mortar-bar method with using the several domestic crushed stones.

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Establishment of Foliar Application Assays for Developing Natural Herbicides (천연물 제초제 개발을 위한 전식물체 수준의 경엽처리 검정법 확립)

  • Kim, Jae-Deog;Jang, Hyun-Woo;Seo, Bo-Ram;Hwang, Hyun-Jin;Choi, Jung-Sup;Kim, Jin-Seog
    • Korean Journal of Weed Science
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    • v.30 no.2
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    • pp.153-163
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    • 2010
  • This study was carried out to establish an improved bioassay system, whole-plant bioassay which is more effective in developing natural herbicides for foliar treatment such as herbicidal essential oils. Two bioassay systems using four weed species (Echinochloa crus-galli, Digitaria sanguinalis, Aeschynomene indica, and Abutilon theophrasti), spraying method and spotting method, were established. Spraying method is applicable if the amount of test compounds is enough, while spotting method is useful for the small amount of test compounds. The initial application rate was desirable at $2,500{\sim}5,000\;{\mu}g\;mL^{-1}$. Herbicidal activities were higher in the NOP treatment when compared to the Tween 20 treatment. To efficiently evaluate volatile compounds such as essential oils, if the compound-treated pots were incubated in dew chamber for about 10hrs, better results were obtained in the degree and stability of herbicidal responses. When the efficiency of bioassay systems established in this study was compared, the spraying method was minimized four times to the conventional method that has beed used for screening of synthetic compounds in KRICT. On the other hand, in the spotting method, screening for development of a natural herbicides was possible even in level of 1/100 test volume and 1/200 amounts of test compound compared to the spraying method.