• Title/Summary/Keyword: Chemical Industries

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Study on the Reaction Parameters in the Preparation of Black Titanium Oxide by the Reaction of TiO$_2$/Mg System (TiO$_2$/Mg 반응에 의한 흑색산화티타늄 제조시 반응 변수 연구)

  • Jeong, Jung-Chae;Jo, Jeong-Ung;Lee, Hyeok-Hui;Lee, Jong-Hyeon;Won, Chang-Hwan
    • Korean Journal of Materials Research
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    • v.11 no.10
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    • pp.851-858
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    • 2001
  • One of the important phase of black titanium oxide is $Ti_4O_7$ which has the excellent properties such as the greatest electrical conductivity among the titanium oxides, chemical resistance against acidic and alkalic conditions and electro-wave absorption etc., so it has been considered as a promising material to be used widely all over the parts of industries. In this study, $Ti_4O_7$ phase was successfully synthesized by the reaction of TiO$_2$/ Mg system. With the change of the mole of TiO$_2$to Mg, the most excellent blackness was appeared in the 3.5 mole which was the smaller amount than the stoichiometric 4.0 mole. In addition, we found that the blackness decreased as the mole ratio of reactent increased. With decreasing particle size of magnesium, blackness of titanium oxide increased. The reaction property was changed with the compaction pressure, and optimum pressure was found to be 10 MPa. At 55$0^{\circ}C$ of reduction temperature, the blackness increased as the reaction time increased. The blackness of synthesized black titanium oxide was 14 to 18, and the average particle size was 0.2 $\mu\textrm{m}$.

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A Study on the Optimum Evaluation Method for Tensile NOL Ring Specimen Manufactured by Filament Winding Process (Filament Winding에 의해 제조된 복합재료 NOL Ring시험편의 최적 인장강도 평가법에 관한 연구)

  • 김윤해;권술철;임철문
    • Composites Research
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    • v.14 no.2
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    • pp.8-12
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    • 2001
  • Filament Winding Process is a comparatively simple operation in which continuous reinforcements in the form of roving are wound over a rotating mandrel. It is well established and versatile method for storage tanks and pipes for the chemical and other industries. In this study, tensile strength of a filament wound ring specimens were evaluated by a split disk test fixture and a dress disk test fixture. The results obtained from experiments were compared with the theoretical values from the rule of mixtures. The purpose of this paper is the suggestion of an appropriate test method for the evaluation of tensile properties of filament wound structures. The tensile strength of a ring specimen tested by the dress disk test showed better agreement with the theoretical values than those tested by the split disk test because of higher stress concentration in edges of a split disk test fixture. The results showed that the tensile strength of a ring specimen was influenced by the geometry of test fixture, the continuity of fibers, fiber-tension, fiber-end and stress concentration in specimen.

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Recent R&D Trends of Solid Oxide Fuel Cell Power Generation System (고체산화물 연료전지 발전시스템의 최근 연구 개발 동향)

  • Pyo, Seong-Soo;Lim, Tak-Hyoung;Lee, Seung-Bok;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.119-130
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    • 2009
  • This article reviews recent R&D trends in SOFC development with an emphasis on industries that can produce the SOFC stack and power generation system. SOFC is an electrochemical device that can convert the chemical energy of fuel into the electrical energy with environment friendly system and high efficiency. SOFC power generation system could be classified as the portable power generation system, auxiliary power unit(APU), residential power generation(RPG) and large size distributed power generation. In the case of more than 10kW system, the major R&D trends are focused on the tubular type SOFC system with high efficient and long term stability to meet the commercialization of SOFC power generation system.

Ecological Risk Assessment based on Watershed System Assimilative Capacity in take Texoma, Texas-Oklahoma, USA (유역시스템 정화력을 고려한 생태위해성평가 사례연구: Lake Texoma Watershed (TX&OK, USA)를 대상으로)

  • An, Youn-Joo;Donald H. Kampbell;Guy W. Sewell
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.27-27
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    • 2003
  • Lake Texoma is located on the border of southern Oklahoma and northern Texas. It has 93,000 surface acres, and is a focus of the recreation, and farming industries in the region. There are potential stressors around the Lake Texoma watershed that may cause adverse ecological effects in the lake. System assimilative capacity (SAC) is the ability of abiotic and biotic processes to atteuniate the stressors. SAC Exceeded indicates potential of occuring adverse eco-effects. A number of representative chemical release sites and stressor sources in the surrounding watershed were characterized, and several impact sites having stressors sources, such as being near agriculture, landfills, housing areas, oil production fields and heavy use recreational activity, were selected for surface water, sediment, and groundwater monitoring. A paired reference site, having similar physical characteristics as its impact site, was also chosen based on its proximity to the impact site. Lake water samples were collected at locations identified as marina entrance, gasoline filling station, and boat dock at five marinas selected on Lake Texoma from September 1999 to December 2001. Paired water and sediment samples were also collected. Groundwater samples were collected at about 70 producing monitoring wells. Water quality parameters measured were inorganics (nitrate, nitrite, orthophosphate, ammonia, sulfate, and chloride), dissolved methane, total organic carbon (TOC) (or DOC), volatile organic compounds (VOCs) such as methyl tert-butyl ether (MTBE) and BTEX, and a suite of metals. Biotic communities were evaluated at impact and reference sites. Five basic components were measured; two terrestirial components (plants and bird comminitires) and three aquatic components (benthic inverbrates, litteral-zone fishes, ecosystem attribures). Potential impacts to these comminites were evaluated.

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Characteristics of Fish Bone as the Functional Food Additives Produced with Different Softening Methods (연화방법에 따른 기능성 식품 소재로써의 생선뼈의 특성)

  • Lee, Yoonmi;Choi, Jeong Wook;Hwang, Hye Jung;Lee, Min Kyeong;Jeong, Su Jin;Nam, Taek Jeong
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.52 no.6
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    • pp.631-636
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    • 2019
  • Fish bone-based calcium products are currently receiving much attention among high value-added industries involving calcium. Industrial processing of fish products yields unused fish parts including bones, which could be used as marine health foods to enhance the economic and environmental benefits of fish production. The ultimate goal of this study is to develop the high value-added fisheries products fortified with fish bones supplementing calcium. We here explored the physical and chemical softening methods of the fish bones to enhance texture of the fish products with a high degree of calcium absorption rates. The eluted calcium from the fish bone was quantified with the inductively coupled plasma optical emission spectrometry (ICP-OES). The characteristics of the softened fish bones were determined by the laser diffraction particle size analysis, texture profile analysis, and volatile organic compounds (VOCs) analysis. As the result, the optimized softening method of fish bone was established when Theragra chalcogramma bone was treated twice with the pressurized high temperature (110-120℃ and 1.0-1.5 kg/cm2). The produced softened fish bone turned out to be suitable for the food additives with low particle sizes, low hardness values, and negligible VOCs responsible for the unpleasant flavors.

A Study on Development of Automatic Path Tracking Algorithm for LNG Aluminium Plate and Selection of Process Parameters by Using Artificial Intelligence (LNG 알루미늄 판재 가공용 자동 궤적 추적 알고리즘 개발 및 인공지능을 이용한 공정조건 선정에 관한 연구)

  • 문형순;권봉재;정문영;신상룡
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.8
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    • pp.17-25
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    • 1998
  • Aluminum alloys have low density, relatively high strength and yield strength, good plasticity, good machinability, and high corrosion and acid resistance. Therefore, they are suitable for large containers for the food, chemical and other industries. Large containers are often bodies of revolution consisting of shell courses, stiffening rings, heads and other elements joined by annular welds. Larger containers have longer welds and require greater leak-tightness and higher weld mechanical properties. The LNG tank consists of aluminum plates with various sizes, so its construction should by divided by several sections. Moreover, each section has its own sub-section consisted of several aluminum plates. To guarantee the quality of huge LNG tank, therefore, the precise control of plate dimension should by urgently needed in conjunction with the appropriate selection of process parameters such as cutting speed, depth of cut, rotational speed and so on. In this paper, a manufacturing system was developed to implement automatic circular tracking in height direction and automatic circular interpolation in depth of cut direction. Also, the neural network based on the backpropagation algorithm was used to predict the cutting quality and motor load related with the life time of the developed system. It was revealed that the manufacturing system and the neural network could be effectively applied to the bevelling process and to predict the quality of machined area and the motor load.

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LCCO2 analysis of wood-containing printing paper by mixed ratio of de-inked pulp and BTMP (DIP 및 BTMP 혼합비율에 따른 인쇄용지의 LCCO2 분석)

  • Seo, Jin Ho;Kim, Hyoung Jin;Chung, Sung Hyun;Park, Kwang Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.2
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    • pp.46-55
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    • 2013
  • Recently, there are growing interests on carbon emissions related in climate change which is worldwide emerging important issue. Some research works are now carrying out in order to reduce the carbon emission in pulp and paper industries by the synthesis of precipitated calcium carbonate using the exhaust carbon dioxide from combustion furnace or incinerator. However, for solving the original problems on carbon emission, we need to consider the analysis of basic methodology on $CO_2$ through the process efficiencies. There are two general tools for carbon emissions; one is the greenhouse gas inventory and the other is $LCCO_2$ method which is applied to particular items of raw materials and utilities in unit process. In this study, the carbon emissions in wood-containing printing paper production line were calculated by using $LCCO_2$ method. The general materials and utilities for paper production, such as fibrous materials, chemical additives, electric power, steam, and industrial water were analyzed. As the results, $Na_2SiO_3$ showed the highest loads in carbon emissions, and the total amount of carbon emissions was the highest in electricity. In the production line of printing paper using de-inked pulp and BTMP, as the mixing ratio of DIP was higher, the carbon emissions were decreased because of high use of electric power in TMP process.

A Study on the Behavior in the Corner Crack Propagation of Al-Alloy used for the Shipbuilding by the Corrosion Fatigue (부식피로에 의한 선박용 알루미늄 합금제 용접부의 균열 전파기동에 관한 연구)

  • Im, U-Jo;Lee, Jin-Yeol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.24 no.4
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    • pp.164-171
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    • 1988
  • Recently with the rapid development in marine and shipbuilding industries such as marine structures, ships and chemical plants, it takes much interest in the study of corrosion fatigue characteristics that was close up an important role in mechanical design. In this study, characteristics of corner crack propagation on the base metal and heat affected zone of 5086 Al-Alloy was tested by using of a rotary bending fatigue tester and was investigated under the environments of specific resistance, $\rho$=25$\Omega$ cm and air. The corrosion fatigue crack initiation and corrosion fatigue life sensitivity were quantitatively inspected for 5086 Al-Alloy in the specific resistance, $\rho$=25$\Omega$ cm. Main results obtained are as follows: (1) The corrosion sensitivity of heat affected zone under specific resistance, $\rho$=25$\Omega$cm shows approximately 1.69~2.22 and corrosion sensitivity of base metal is more susceptible than that of heat affected zone. (2) The corrosion fatigue life sensitivity on heat affected zone decreases eminently than that of initial corrosion fatigue crack. (3) The characteristics of quarter elliptical corner crack propagation shows that depth crack is more grown than surface crack at crack initiation, but the surface crack is more propagated than depth crack as the crack propagation is increased. (4) The surface crack and depth crack growth on heat affected zone by softness show delayed phenomenon than that of base metal.

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Effects of Firm Characteristics on Qualification for Government R&D Supports (기업특성이 연구개발 정부지원 수혜에 미치는 영향)

  • Cho, Ka-Won
    • Journal of Technology Innovation
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    • v.18 no.1
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    • pp.99-121
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    • 2010
  • The goal of this paper is to analyze the effects of various firm characteristics on the probability for a firm to receive government’s financial supports for R&D. In the empirical analysis, a Probit model is estimated for the 2008 Korea Innovation Survey data. The main contribution of the paper is to investigate the distribution of R&D supports at the national level, instead of the program level. Especially, it is the first academic effort to evaluate the effects of regional and industrial variables. The results show that: (1) firm size and export increase the probability of receiving government’s R&D support; (2) variables measuring firms’ innovative ability, such as official designation as innovative firm, running R&D institute, number of R&D personnel, also have significantly positive effects; (3) firms in the chemical and automobile industries are more likely to receive R&D supports; and (4) firms in Teakyoung and Bukyoung regions are more likely to receive R&D supports.

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AFM Studies on the Surface Morphology of Sb-doped $SnO_2$ Thin Films Deposited by PECVD (AFM을 이용한 PECVD에 의해 증착된 Sb-doped $SnO_2$ 박막의 표면형상에 관한 연구)

  • Yun, Seok-Yeong;Kim, Geun-Su;Lee, Won-Jae;Kim, Gwang-Ho
    • Korean Journal of Materials Research
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    • v.10 no.8
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    • pp.525-531
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    • 2000
  • Sb-doped tin oxide films were deposited on Cornig glass 1737 substrate by plasma enhanced chemical vapor deposition (PECVD) technique. The films deposited at different reaction parameters were then examined by using XRD and AFM. The relatively good crystalline thin film was formed at $450^{\circ}C$, input gas ratio R[$P_{SbCl}P_{{SnCl}_4}$]=1.12 and r.f. power 30W. The surface roughness of the film formed by PECVD compared to TCVD was more smooth. Higher concentration of Sb dopant, lower deposition temperature, and thinner thickness of deposited film led to de-creasing surface roughness of the formed thin films.

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