• 접착 및 계면
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• 제12권1호
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• pp.34-42
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• 2011

자동차용 도장시스템으로 새롭게 대두되고 있는 roll coating process는 비친환경적이면서도 생산성이 떨어지는 기존의 습식도장공정을 완전 대체할 수 있는 기술로 알려져 있다. Pre-painted 강판 시스템에서 도막 유연성 및 강도 등의 구현을 위하여 경화거동뿐만 아니라 내식성 및 성형가공성, 유변학적 거동 등의 평가가 매우 중요하다. 본 연구에서는 pre-painted system에 적용하기 위하여 polyester 수지를 수산화기 및 분자량 변성을 통하여 합성한 후, 경화거동 및 딥드로잉, 인장력, 유변특성 등을 평가하였다. 40 (mg KOH-/mol)정도의 수산화기를 갖는 N-0375-40 system이 유연성 및 도막강도, 경화거동 등의 가장 우수한 물성을 나타내었다.

• 한국산업보건학회지
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• 제11권3호
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• pp.179-189
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• 2001

This study was performed to identify the current status of work environment management and to provide appropriate recommendations for small scale industry with less than 5 workers from September, 2000 to October, 2000 in Seoul city and Gyoung-gi province. The 211 companies were surveyed by checklist included the elements of management of work environment, hazardous chemicals, MSDS, personal protective equipment, and ventilation system. The proportion of metal products manufacturing and printing industries are 25.6 % and 22.3%, respectively. The daily working hours in printing industry is longer than others. The industries that produce potentially hazardous agents, such as noise, dust, metal, organic solvents, radiation and chemical material are pulp, plating, machinery, and printing, respectively. In above industries, only 2.8 % of those recognised and had MSDS. The proportion of companies providing fire extinguishers, safety showers are found to be 13.3 %, 7.1 %, respectively. Only 24.2 % of companies provided personal protective equipment to the workers. The ventilation system was operated in most of companies. But local exhaust ventilation system is provided to 22.3 % of those, also had not been annually inspected. This study showed that the current status of occupational safety and health was not appropriate for workers in small scale industries. It is suggested that annual physical examination have to be performed, MSDS usage must become widespread, and employer and emplyees in small scale industry should be educated for the treatment and storage of hazardous chemicals to improve the occupational safety and health of the working environment. also, regulatory standard has to be applied to local exhaust ventilation system in small scale industry to improve the working condition.

• 한국산업보건학회지
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• 제32권1호
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• pp.1-9
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• 2022

Objectives: The purpose of this study is to evaluate exposure characteristics of lead using data from the domestic occupational exposure literature. Methods: Occupational airborne exposure data on lead reported in the domestic literature from 1981 to 2018 were collected and re-analyzed. The exposure levels in the data were expressed as an estimated arithmetic mean and a weighted arithmetic mean (WAM) of the number of samples. Lead exposure characteristics were analyzed by industry, process, and year. Results: From a total of 14 documents, 8,305 airborne lead measurements for 17 industries were identified, and the WAM concentration in eight industries exceeded the occupational exposure limit of 50 ㎍/m³. Three industries (battery manufacturing, lead smelting, and litharge manufacturing) accounted for 95% of the total data, and exposure trends could be confirmed over 10 years. Exposure levels continue to decrease in all three industries. Conclusions: Considering the distribution outlook of lead and lead compounds, the main management targets are lead storage battery manufacturing and secondary smelting for lead regeneration.

• 대한환경공학회지
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• 제28권9호
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• pp.961-976
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• 2006

최근에 배출수를 고도 처리하여 재이용하는 기존의 방법에서 벗어나 공정 내에서 용수를 절약함과 동시에 생산 공정의 과학적이고 체계적인 분석을 통하여 용수의 이용률을 극대화한 후 최종 방류함으로써 물이용의 효율성을 높이고자 하는 용수재이용 기술이 많은 관심을 받고 있다. 이에 따라 제지, 석유화학 및 철강 산업 같이 용수를 많이 필요로 하는 용수 과소비 산업의 경우 공정수의 내부 재순환을 최적화 하여 유입되는 공업용수를 저감하는 동시에 재이용수의 사용으로 전체 용수 사용량을 줄이고 폐수의 방류량을 줄이고자 하는 워터핀치기술(water pinch technology)에 대한 관심이 높아지고 있다. 이 기법은 공정수의 재이용을 최적화 시켜 주는 방법을 사용하기 때문에 폐수의 방류량을 줄이면서 전 생산 공정을 대상으로 최적의 공정용수 재이용 라인을 구축할 수 있는 것으로 알려져 있다. 본 총설에서는 공정 설계 단계에서 병목을 찾아 재이용 최적화를 통해 용수 및 폐수 최소화하는 워터핀치 기술과 국내외 산업체에서 용수 재이용 네트워크 설계의 사례연구를 소개하고자 한다. 또한 최근 각광을 받는 에너지와 용수 재이용 네트워크의 동시 설계와 생태산업단지에서 기업간 용수 재이용 네트워크 설계 같은 최신 연구 동향을 소개한다.

• 한국환경보건학회지
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• 제36권5호
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• pp.391-401
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• 2010

A reduction in risk of occupational exposure to chemical hazards within the workplace has been the focus of attention both through industry initiatives and legislation. The aims of this study were to develop an exposure matrix by industry and process, and to apply this matrix to control the risk of occupational exposure to Dichloromethane (DCM). The exposure matrix is a tool to convert information on industry and process into information on occupational risk. The exposure matrix comprised industries and processes involving DCM, based on an exposure database provided by KOSHA (the Korean Occupational Safety and Health Agency), which was gathered from a workplace hazards evaluation program in Korea. The risk assessment of the exposure matrix was performed using Hallmark risk assessment tool. The results of the risk assessment were indicated by a Danger Value (DV) calculated from the combination of hazard rating (HR), duration of use rating (DUR), and risk probability rating (RPR) of exposure to the chemical, and were divided into four control bands which were related to control measures. The applicability of the risk assessment of the exposure matrix was evaluated by a field study, and survey of the employees of the exposure matrix groups. Among 45 industries examined, this study found that greater attention should be paid to two industries: the manufacture of other optical instruments and photographic equipment, and the manufacture of printing ink, and to one process among 47 examined, the packing process in the manufacture of printing ink, because these were regarded as carrying the highest risk. This tool of a risk assessment for the exposure matrix can be applied as a general exposure information system for hazard control, risk quantification, setting the occupational exposure limit, and hazard surveillance. The exposure matrix includes workforce data, and it provides information on the numbers of exposed workers in Korea by agent, occupation, and level of exposure and risk.

• 한국가스학회지
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• 제20권2호
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• pp.66-71
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• 2016

현재 산업단지에는 수많은 센서로부터 얻는 정보를 이용해 누출 발생지역을 감지 감시하고 있다. 그러나 화학물질 누출사고는 꾸준히 발생하고 있으며, 때에 따라 다량의 화학물질이 누출되는 경우에는 큰 피해가 발생하고 있다. 이때 중요하게 작용하는 센서 배치가 현재까지는 과거의 경험을 통하여 그 결정이 이루어지거나, 또는 센서제작 업체에서 제시하는 가이드를 통하여 설치되고 있다. 따라서 본 연구에서는 화학물질 누출이 일어났을 때 빠른 감지 및 대응을 위해 가장 중요한 요소인 센서 배치 최적화 방법론을 제시하였다. 특히 공정구조에 따른 누출흐름이 미반영된 상태에서 초기 배치 최적화를 위해 센서 개수 최소화 측면과 화학물질감지확률 측면으로 나누어 일반적으로 사용할 수 있는 수식을 제시하였다. 제시된 방법은 간단한 누출 시나리오를 이용하여 검증을 진행하였고, 이를 통해 각 공정의 안전성 목표치를 성취함으로써 안전한 공정 운영이 가능하도록 하였다.

• Korean Chemical Engineering Research
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• 제46권1호
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• pp.156-163
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• 2008

화학공장에서는 공정 이상, 장치 수명 및 경제적 환경 등에 의하여 변경이 발생하고 있다. 그리고 변경관리는 정확한 기술적 판단근거에 의한 변경 판정, 위험도 확인 및 위험성 평가 수행 등 근본적인 공정안전 기술을 바탕으로 이루어진다. 그러나 변경관리는 경험 부족, 지식 부족 및 기술인력 부족 등의 이유로 수행하기 매우 어려운 상황에 놓여있다. 본 연구에서는 화학공장 변경관리의 취약점을 파악하고 이를 적절히 보완하여 안전성을 향상할 수 있는 변경관리 체계를 구축하였다. 위험성 평가를 기반으로 하는 변경관리 절차의 정립 및 변경 여부 판단, 변경시 위험도 산정 등 변경관리 의사결정 단계들의 명확한 판단 기준 체계 정립을 통한 장치산업의 변경관리 수행 체계를 제안하였다. 이러한 안전공학 기술이 접목된 형태의 변경관리 절차를 제안하여 화학공장의 안전성 향상을 꾀하고자 하였다.

• Korean Chemical Engineering Research
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• 제60권1호
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• pp.70-79
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• 2022

Biodiesel production has attracted attention as a sustainable source of fuel and is a competitive alternate to diesel engines. The glycerol that is produced as a by-product is generally discarded as waste and can be converted to green chemicals such as acetins to increase bio-diesel profitability. Acetins find application in fuel, food, pharmaceutical and leather industries. Batch experiments and analysis have been previously conducted for synthesis of acetins using glycerol esterification reaction aided by sulfated metal oxide catalysts (SO₄^2-/CeO₂-ZrO₂). The aim of this study was to optimize process parameters: effects of mole ratio of reactants (glycerol and acetic acid), catalyst concentration and reaction temperature to maximize glycerol conversion/acetin selectivity. The optimum conditions for this reaction were determined using response surface methodology (RSM) designed as per a five-level-three-factor central composite design (CCD). Statistica software 10 was used to analyze the experimental data obtained. The optimized conditions obtained were molar ratio - 1:12, catalyst concentration - 6 wt.% and temperature -90 ℃. A packed bed reactor was fabricated and column studies were performed using the optimized conditions. The breakthrough curve was analyzed.

• KSBB Journal
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• 제26권4호
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• pp.267-276
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• 2011

There is a growing worldwide interest in the potential of marine biomass as an environmentally friendly and economically sustainable resource. Due to the great lack of comprehensive information about domestic seaweed resources, this study aimed to analyze the existing literature on the production and types of domestic seaweed species. Based on this data the possibilities of industrial use of domestic seaweed for the production of biofuels and bioplastics had been assessed. Our review took into account the seaweed species on domestic coasts as well as the species currently in great production via seaweed farming. Due to their wide distribution, their status as farmed crops, and the likelihood of securing their reliable supply, Codium fragile, Hizikia fuciformis, and Gelidium amansii were deemed to be the most appropriate candidates for domestic industrial use. The industrial potential of seaweed biomass was also explored by comparing the predicted amount of biomass necessary to replace current gasoline and plastics use with currently available farming space. The results of our study imply that once a steady and adequate supply of the proper kinds of seaweed can be secured through seaweed farming, there is a great potential for the development of new seaweed-based biofuels and bioplastics industries in Korea.

• 한국재료학회지
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• 제2권1호
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• pp.19-26
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• 1992

$WF_6$와 $SiH_4$의 화학반옹으로부터 산화규소막 위에 텅스텐 핵이 형성되는 현상을 실험을 통해 관찰하였다. 핵이 생성되는 속도는 반응온도가 높고 운반기체의 유량이 적으며 반응기내의 압력이 높을수록 큰 것으로 나타났다. 또한 반응기체가 흘러가는 방향에서 아랫쪽으로 위치하는 표면에 핵이 생성되는 속도가 큰 것으로 나타났다. 산화막위에 생성된 텅스텐 핵의 형상과 파단면을 주사현미경으로 관찰하였으며 산화막위에 형성된 텅스텐 박막의 화학적 조성을 밝혀내었다.