• 설비공학논문집
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• 제16권1호
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• pp.34-41
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• 2004

The chemical heat pump based on the Dehydration/Hydration process with a MgO/$H_2O$ system has been researched. The reactor bed could be expected to store the heat around 200∼37$0^{\circ}C$ by the dehydration reaction and to release the heat around 100∼16$0^{\circ}C$ by the hydration reaction under the heat amplification mode operation. The heat output rate of the heat pump system was evaluated using the experimentally determined parameters. The results show that 6∼50 W/kg of heat output and 0.5∼0.8 of heat recovery ratio are attainable. The heat pump will be applicable for a load leveling in a co-generation system by chemical storage of surplus heat at low heat demand and by supplying heat in the peak load period.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1993년도 추계학술발표회 초록집
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• pp.78-81
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• 1993

AN EXTENSIVE RESEARCH AND DEVELOPMENT WORK WILL BE CARRIED OUT FOR THE COMMERCIALIZATION OF THE CHEMICAL HEAT PUMP SYSTEM WHICH BASED ON THE ELF AQUITAINE FRANCE PATENTED AND KIME LICENSED SOLID/GAS CHEMICAL REACTION TECHNOLOGY. TOWARD ON THAT GOAL, THE BASIC AND ENGINEERING DETAILS SUCH AS IMPEX BLOCK MATERIAL, PHYSICO-CHEMICAL AND THERMO-CHEMICAL CHARACTERISTICS OF REACTION MECHANISMS IN THE SOLID/GAS CHEMICAL REACTION HEAT PUMP SYSTEMS. THREE KIND OF APPLICATION SYSTEM ARE NOW INVESTIGATED; AIR CONDITIONING, REFRIGERATOR AND INDUSTRIAL PROCESS HEATING AND COOLING SYSTEM.

• 한국수소및신에너지학회논문집
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• 제1권1호
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• pp.24-30
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• 1989

Prototype metal hydride chemical heat pump was constructed using $LaNi_{4.7}Al_{0.3}$ for high temperature hydride and $MmNi_{4.15}Fe_{0.65}Al_{0.2}$ for low temperature hydride, and the effects of operating conditions on the performace of heat pump were investigaed to find out the optimum operating condition. Operating variables considered in this work were cycling time, temperature of hot air blown to the high temperature reactor, the amount of hydrogen gas with which the system was charged initially, and the flow rate of air at both reactors. Power of heat pump increases monotonically as $T_h$ increases, and shows maxima at 4.8H/M and 15-25 min in $H_2$ charged and cycling time respectively. Power of heat pump increases as air flow rate increases at low flow rate, but saturates to some value confined by heat flow rate through the hydride bed, These all phenomena can be explained by the modified power equation.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1991년도 한국자동제어학술회의논문집(국내학술편); KOEX, Seoul; 22-24 Oct. 1991
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• pp.1085-1090
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• 1991

Chemical heat pump is a system to upgrade the low level energy such as industrial waste heat and solar energy by using coupled endothermic and exothermic chemical reactions. Dehydrogenation of 2-propanol can absorb heat near 80.deg. C and is transformed into acetone and hydrogen. Hydrogenation of acetone can liberate heat near 200.deg. C. Dehydrogenation of 2-propanol is difficult around 80.deg. C because .DELTA.G has positive value, but dehydrogenation reaction in liquid phase can overcome this problem because vaporized acetone and hydrogen can be rapidly eliminated. In this work, dehydrogenation of 2-propanol was investigated in liquid phase with Raney nickel catalyst. The energy efficiency of the chemical heat pump was estimated by computer simulation.

• 설비공학논문집
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• 제6권4호
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• pp.406-416
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• 1994

In this study the reactor design procedure and method of solid-solid-gas chemical heat pump system using STELF technology were investigated. For manufacturing IMPEX block which is the kernel of reactor, proper salt pair should be selected, and equilibrium temperature drop and COP should be examined for selected salt pair. Moreover, apparent density, residual porosity, and graphite ratio should be calculated to give minimum block volume and mass, and maximum energy density without causing heat and mass transfer problems. Since heat exchange area can be changed with operating condition, reactor diameter, length, and stainless steel thickness should be decided for desired specifications. These procedure and method were applied to the case study of 6kW cold production and 8 hours storage capacity reactor.

• 에너지공학
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• 제15권4호
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• pp.284-290
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• 2006

냉 난방 수요에서 일어나는 환경오염의 최소화와 화석연료 소비를 감소시키기 위해서 에너지 회수를 개선시키는 것은 필수적이다. 이러한 점에서 흡수식 열펌프기술은 에너지 절약을 위해서 많은 가능성을 가지고 있다. 흡수식 열펌프는 에너지를 주입하지 않고 폐열의 이용을 높일 수 있는 방법이다. 본 연구에서는 에너지 회수를 위한 재흡수 열펌프 연군를 메탄올-글리세린을 이용하여 수행하였다. 이 물질의 열역학 데이터를 이용하여 재흡수 열펌프의 이론적 열효율 값을 각 기관의 조업 조건에 따라서 계산하였다. $70{\sim}80^{\circ}C$의 산업 폐열 온도를 가지고 $40{\sim}50^{\circ}C$ 승온 시킬 때 열효율 값 0.4 이상을 얻을 수 있었다.

• 에너지공학
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• 제6권1호
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• pp.87-95
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• 1997

금속염화물과 암모니아간의 가역반응을 이용한 화학열펌프는 비프레온계 냉동 냉장시스템으로서 환경규약의 제한이 없고 가스, 전기 및 산업폐열 등 다양한 구동열원을 사용할수 있으며 축열에 의한 에너지 저장이나 산업공정에서의 대용량 에너지관리 시스템 등 응용분야가 다양한 장점을 갖고 있다. 통상 소규모의 실험실 장치에서 파일롯트 플랜트(pilot plant)로 전환하는 과정에서 시스템의 성능에 대한 해석이 필요하며 화학반응기의 거동에 대한 컴퓨터 모사도 필수적이다. 따라서 본 연구에서는 작동조건에 따라 화학식 냉동기 성능계수가 어떻게 변하는지를 예측하였고 반응기 모델링에 의한 동적모사를 수행하여 반응기의 온도거동, 작동조건에 따른 전화율 변화, 반응혼합물의 제조변수가 냉동기 성능에 미치는 영향 등을 고찰하였다.

• 한국산업융합학회 논문집
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• 제8권4호
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• pp.191-196
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• 2005

This study was carried out to investigate the heat storage/release characteristics of the thermochemical reaction of the calcined dolomite with the packed bed shape experimental apparatus for development of chemical heat pump system. In the present study, it was found that MgO of the calcined dolomite was not hydrated during the hydration process under the experimental conditions. Therefore, the MgO of the calcined dolomite can be regard as an inert material. As a result, it was found that all of CaO packed kept the reaction temperature of about $510^{\circ}C$ through the entire part of the bed. The dehydration reaction was incurred first at the wall side area as the supplied heat was transferred through the wall side into the packed bed. As a result of the temperature and concentration spread, the reaction was completed at the wall side progressed into the center.

• 설비공학논문집
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• 제17권12호
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• pp.1192-1203
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• 2005

A technical analysis was conducted to predict the development trend for heat pump system. The study was based on a submitted patent from 1983 to 2002 in Korea, U.S.A. and Japan. The total number of raw data from the registered database was 19,261 and the obtained data to be analyzed through the filtering process was 5,143. Technical development of compression type heat pump was more dominant than the other types, absorption, adsorption, and chemical heat pump. The patents for compression type made up over $80\%$ in each country, Most of patents were developed for the defrosting and controlling technology of the compression type heat pump system. Approximately $24\%\;and\;62\%$ of the patents about compression type heat pump were for defrosting and control technologies, respectively.

• 대한설비공학회지:설비저널
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• 제22권5호
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• pp.325-340
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• 1993