• Journal of the Korean Chemical Society
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• v.22 no.5
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• pp.334-339
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• 1978

The hydrolysis of ${\alpha}$-bromophenylacetamide in the acidic media has been studied. The reactions in sulfuric acid and p-toluenesulfonic acid afforded mainly mandelic acid ; on the other hand, in hydrochloric acid ${\alpha}$-chlorophenylacetic acid was the main product. In either case, it was difficult to obtain ${\alpha}$-bromophenylacetic acid without concomittant formation of mandelic acid and ${\alpha}$-chlorophenylacetic acid respectively from the hydrolysis of ${\alpha}$-bromophenylacetamide. Mandelic acid and ${\alpha}$-chlorophenylacetic acid were obtained in good yields (86, 95 %) in sulfuric and hydrochloric acid respectively; the reactions are therefore potentially useful processes for obtaining them.

• Journal of the Korean Chemical Society
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• v.57 no.2
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• pp.264-271
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• 2013

Corrosion inhibition of mild steel used in water station in 35 ppm aluminum sulfate and 10 ppm chloride solution by Camellia sinensis leaves extract was studied using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy techniques at $30^{\circ}C$. Results show that the inhibition efficiency increases with increasing concentration of the extract and decreases with increasing temperature. Inhibitive effect was afforded by adsorption of the extract's components which was found to accord with Langmuir adsorption isotherm. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency and was further corroborated by the values of activation parameters obtained from the experimental data.

• Journal of the Korean Professional Engineers Association
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• v.45 no.6
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• pp.28-32
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• 2012

Namhae chemical is one of the largest fertilizer manufacturing company in Korea which company has operating 4 unit agitator gear boxes and producing variety kinds of fertilizer production. The gearbox operating temperature of agitator is approximated in $55^{\circ}C{\sim}90^{\circ}C$ and required to keep operating continuous without stopping. The system required high performance oil and longer oil drain interval as limited workforce in maintenance team. It was lubricated by mineral gear oil of ISO VG 320 and also need to change to new oil frequently. Namhae Chemical would expect to keep stable operating condition without shut down and consider, lower cost of operation and equipment protection.

• Journal of Adhesion and Interface
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• v.8 no.1
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• pp.8-14
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• 2007

Poly(urethane-methyl methacrylate) hybrid emulsions can be controlled with their thermal, mechanical and anti-chemical properties as plastic coating materials. In this study, water dispersed poly(urethane-methyl methacrylate) hybrid emulsions were prepared by prepolymer synthesis and soap free emulsion polymerization. For imparting hydrophilicity on polyurethane prepolymer, 2,2-bis (hydroxymethyl) propionic acid was added to the polyurethane prepolymer with methyl methacrylate monomer and was neutralizated by triethylamine (TEA). After neutralization, the prepolymer mixture was dispersed in the water phase with stable droplets. The synthesis was carried out with chain extension from the ethylene diamine and initiation of methyl methacrylate by soap free emulsion polymerization. Stable poly(urethane-methyl methacrylate) hybrid emulsion was successfully obtained with different synthetic conditions and acrylic monomer contents. Poly(urethane-methyl methacrylate) hybrid emulsion were characterized and compared with tensile strength, viscosity, and adhesion properties.

• Journal of Environmental Health Sciences
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• v.43 no.5
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• pp.360-369
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• 2017

Objectives: The organizational culture of small-scale enterprises is influenced by a lack of awareness of industrial accidents and a business-oriented culture. Therefore, the purpose of this study is to establish a correlation between chemical awareness and worker safety, which is the reason why a company's safety environment is responsible for human factor accidents. Methods: The research model established the organizational culture, human relationships, organizational relationships, workplace culture, safety climate, and safety parameters, all of which affect the perception of chemical substances, then established safety rankings, communication, safety regulations, and safety support. Results: In order to derive the results of this study, the satisfaction level was mostly derived from the degree of engagement (+) depending on the number of years worked, in the hierarchical regression analysis. During work with chemicals, the number of years spent on the level of the service was determined by the influence of the chemical (-). Based on this company, the occurrence of chemical accidents caused by chemical materials was felt to be felt at the risk of causing the hazard to be felt, the absence of physical damage was excluded from the variables. The other variables detected in the variables were $62.8{\pm}24.4$. Conclusion: As a result, it is necessary to develop a statistical model for the verification of the hierarchical regression analysis, and the relationship between safety and awareness of the dangers of chemicals and biological agents requires periodic safety training. Job satisfaction was found to be higher if the level of awareness was sufficient.

• The tire
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• s.96
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• pp.21-29
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• 1981

현재 미국에서는 카본블랙 시장에 영향을 주는 많은 변화가 일어나고 있다. 즉, 카본블랙의 원료유 가격인상, 종류별 사용량의 변화, 가격인상 압력 등, 이 모든 요인들이 앞으로의 카본블랙 공업의 방향을 결정하게 될 것이다.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.490-498
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• 2010

The optimum mold design and the optimum process condition were constructed upon executing process simulation of rubber injection molding with the commercial CAE program of MOLDFLOW(Ver. 5.2) in order to solve the process-problems of K company relating to air-traps and short-shots. The former occurs at the cavity edge of torque-rod-bush and the latter takes place for the injection molding of dynamic dampers. As a result the process problem relating to air traps was solved by optimizing edge-angle and the number of gates to prevent the flow congestion of flow-front and to make the flow-front movement unaffected by congestion. For dynamic dampers of K company the unmolded flaw caused by their unfilled cavity was corrected by installing the air-vent at the confronting locations of both upstream and downstream of flow-front where air traps frequently occur. Besides the unmolded flaws were rectified by altering the position of gate from the upper to the middle or by increasing the number of gates. Thus the process problems of K company relating to air-traps and short-shots of torque-rod-bush and dynamic dampers, respectively, were solved by proper altering of mold design with process simulation of rubber injection molding.

• Tribology and Lubricants
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• v.30 no.6
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• pp.343-349
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• 2014

Currently, in order to resist the scratching of the fuel rod surface while fabricating the fuel assembly of the light-water nuclear reactor, we use a solution of nitrocellulose, an explosive material, as a dry lubricant along with its solvent. However, the demand for developing safe and harmless aqueous alternative materials for environment-conservation and field-worker safety has increased. In this study, we demonstrate the preparation of a novel aqueous resin composite using a formulation of aqueous polymeric resin, alcoholic solvent, and water. Subsequently, we characterize this composite on the basis of hardness, adhesive property, and water solubility using plates similar to the fuel rod material. The insertion test of a fuel rod coated with the YS-3 composite shows load values of $18.8-20.5kg/cm^2$, which is comparable with $18.8-20.5kg/cm^2$ of the nitrocellulose coating agent. In addition, the depth and width of longitudinal scratches caused by the YS-3 composite test are 50% higher than those of the standard. We can develop a harmless and safe aqueous dry lubricant to replace the existing NC products through field testing of 264 pieces of fuel rods, after producing 350 kg of the YS-3 prototype. The scratch test for the rod surface showed that weight of chip of YS-3 prototype was smaller than that of NC before and after solvent treatment, indicating the properties of YS-3 prototype was comparable to the counterpart.

• Journal of Pharmaceutical Investigation
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• v.26 no.4
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• pp.315-321
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• 1996

It has been indicated that problems associated with insulin iontophoresis are low bioavailability, slow absorption rate and the use of high dosage. Pretreatment of skin as a method of solving these problems was used in alloxan-induced diabetic white rabbits. Skins were treated with skin needle, electric razor, knife razor and scotch tape. Transport data shows that insulin delivery was enhanced significantly by the treatment which disrupt the barrier properties of stratum corneum. The data also shows that insulin absorption lasted for several hours after the cessation of iontophoresis. The degree of skin treatment was estimated by measuring the electrical resistance of skin. When the skins were treated with skin needle and electric razor, the standard deviations of resistance were small, which suggests the possibility of uniform delivery of insulin. The dermal responses after the invasive delivery were evaluated in accordance with OECD Guideline. It seems that electrical resistance of the skin correlate well with the dermal irritation.

• Korean Journal of Occupational Health Nursing
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• v.21 no.3
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• pp.192-200
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• 2012

Purpose: The purpose of this study aimed to investigate job stress levels of occupational health managers and whether job stress levels were affected by various factors such as size and types of company and work-related characteristics of occupational health managers. Methods: The study was conducted from May to September 2011 in the chemicals manufacturing factories in Korea and total subjects were 59 occupational health managers. We measured job stress levels of occupational health managers using Korean occupational stress scale (KOSS) questionnaires and the information of company characteristics was obtained using a self-reported questionnaire. Results: The characteristics of company such as type, size and industries and job characteristics of occupational health managers were significant factors in job stress. Job demand, job control, job insecurity, organizational system and occupational environment scores were significantly associated with type, size and industries of company. In multiple regression analyses, we found that job demand was significantly associated with occupational position and type of company, and job insecurity was significantly associated with working hour. Also, we found that lack of reward was significantly associated with education level, speciality, duration of work and hour and type of company. Conclusion: These results indicate that job stress of occupational health managers is significantly associated with work-related characteristics and company's characteristics.