• Title/Summary/Keyword: Chemical Change

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Effect of Interconnect Structure on the Cell Performance in Anode-supported Tubular SOFC Using Three-dimensional Simulation (3차원 수치모사를 통한 연료극 지지식 관형 고체산화물 연료전지의 전지 성능에 대한 연결재 구조 효과)

  • Hwang, Ji-Won;Lee, Jeong-Yong;Jo, Dong-Hyun;Jung, Hyun-Wook;Kim, Sung-Hyun
    • Clean Technology
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    • v.16 no.4
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    • pp.297-303
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    • 2010
  • Effect of interconnect structure on the cell performance in anode-supported tubular solid oxide fuel cell (SOFC) has been investigated in this study, employing the Fluent CFD solver. For the robust and reliable theoretical analysis corroborating experimental results, it is of great importance to elucidate the role of interconnect which is electrically connected with electrodes on the cell characteristics. From the fact that the thin interconnect provides the enhanced cell performance, it is revealed that the interconnect thickness is a key parameter that is able to effectively control the ohmic resistance. Under the constant thickness condition, the cell performance does not considerably change with the variation of interconnect width. This is because the current passage along with circumferential direction is not effectively altered by the change of interconnect width in tubular SOFC system.

Identification of College Students' Understanding of the Thermodynamic Aspects Regarding the Dissolution of Solids and Gases (고체와 기체의 용해에 대한 대학생들의 열역학적 이해 조사)

  • Park, Jong-Yoon;Lee, Yun-Hee
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.186-196
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    • 2008
  • purpose of this study was to investigate college students' understanding of the thermodynamic aspects of the dissolution of solids and gases. The subjects were 34 juniors from the Seoul area who answered questionnaires composed of six items which asked the directions and reasons for the changes in enthalpy, entropy, and the solubility by temperature for the dissolution of solid sodium chloride and gaseous carbon dioxide into water. The results showed that the students understanding of the enthalpy change of dissolution was poor: many students answered that the dissolution of solids is an exothermic process because the dissolution occurs when the solute-solvent interaction is greater than the solute-solute interaction; the students also thought that the enthalpy should be reduced for spontaneous dissolution because the spontaneity depends on the enthalpy change only. For the entropy change, the students understanding was better and they explained it according to the meaning of disorder. For the temperature dependence of solubility, most students answered correctly regarding the direction, but only 25% of them explained the reason accounting for the enthalpy change. Many students who answered incorrectly on the enthalpy change could not explain the reason why.

Physical and Morphological Characteristics Change of Hair according to Water Content when Heat Permanent Wave is treated (열펌 시술시 수분함량에 따른 모발의 물리적·형태학적 특성 변화)

  • Lee, Soon-Hee;Kim, Sung-Nam
    • Fashion & Textile Research Journal
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    • v.10 no.3
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    • pp.389-393
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    • 2008
  • The purpose of this study is to provide beauticians with the fundamental material for them to use effectively heat permanent wave and satisfy their customers. It carried out an experiment with hair of a woman in her late twenties to investigate the change of physical and morphologic characteristics by its water content when performing heat permanent wave. It evaluated the water content as 0g, 1g, 2g, 3g and 4g respectively when performing the heat permanent wave on hair, then it compared and observed the wave type, tensile strength and elongation for its physical change also observed the morphologic change by scanning electronic microscope and transmission electronic microscope. The result of experiment on the physical specificity revealed that the wave was the most ideal when the water content was 2 g. The material with much water content made wave but the result was not satisfied. In the case of hair with water content of nearly 0g didn't make wave. In terms of tensile strength and elongation, the tensile strength was generally reduced as hair was damaged, on the contrary, the elongation was increased. It observed the change of morphologic characteristic and got the result that the damage on hair cuticle was deepen as its water content was decreased. It also showed the result that damage happened on hair cuticle more than hair cortex with the observation of fine structure on hair section by transmission electronic microscope. Generally chemical treatment damaged hair. Under consideration of this aspect, the ultimate goal of this thesis is to minimize the damage of hair caused by chemical treatment and get the satisfaction on the hair style. The result of experiment presented that the hair showed the best result when its water content was 2 g.

The Solvolysis of Benzoyl Chloride in Water-Acetone Mixtures Under High Pressure

  • Jee, Jong-Gi;Ree, Taik-Yue
    • Bulletin of the Korean Chemical Society
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    • v.8 no.1
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    • pp.31-39
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    • 1987
  • By using a complete rate constant($k_e$) which treats a solvent (water) as a reactant, and a conventional rate constant($k_c$), which ignores the solvent in describing the rate, the parameters ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were introduced. These quantities represent the volume change, the enthalpy change, and the entropy change accompanying the electrostriction which occurs when solvent molecules condense on the activated complex. The authors measured the rates of the solvolysis of benzoyl chloride in water-acetone mixtures at $15^{\circ}$ to $30^{\circ}C$ and 1 bar to 2500 bars. Applying the authors' theory to the experimental results, the parameters, ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were evaluated, and it was found that they are all negative, indicating that water dipoles condense on the activated complex. They also proposed the following equations: ${\Delta}H^{\neq}_c\;=\;{\Delta}H^{\neq}_e\;+\;{\Delta}H^{\neq}_s\;and\; {\Delta}S^{\neq}_c\;=\;{\Delta}S^{\neq}_e\;+{\Delta}S^{\neq}_s\;,\;where\;{\Delta}H^{\neq}_c\;and\;{\Delta}H^{\neq}_c\;and\;{\Delta}S^{\neq}_s $are the activation enthalpy change and the activation entropy change for the conventional reaction rate, respectively, and ${\Delta}H^{\neq}_e$ and ${\Delta}S^{\neq}_e$ are the corresponding quantities for the complete reaction rate. The authors proposed that for the $SN_1$ type, all the quantities, ${\Delta}V^{\neq}_s,\;{\Delta}S^{\neq}_s\;,{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ are comparatively large, and for the $SN_2$ type, these quantities are smaller than for the $SN_1$ type, and occasionally the case ${\Delta}S^{\neq}_e$ < 0 occurs. Using these criteria, the authors concluded that at high temperature, high pressure and for a high water content solvent, the SN_1$ type mechanism predominates whereas in the reversed case the $SN_2$M type predominates.

A Study on Effect of Individual Education about Chemical Therapy for Preventing Cancer on Quality of Life of Patient Who Suffers From Cancer (항암화학요법에 관한 개별교육이 암 환자의 삶의 질에 미치는 효과)

  • Choo, Yeun-Hwa;Kim, Kyung-Hee
    • Asian Oncology Nursing
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    • v.4 no.2
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    • pp.103-109
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    • 2004
  • The disease occurrence rate of the cancer is rapidly increased and It is becoming the main factor for the death The chemical therapy for preventing the cancer is recently used for many patients and thus extended the life of the patients. However, the side effect caused by the medical substances when performing the chemical therapy for preventing the cancer and the consequent mental and social problem are incurred to deteriorate the quality of the life. Therefore, it is needed to help the patient In order to reduce the above problems, and so this study was executed in order to examine the effect of the individual education on the quality of the life of the patients who are treated by the chemical therapy for preventing the cancer. The study was performed from Jan. 19. 2004 to Apr. 18. 2004 for the patients who were firstly treated by the chemical therapy for preventing the cancer in a university hospital located in the downtown in Seoul. The individual education on the chemical therapy for preventing the cancer was provided to 40 patients of the experimental group. The study plan is the experimental plan before and after the sole group, and it is the beginning experimental plan. The title of the booklet on the chemical therapy for preventing the cancer is "Cancer, The more you know, the more you can be cured", and the book was composed up of the side effect of the chemical therapy for preventing the cancer, treatment way for the side effect, and guide of the daily life. The survey with the questionnaire sheet was distributed to the experi- mental group before the education, the survey sheet was made out when they were hospitalized for 3-4 weeks after the education, and the data were examined by using SPSS statistical program with making our the survey questionnaires and the change of the quality of the life before and after the education of the patients who are treated by the chemical therapy for preventing the cancer was analyzed by using the parred t-test. The research result was verified that it has the meaningful that the quality of the life for the physical field, mental field, social field, and spiritual field after the individual education. The suggestion concluded by the above research result is as follows. First, there is the limitation to interpret the result since it was the beginning experimental plan for the sole group. Thus, it is suggested that the similar experimental plan should be executed with the expansion of the research subject and also with the contrast group. Second, it is suggested that the study on the change of the quality of the lifeaccording to the support of the individual education and family of the patients who are treated by the anti-cancer therapy.

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Fabrication of Chemical Sensors for the Detection of Acidic Gas using 1,3-bisdicyanovinylindane (1,3-bisdicyanovinylindane을 이용한 산성가스 감지용 화학 센서 제작)

  • Song, Hwan-Moon;Park, Young-Min;Son, Young-A;Lee, Chang-Soo
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.184-188
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    • 2008
  • This study presented simple and efficient fabrication of chemical sensors for the detection of acidic gas using 1,3-bisdicyanovinylindane as an indicator because it can be promising materials having property of the rapid color change according to the variation of pH. The dissociation of proton and dye in acidic condition as changing of ion pairs give rise to dramatically change the absorbance intensity of 1,3-bisdicyanovinylindane, which can be easily applied to the development of chemical sensors. In addition, indicator dyes having negatively charge in aqueous phase can be easily fabricated using layer-by-layer (LBL) methods by way of electrostatic interaction. For the proof of concept, we demonstrated the abrupt presentation of skeleton symbol on the chemical sensor, which could be resulted from the reaction of 1,3-bisdicyanovinylindane as background color with acidic gas. Thus, the rapid appearance of symbol will induce user's caution under the emergency condition. The presented chemical gas sensor using 1,3-bisdicyanovinylindane have strong advantages. First, the fabrication process of gas sensor was very simple and low-cost. Secondly, sensors reacted by acidic gas could be reused for several times. Finally, the chemical gas sensor would be environmentally friend, which can be a basic tool for the realization of eco-organic sensor device.

Physical and Chemical Properties of Waste LCD Glass as Raw Materials for the Production of Foamglass (발포유리 제조원료로서 폐 LCD유리의 물리화학적 특성)

  • Lee, Chul-Tae;Lee, Jinsoo;Jang, Moonho;Lee, Sunyoung
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.266-272
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    • 2009
  • Physical and chemical properties of waste LCD glass were investigated to test the feasibility of feed materials for the production of foamed glass. For this study, chemical analysis, thermal analysis, rheological consideration with the viscosity change under high temperature and thermal expansion coefficient were carried out and the trial production of foamed glass as; in spherical and block type also attempted. All results showed waste LCD glass would be a good feed material for the production of foamed glass and foaming technology of LCD glass would be an effective recycling alternative.