• Bulletin of the Korean Chemical Society
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• v.28 no.2
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• pp.173-174
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• 2007

• Journal of the Korean Chemical Society
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• v.11 no.2
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• pp.56-59
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• 1967

Mixtures of amines can be separated by elution chromatography on a chelating resin, Dowex A-1 loaded with nickel ions based on ligand exchange. Aqueous ammonia is used as the eluent. The method has proved particulary effective for separating aromatic amines.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.2
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• pp.69-72
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• 2021

The reaction of ammonium ferric sulfate with sodium borohydride in laponite sol yields nanoiron colloidal solution. This solution in air forms transparent yellow brown solution. The resulting solution reacts with bidentate chelating ligands. The reaction products are characterized by UV-Vis absorption spectroscopy and X-ray diffraction. All compounds show metal to ligand charge transfer band in the region of 400~650 nm in UV-Vis absorption spectra. This indicates the formation of iron-ligand complex by air oxidation of nanoiron. Also, XRD patterns exhibit that the iron-ligand complex is intercalated in the interlayer of laponite.

• Resources Recycling
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• v.28 no.3
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• pp.35-44
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• 2019

In this study, we conducted experiments to store $CO_2$ and produce $CaCO_3$ through indirect carbonation using paper sludge ash (PSA) and three chelating reagents (fumarate, IDA and EDTA). Fumarate and IDA used as solvents could facilitate the indirect carbonation reaction to store more $CO_2$ than water. When 0.1 M fumarate and IDA were used, $CO_2$ storage was 63 and $89kg-CO_2/ton-PSA$, respectively, and $CaCO_3$ yield was 144 and $202kg-CaCO_3/ton-PSA$. For the case of EDTA, however, the carbonation was hardly progressed. As either the concentration or Ca-ligand stabilization constant of each chelating reagent increased, the calcium extraction efficiency from PSA increased. In addition, the carbonation efficiency was influenced by the Ca-ligand stabilization constant. As the Ca-ligand stabilization constant increased, more calcium could be extracted from the PSA. With the constant larger than that of $CaCO_3$ ($10^{8.35}$), however, the carbonation reaction was not proceeded.

• Bulletin of the Korean Chemical Society
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• v.18 no.4
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• pp.406-409
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• 1997

The various cobalt(Ⅱ) complexes were synthesized and characterized using tris-(2-benzimidazolylmethyl)amine (ntb) as a ligand where the ntb plays as a tripodal tetradentate ligand to form complexes with a trigonal pyramidal geometry. The complexes have 5 and 6 coordinate cobalt(Ⅱ) ions depending on the additional ligand used. In each complex the additional ligand, chloride anion, or acetate anion occupies the "open" site trans to the apical tertiary nitrogen atom of ntb ligand. Complex 1, [Co(Ⅱ)(ntb)Cl]Cl has a trigonal bipyramidal geometry. This geometry was easily constructed using ntb as a tetradentate ligand and chloride as a monodentate ligand. The complex is isostructural to the corresponding manganese(Ⅱ) complex. Crystal data are as follows: [Co(Ⅱ)(ntb)Cl]Cl·MeOH, 1. triclinic space group P1; a=13.524(2) Å, b=14.037(2) Å, c=17.275(1) Å; α=78.798(9), β=84.159(8)°, γ=65.504(9)°; V=2929.6(6) Å3; Z=4; R1=0.0715, wR2=0.1461 for reflections of I > 2σ(I). Six coordinate complex 2 [Co(ntb)(OAc)](OAc) was synthesized using ntb as a tetradentate ligand and acetate as a bidentate chelating ligand.

• Journal of Environmental Health Sciences
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• v.18 no.2
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• pp.106-116
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• 1992

In order to examine the influences of diluent, DVB, and ligand content, in the adsorption velocities and capacities of chelating resins to heaw metal ions, the chelating resins containing the PO$_3$H, amide, and PO$_3$H+amide were prepared from AN-STR-DVB copolymer. The adsorption capacities of chelating resins were measured by ICP-AES. The major results of the studies are as follows: The optimized compositions of the chelating resins having the highest adsorptivity for the heavy metal ions were found to be DVB=7 wt%, toluene= 100 vol%. The adsorption rate of the chelating resins to the heaw metal ions was PO$_3$H > PO$_3$H+Amide > Amide in order.

• Bulletin of the Korean Chemical Society
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• v.27 no.3
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• pp.359-360
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• 2006

• Proceedings of the Korean Fiber Society Conference
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• 1993.06b
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• pp.90-94
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• 1993

• Proceedings of the Membrane Society of Korea Conference
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• 2004.03a
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• pp.37-59
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• 2004

Advantages : - Multi-functionality of inorganic surface ㆍMetal chelating ligand $\longrightarrow$ metal recovery .Alkylation $\longrightarrow$ hydrophobicity control - Enhanced stability ㆍThermal, mechanical and chemical stability ㆍSeparation in high temperature and pressure (omitted)

• Journal of the Korean Applied Science and Technology
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• v.16 no.2
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• pp.143-146
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• 1999

In order to study for Onion ethanolic extract on the Heavy Metal Elimination and antioxidation, the peroxide values of oil and eliminated metal were analyzed. The results are follows: It was very effective as a retardant for autoxidation processing of the soybean and olive oil by the Onion ethanolic extract. Quercetin in the Onion ethanolic extract was affected as a ligand for chelating with some metals. Through out this study, Quercetin in the Onion ethanolic extract was affected as eliminator of the Mercury, Lead, and Cadmium.Abstracts In order to study for Onion ethanolic extract on the Heavy Metal Elimination and antioxidation, the peroxide values of oil and eliminated metal were analyzed. The results are follows: It was very effective as a retardant for autoxidation processing of the soybean and olive oil by the Onion ethanolic extract. Quercetin in the Onion ethanolic extract was affected as a ligand for chelating with some metals. Through out this study, quercetin in the Onion ethanolic extract was affected as eliminator of the mercury, lead, and cadmium.