• Title/Summary/Keyword: Charring

Search Result 45, Processing Time 0.021 seconds

Extended Unmixing-Mixing Scheme for Prediction of 3D Behavior of Porous Composites (다공성 복합재료의 삼차원 거동 예측을 위한 분리-혼합 기법의 확장)

  • Choi, Hoi Kil;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.41 no.2
    • /
    • pp.91-97
    • /
    • 2013
  • Pyrolysis and surface recession of charring composites are progressed primarily in the thickness direction. The unmixing-mixing scheme is applied to describe the in-plane and through-thickness behaviors of porous composites. The extended unmixing-mixing equations are based on transverse isotropy of unidirectionally fiber-reinforced composites. The strain components of gas pressure in pores, thermal expansion, and chemical shrinkage are included in the constitutive model. By analyzing micromechanical representative volume elements of porous composites, the validity of the derived equations are examined.

Matrix Modification for Graphite Furnace Atomic Absorption Spectrophotometric Determination of Volatile Elements(III) Trace Bismuth

  • Kim, Young-Sang;Choi, Jong-Moon;Kim, Young-Man
    • Analytical Science and Technology
    • /
    • v.8 no.4
    • /
    • pp.435-442
    • /
    • 1995
  • A matrix modification was studied for the determination of trace bismuth in water samples by graphite furnace atomic absorption spectrophotometry. The type and quantity of modifiers as well as the use of auxiliary modifiers were investigated to realize the efficient modification. Palladium was chosen as a single modifier. By the addition of palladium($5{\mu}g/mL$) to 100 ng/mL bismuth solution, the temperatures could be raised from $500^{\circ}C$ to $1,300^{\circ}C$ for the charring and from $2,000^{\circ}C$ to $2,200^{\circ}C$ for the atomization as well as the sensitivity and reproducibility were improved. The absorbance of bismuth was maximum and not changed in the range of Pd $3-25{\mu}g/mL$. And several materials were examined as an auxiliary modifier. The mixed solution of $1{\mu}g/mL$ palladium and $200{\mu}g/mL$ nickel have raised the temperatures as with $5{\mu}g/mL$ palladium only. The maximum absorbance of bismuth was shown in the nickel concentration range of $100-300{\mu}g/mL$ in $1{\mu}g/mL$ palladium modified system. With such optimum conditions, the trace amount of bismuth in several water samples could be determined by a calibration curve method, and good recoveries were also obtained.

  • PDF

Developments of Fire-Resistant Wooden Structural Components and Those Applications to Mid- to High-Rise Buildings in Japan

  • Hanai, Atsunari;Nakai, Masayoshi;Matsuzaki, Hiroyuki;Ohashi, Hirokazu
    • International Journal of High-Rise Buildings
    • /
    • v.9 no.3
    • /
    • pp.221-233
    • /
    • 2020
  • Based on past experiences of natural disasters and fires in Japan, it is stipulated by law that fire-resistant buildings larger than a certain size should be unique in the world. Recent interest in global environmental issues has led to the active introduction of wooden buildings also in Japan, and it is expected that wooden buildings will become larger and higher in size. This paper introduces the background of the development of fire-resistant laminated timber with a "Self-Charring-Stop layer", the contents of this development including other related developments, and the application of these technologies. In addition, towards the realization of much larger and higher buildings in the future, the current problems and issues to be solved are set and the necessity of the future technological development is described. Finally, a conceptual model of wooden high-rise building is proposed, which will be able to be constructed in 2025 by the further technological development.

A Study on the Characteristics of Fire Resistance of Window Material in Compartment Fire (건물화재시 창문재료에 따른 내화특성 연구)

  • Hur, Man-Sung;Jang, Moon-Seok;Cho, Soo
    • Fire Science and Engineering
    • /
    • v.17 no.1
    • /
    • pp.62-67
    • /
    • 2003
  • The full-scale compartment fire tests were carried out to evaluate the characteristics of fire resistance of window material under actual fire conditions. The room size used for full-scale room fire tests was 4 by 3.8 m with 2.4 m high ceiling. The windows with PVC, Aluminum and AL+Wood frame materials were established, sofa and mattress were used as fire sources. The window contained pair glasses with the air between 6 mm glasses. Temperatures at total 32 points in the room were measured to find the temperature distribution in the room fire. It is examined that thermal effects on window frame materials such as charring, distortion, melting, structural collapse, and other effects.

Matrix Modification for Electrothermal Atomic Absorption Spectrophotometric Determination of Trace Manganese in Seaweeds (해조류중 흔적량 망간의 전열원자흡수 분광광도법 정량을 위한 매트릭스 개선에 관한 연구)

  • 최종문;강동수
    • Journal of Environmental Health Sciences
    • /
    • v.26 no.4
    • /
    • pp.75-81
    • /
    • 2000
  • A matrix modification was studied for the determination of trace manganese in several seaweeds by electrothermal atomic absorption spectrophotometry(ETAAS). The type and quantity of modifiers were investigated to realize the efficient modification. Palladium was chosen as a single modifier. By the addition of palladium(5$\mu\textrm{g}$/$m\ell$) to 2ng/$m\ell$ manganese solution, the temperatures were raised from 1,00$0^{\circ}C$ to 1,20$0^{\circ}C$ for the charring and from 2,10$0^{\circ}C$ to 2,20$0^{\circ}C$ for the atomization as well as the sensitivity and reproducibility were improved. With such optimum conditions, the trace amount of manganese in several seaweeds(laver, tangle and brown seaweed) could be determined by a calibration curve method, and good recoveries of more than 965 were also obtained in the samples in which a given amount of manganese was spiked. The detection limit of this method was about 0.048ng/$m\ell$.

  • PDF

Thermal Decomposition and Ablation Analysis of Solid Rocket Propulsion (삭마 및 열분해 반응을 고려한 고체 추진기관의 열해석)

  • Kim, Yun-Chul
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.14 no.5
    • /
    • pp.32-44
    • /
    • 2010
  • A two-dimensional thermal response and ablation analysis code for predicting charring material ablation and shape change on solid rocket nozzle is presented. The thermogravimetric analysis (TGA) techniques have been used to characterize the thermal decomposition constants for Arrhenius parameters. Two heterogeneous reactions involving carbon and the oxidizing species of $H_2O$ and $CO_2$ are considered and determined by Zvyagin's ablation model and kinetic constants. The moving boundary problem and mesh moving are solved by remeshing-rezoning method in MSC-Marc-ATAS program. The difference between the calculated and experimental value of char and ablation thickness is up to 20%. For the performance prediction of thermal protection systems, this method will be integrated with a three-dimensional finite-element thermal and structure analysis code through the real time sensing of in-depth temperature and heat flux.

A Study on the Fire Resistance Performance of Wood Framed Lightweight Wall which Including a Middle Lintel (중인방을 포함한 목골조 경량벽체의 내화성능에 관한 연구)

  • Yeo, In-Hwan;Cho, Bum-Yean;Min, Byung-Yeol;Yoon, Myung-O
    • Fire Science and Engineering
    • /
    • v.25 no.3
    • /
    • pp.91-98
    • /
    • 2011
  • This study is about fire resistance performance of wood framed lightweight wall including a middle lintel as a traditional wall form in Korea. The target wall is non-loadbearing system which constructed with $38{\times}89$ mm ($2"{\times}4"$) wood frame and fireproof gypsum board covering, including a middle lintel made of $150{\times}150$ mm section glue-laminated timber. As a test results, all specimens have showed fire resistant performance over 90 minutes and tests were maintained until flame occuring on Specimen-l, 2, 3 at 91 min, 97 min and 98 min respectively. Fire resistance of the heat side gypsum board was 45 minutes and charring rate of middle lintel was equivalant with that of usual timber. The wood stud inside wall system showed relatively quick combution characteristic when exposed to high temperature with no temperature rising delaying time caused by moisture evaporation because of the dehydration preceded during the early period of fire side gypsum board resist to heat.

The Scanning Electron Microscopic study on the effect during subgingival calculus removal using Nd:YAG laser (치은연하치석제거술시 Nd : YAG 레이저를 이용한 효과에 관한 주사전자현미경적 연구)

  • Jeon, Yong-Seon;Choi, Byung-Son;Lee, Seok-Cho;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
    • /
    • v.27 no.2
    • /
    • pp.411-424
    • /
    • 1997
  • The purpose of this study was to evaluate in vitro the effects during subgingival calculus removal using Nd:YAG laser. The study group was consisted of 30 teeth with advanced periodontal disease extracted before the start of periodontal therapy. The specimens were divided into 8 different groups : 1) untreated control 2) scaling and root planing only 3) laser treated using 150mJ/pulse, 1sec, 5sec, contact mode 4) laser treated using 200mJ/pulse, 5sec, contact mode 5) laser treated using 150mJ/pulse, 1sec, non-contact mode 6) laser treated using 200mJ/pulse, 5sec, non-contact mode 7) laser treated using l5OmJ/pulse, 1sec, contact mode with water irrigation 8) laser treated using 200mJ/pulse, 5sec, contact mode with water irrigation. All specimens were prepared for evaluation by scanning electron microscopy(SEM). Specimens from Group 2 exhibited a smear layer of scale like texture with parallel instrument tracks resulting from curet use. Specimens treated by contact mode, Group 3 and 4 featured surface changes not observed· in controls such as charring, randomly distributed pitting and crater formation, and melting down of the tooth material and calculus. Specimens treated by noncontact mode, Group 5 and 6 featured similar surface changes observed in contact mode. However, the differences between contact and non-contact groups not significant. Specimens treated by contact mode with water irrigation, Group 7 and 8 featured slight surface change compared to other groups. The results suggested that Nd: YAG laser did not completely remove the subgingival calculus but was possible the application as adjunctive method.

  • PDF

Investigation and Theoretical Analysis of a Fire Accident Caused by Smoldering Combustion (Smoldering 연소로 인한 화재사고 조사보고 소개 및 이론적 해석)

  • 김연승;변영철;황정호
    • Fire Science and Engineering
    • /
    • v.13 no.3
    • /
    • pp.3-17
    • /
    • 1999
  • Smoldering is a non-flaming combustion mode, characterized by thermal degradation and c charring of the virgin material, evolution of smoke and emission of visible glow. A big fire may @ occur even in a confined environment having a limited amount of oxygen, due to smoldering c combustion through a porous solid material. This paper presents a theoretical analysis on the effect of smoldering combustion on fire occurrence based on a report about fire investigation of a real f fire accident. It is assumed that the propagation of the smolder wave is one-dimensional, d downward, opposing an upward forced flow and steady in a frame of reference moving with the s smolder wave. Smoldering combustion is modeled by a one-step reaction mechanism, without c considering pyrolysis. It is found that dominant parameters controlling smoldering combustion i include mass flux of oxidizer entering the reaction zone and void fraction of solid fuel. It is also found that the mechanism of transition to flaming is critically influenced by these two parameters.

  • PDF

Effects of Manufacturing Methods of Broiler Litter and Bakery By-product Ration for Ruminants on Physico-chemical Properties (육계분과 제과부산물을 이용한 반추가축용 완전혼합사료(TMR) 제조 시 가공처리 방법이 물리화학적 특성에 미치는 영향)

  • Kwak, W.S.;Yoon, J.S.;Jung, K.K.
    • Journal of Animal Science and Technology
    • /
    • v.45 no.4
    • /
    • pp.593-606
    • /
    • 2003
  • This study was conducted to develop effective manufacturing methods of a total mixed ration(TMR) composed of broiler litter(BL) and bakery by-product(BB) for ruminants. Five experiments included a small-scaled manufacture of TMR using a deepstacking method(Exp. 1), its pelletization(Exp. 2), its field-scaled manufacture(Exp. 3), a field-scaled manufacture using an ensiling method(Exp. 4), and a mixing process of deepstacked BL and BB prior to feeding(Exp. 5). BL and BB were mixed at a ratio which makes total digestible nutrients of the TMR 69%. For each experiment, temperature, appearance and physico-chemical properties were recorded and analyzed. The chemical composition data revealed that the mixture of BL and BB showed nutritionally additive balance which resulted from a considerable increase(P<0.05) of organic matter and a desirable decrease(P<0.05) of protein and fiber up to the requirement level for growing ‘Hanwoo’ steers. Deepstacking of BL and BB in Exp. 1 and 3 resulted in a sufficient increase of stack temperature for pasteurization, little chemical losses, appearance of white fungi on the surface, and partial charring due to excess stack temperature. For Exp. 2, its pelleting, which was successful using a simple, small-scaled pelletizer, resulted in a little loss(P<0.05) of organic matter and an increase(P<0.05) of indigestible protein(ADF-CP). Ensiling the mixture in Exp. 4 made little effect on chemical composition; however, one month of the ensiling period was not enough for favorable silage parameters. Deepstacking BL alone in Exp. 5 tended(P<0.1) to decrease true protein : NPN ratio and hemicellulose content and increase ADF-CP content due to the heat damage occurred. Deepstacking or ensiling of BL-BB mixtures and simple incorporating of BB into deepstacked BL prior to feeding could be practical and nutrients-preservative methods in TMR manufacture for beef cattle, although ensiling needed further hygienic evaluation.