• 자원리싸이클링
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• 제18권1호
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• pp.13-21
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• 2009

본 연구에서는 마찰하전형정전선별법을 적용하여 EVA(ethylene vinyl acetate)와 PET(polyethylene terephthalate) 혼합 폐플라스틱의 재활용을 위한 재질분리 연구를 수행하였다. 하전물질 선정을 위한 하전특성 연구결과, PP(polypropylene)재질이 EV4와 PET 폐플라스틱의 재질분리에 가장 효과적인 하전물질로 확인되어, PP재질의 pipe-type 하전장치를 개발하였다. 본 연구에서 개발된 하전장치를 이용한 재질분리 실험결과, 최적 실험조건에서 PET의 품위와 회수율이 각각 98.7%와 89.7%인 결과를 얻었다.

• 한국수소및신에너지학회논문집
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• 제8권4호
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• pp.161-171
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• 1997

$AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

• Carbon letters
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• 제1권3_4호
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• pp.148-153
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• 2001

The initial irreversible capacity, $Q_i$, is one of the parameters to express the material balancing of the cathode to anode. We introduced new terms, which are the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface ($Q_{is}$), to express precisely the irreversibility of an electrode/electrolyte system. Two terms depended on kinds of active-materials and compositions of the electrode, but did not change with charging state. MPCF had the highest value of IIE and the lowest value of $Q_{is}$ in 1M $LiPE_6$/EC + DEC (1 : 1 volume ratio) electrolyte. IIE value of $LiCoO_2$ electrode was 97-98%, although the preparation condition of the material and the electrolyte were different. $Q_{is}$ value of $LiCoO_2$ was 0~1 mAh/g. MPCF-$LiCoO_2$ cell system had the lowest of the latent capacity. $Q_{is}$ value increased slightly by adding conductive material. IIE and $Q_{is}$ value varied with the electrolyte. By introducing PC to EC+DEC mixed solvent, IIE values were retained, but $Q_{is}$ increased. In case of addition of MP, IIE value increased and $Q_{is}$ value also increased a little.

• 한국기계기술학회지
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• 제13권2호
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• pp.115-121
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• 2011

The size of hydrogen molecule is not so small as to invade into the lattice of material, and therefore, hydrogen invades into the material as atom. Hydrogen movement is done by diffusion or dislocation movement in the near crack tip or plastic deformation. Hydrogen appeared to have many effects on the mechanical properties of the Cr-Mo steel alloys. The materials for this study are 1.25Cr-0.5Mo and 2.25Cr-1Mo steels used at high temperature and pressure. The hydrogen amount obtained by theoretical calculation was almost same with the result solved by finite element analysis. The distribution of hydrogen concentration and average concentration was calculated for a flat specimen. Also, finite element analysis was employed to simulate the redistribution of hydrogen due to stress gradient. The calculation of hydrogen concentration diffused into the material by finite element method will provide the basis for the prediction of delayed fracture of notched specimen. The distribution of hydrogen concentration invaded into the smooth and notched specimen was obtained by finite element analysis. The hydrogen amount is much in smooth specimen and tends to concentrate in the vicinity of surface. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• 한국재료학회지
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• 제30권8호
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• pp.426-434
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• 2020

The performance characteristics of a lead acid battery are investigated with the content of Sodium Perborate Tetrahydrate (SPT, NaBO₃·4H₂O) in a positive plate active material. SPT, which reacts with water to form hydrogen peroxide, is applied as an additive in the positive plate active material to increase adhesion between the substrate (positive plate) and the active material; this phenomenon is caused by a chemical reaction on the surface of substrate. A positive plate with the increasing content of SPT is prepared to compare its properties. It is confirmed that the oxide layer increases at the interface between the substrate and the active material with increasing content of SPT; this is proven to be an oxide layer through EDS analysis. Battery performance is confirmed: when SPT content is 2.0 wt%, the charging acceptance and high rate discharge properties are improved. In addition, the lifetime performance according to the Standard of Battery Association of Japan (SBA) S0101 test is improved with increasing content of SPT.

• 한국재료학회지
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• 제33권6호
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• pp.257-264
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• 2023

To develop a high capacity lithium secondary battery, a new approach to anode material synthesis is required, capable of producing an anode that exceeds the energy density limit of a carbon-based anode. This research synthesized carbon nano silicon composites as an anode material for a secondary battery using the RF thermal plasma method, which is an ecofriendly dry synthesis method. Prior to material synthesis, a silicon raw material was mixed at 10, 20, 30, 40, and 50 wt% based on the carbon raw material in a powder form, and the temperature change inside the reaction field depending on the applied plasma power was calculated. Information about the materials in the synthesized carbon nano silicon composites were confirmed through XRD analysis, showing carbon (86.7~52.6 %), silicon (7.2~36.2 %), and silicon carbide (6.1~11.2 %). Through FE-SEM analysis, it was confirmed that the silicon bonded to carbon was distributed at sizes of 100 nm or less. The bonding shape of the silicon nano particles bonded to carbon was observed through TEM analysis. The initial electrochemical charging/discharging test for the 40 wt% silicon mixture showed excellent electrical characteristics of 1,517 mAh/g (91.9 %) and an irreversible capacity of 133 mAh/g (8.1 %).

• 설비공학논문집
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• 제24권5호
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• pp.454-460
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• 2012

The purpose of the present work is to investigate the removal characteristics of positively charged filters for capturing negatively charged particles such as bacteria and virus in water. In order to reduce the pressure drop and increase the filtration efficiency, the filter media, modified by charge modifier having positive functional groups, is developed and evaluated. Improved liquid filters have been developed with the modified surface charge to capture and adsorb particles by electrokinetic interaction between the filter surface and particles contained in an aqueous liquid. The positively charged filter media is composed of glass fiber, cellulose and poly-ethylenimine resin for positively charging with the variation of volume ratio. The zeta potential value of the positively charged filter is +37.92 mV at the glass fiber and cellulose content ratio of 50 : 50 with resin content of 100%, while that of the PSL test particle is -23.5 mV at pH 7. The removal efficiency of the electro-positively charged filter is 98% for PSL particles of 0.11 ${\mu}m$, while that of the negatively charged filter is 7%. The positively charged filter media showed the potential to be an effective method for removing fine particles from the contaminated water for liquid filtration.

• 한국전기전자재료학회논문지
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• 제33권1호
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• pp.31-36
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• 2020

An investigation was conducted to determine whether the ratio of the fluid to the charged particles affects the panel reflexibility rate and the drifting current flowing in the panel, in electrophoretic-based electronic paper. In this regard, three panels were produced in this study with the ratio of the charged particles to the fluid set as 1:5, 1:1, and 5:1. Each sample was driven using an identical input pulse, for which the current flowing in the panel and the output voltage of the photodiode were measured for the panel reflexibility rate. Consequently, the drifting current initially exhibited a peak value and a saturated value at a later point. This value was proportional to the ratio of the charged particles, and it was similar to this ratio when it is higher than 1:1. The output voltage of the photodiode due to the panel reflexibility rate was proportional to the ratio of the charged particles. However, the response speed decreased if the ratio was higher than 1:1. It is expected that the results of this study will contribute to the analysis of the charging of charged particles in electrophoretic-based electronic paper, and the selection of an appropriate concentration.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 춘계학술대회 논문집 디스플레이 광소자 분야
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• pp.165-168
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• 2000

An active-matrix LCD using thin film transistors (TFT) has been widely recognized as having potential for high-quality color fiat-panel displays. Pixel-Design Array Simulation Tool (PDAST) was used to profoundly understand the gate signal distortion and pixel charging capability, which are the most critical limiting factors for high-quality TFT-LCDs. In addition, PDAST can estimate voltage distributions in common electrode which can affect pixel voltage and feed-through voltage. Since PDAST can simulate the gate, data and the pixel voltages of a certain pixel on TFT array at any time and at any location on an array, the effect of common electrode voltage can be effectively analyzed. The information obtained from this study could be utilized to design the larger area and finer image quality panel.

• 한국전기전자재료학회논문지
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• 제21권7호
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• pp.679-685
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• 2008

This paper describes the degraded properties of between the charge and discharge current for ${\gamma}$-ray irradiated in electric power cable rubbers using in nuclear power generating station. The charge and discharge current of degradation in EPR(Ethylene Propylene Rubber), which were irradiated with the radiant capacity of 0.033 Mrad/h, have been measured in order to investigate the influence of the atmosphere(in amount of reinforcing agent, moisture absorption and heat treatment) on electrical properties. When ${\gamma}$-ray were irradiated on the EPR with more reinforcing agent from 4 to 40 Phr, charge and discharge currents was increase due to the amount of reinforcing agent. It was verified that the discharging and charging currents irradiated by ${\gamma}$-ray were higher than those that was not irradiated. The amount of the degraded current was more after moisture absorption than before moisture absorption. The charge and discharge current after heat treatment was similar to that of before heat treatment and it was decreased with the time elapsed. As these properties related with ${\gamma}$-ray irradiation dose, it is suggested that these properties can be utilized as a index of irradiation degradation.