• Bulletin of the Korean Chemical Society
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• 제18권8호
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• pp.874-880
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• 1997

Various classes of phospholipids were investigated for the structural determination of fatty acyl groups by fast atom bombardment tandem mass spectrometry (FAB-MS/MS). Phospholipids were desorbed by FAB as molecules chelated with sodium ion (or ions). Collision-induced dissociation (CID) of intact sodium adduct molecular ions ([M+Na]+, [M-H+2Na]+ or [M+Na-2H]-) produced a series of homologous fragment ions via the charge-remote fragmentation along the fatty acid chains. These ions were found useful to locate the double bond positions even for the polyunsaturated fatty acid chains. The regiospecificity of the acyl chain linkages in phosphatidylcholine (PC) could also be determined based on the ratio of relative abundance of the product ions (i.e., [M+Na-85-R2COOH]+ vs [M+Na-85-R1COOH]+) in CID-MS/MS of [M+Na]+. These are generated by the loss of fatty acyl groups at sn-1 and sn-2, respectively, together with the choline group. In all the phospholipid compounds investigated, loss of the fatty acid at the sn-2 position was dominant. The present method was applied to the structural determination of molecular species of phosphatidylglycerols (PG) isolated from cyanobacterium Synechocystis sp. PCC 6803.

• Food Science and Biotechnology
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• 제17권4호
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• pp.787-793
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• 2008

A major polyphenolic compound extracted from omija (Schisandra chinensis) fruit was structurally identified, and its composition of major nutrients was investigated as well in this study. A dominating high performance liquid chromatography (HPLC) peak of water-extracted anthocyanin represented 94.1% of total absorbable compounds at 520 nm, which was further identified with HPLC-mass spectrometry (MS). As a result, mass-to-charge ratio (m/z) of the predominant anthocyanin was determined to be 727, and it was identical to molecular mass of cyanidin-3-xylosylrutinoside (Cya-3-O-xylrut). This is the first report that colorant of omija is predominantly composed of Cya-3-O-xylrut. Omija fruit contained exclusively 3 types of monosaccharide such as glucosc (0.68 g), galactose (0.01 g), and fructose (0.52 g) per 100 g of fruits. Several organic acids, citric (3.29 g), malic (1.4 g), acetic (0.4 g), and succinic acids (0.36 g) per 100 g of fruits, were detected by high performance anion exchange chromatography (HPAEC) analysis. During the compositional analysis of tree amino acid by HPLC, it was noticed that omija fruit contained substantial amount (0.01 g/100 g of fruits) of $\gamma$-amino butyric acid (GABA).

• 한국전기전자재료학회논문지
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• 제24권8호
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• pp.669-673
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• 2011

The charged particle type display is a kind of the reflectivity type display and shows an image by absorption and reflection of external light source, which has keep an image without additional electric power because of bistability. In this paper, we made a device whose cell gap is $56\;{\mu}m$ and also analyzed driving and memory characteristics by applied driving voltages. As a result, we found that the driving voltage and memory effect depend on q/m(charge to mass ratio) of charged particle. In this case of breakdown voltage, the devices showed degradation of reflectivity and memory effect due to irregular movement of overcharged particles. In addition, contrast ratio of the device varies with memory effect. Thus, we consider that device needs uniform q/m for improvement of electric and optical properties and memory effect.

• 대한기계학회논문집B
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• 제21권8호
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• pp.1068-1076
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• 1997

Emission control of acid exhaust gases from coal-fired power plants and waste incinerators has become an increasing concern of both industries and regulators. Among those gaseous emissions, SO$_{2}$ has been eliminated by a Spray Drying Absorber (SDA) system, where the exhaust gas is mixed with atomized limestone-water slurry droplets and then the chemical reaction of SO$_{2}$ with alkaline components of the liquid feed forms sulfates. Liquid atomization is necessary because it maximizes the reaction efficiency by increasing the total surface area of the alkaline components. An experimental study was performed with a laboratory scale SDA to investigate whether the scrubbing efficiency for SO$_{2}$ reduction increased or not with the application of a DC electric field to the limestone-water slurry. For a selected experimental condition SO$_{2}$ concentrations exited from the reactor were measured with various applied voltages and liquid flow rates. The applied voltage varied from -10 to 10 kV by 1 kV, and the volume flow rate of slurry was set to 15, 25, 35 ml/min which were within the range of emission mode. Consequently, the SO$_{2}$ scrubbing efficiency increased with increasing the applied voltage but was independent of the polarity of the applied voltage. For the electrical and flow conditions considered a theoretical study of estimating average size and charge of the atomized droplets was carried out based on the measured current-voltage characteristics. The droplet charge to mass ratio increased and the droplet diameter decreased as the strength of the applied voltage increased.

• 한국산업융합학회 논문집
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• 제20권2호
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• pp.105-113
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• 2017

Recently the direct injection diesel engine is the most efficient one available for road vehicles, so this fundamental advantage suggests the compression injection diesel engine are a wise choice for future development efforts. The compression ignition diesel engine, with its bigger compression ratios if compared to the SI engine, offers a higher thermodynamic efficiency, also additionally the diesel engine with its less pumping losses due to the throttled intake charge as in a SI engine has higher fuel economy. But the largest obstacle to the success of this engine is meeting emission standards for Nitric oxides and particulate matter while maintain fuel consumption advantage over currently available engines. Thus its use should be largely promoted, however, diesel engine emits more Nitric oxides and particulate matter than other competing one. There has been a trade-off between PM and NOx, so efforts to reduce NOx have increased PM and vice versa, but trap change this situation and better possibility emerge for treating NOx emission with engine related means, such as injection timing, equivalence ratio, charge composition, and engine speed. The common rail direct injection system is able to adjust the fuel injection timing in a compression ignition engine, so this electronically controlled injection system can reduce the formation of NOx gas without increase in soot. In this study it is designed and used the engine test bed which is installed with turbocharge and intercooler. In addition to equipped using CRDI by controlling injection timing with mapping modulator, it has been tested and analyzed the engine performance, combustion characteristics, and exhaust emission as operating parameters.

• 한국조경학회지
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• 제27권4호
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• pp.1-12
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• 1999

This study aims to find basic data for using the quantitative assessment of the sustainability and establishing the systematic index of the planning for local cities to consider the environmentally sound and sustainable development. The research designs to review professional responding to surveys preceded by separate questionnaires and interviews from book reviews, and suggests to make an assessment model of the sustainability for local cities. The research found consequently as follows. Firstly, the research survey items were decides totally 52, grouped 9 assessmental issues and distributed under 4 assessmental domains for the sustainability from the references of book reviews. Secondly, the research result concentrated on the followings from the professional responding to surveys. 1. A most influent factor is the distribution of animals and plants in a nature domain. The next influent factors are the ratio of mass-transportation systems, the numbers of the species of animals and plants, the acreage of conservative forestry, the numbers of reused water resources, and the usage number of water supply, orderly in the nature domain. 2. A most influent factor is the usage number of synthetic detergents in a pollution domain. The next influent factors are the volume of waste water, the number of registered vehicles, the degree of soil pollution, and the charge of development imposition, orderly in the pollution domain. 3. A most influent factor is the acreage of athletic facilities, in an urban domain. the next influent factors are the acreage of recreational facilities, the number and acreage of cultural assets, the number of cultural facilities, the acreage of landscape conservation area, the charge of cultural asset management, orderly in the urban domain. 4. A most influent factor is the number of waste disposal facilities in a participation domain. The next influent factors are the capacity of reused waste, the usage of synthetic detergents, the ratio of waste water disposal, orderly in the participation domain. 5. A most contributed influent domain to the assessment of the sustainability for local cities is the urban domain. The next influent domains are nature domain, participation domain, and pollution domain, orderly in the contribution of the assessment of the sustainability. But, the pollution domain is little relationship with the sustainability. Therefore, it is clear that the abundant greens and the improved level of culture are dominant influences on the sustainabiligy, as like improving the ratio of roadside trees, the acreage of parks, and enlarging the number of cultural facilities.

• 대한기계학회논문집B
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• 제25권7호
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• pp.923-932
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• 2001

A series of experiments were conducted to generate fine liquid(water) drops through the electrohydrodynamic atomization process. The atomization mode depended on flow rate and DC voltage input. For water, having electric conductivity larger than 10(sup)-7S/m, the spindle mode turned out to be the only mode to generate uniform-size drops within the range of 30-450 microns that have wide applications. Within this mode, both the uniformity and the fineness of drops were improved at an optimum voltage input for a given flow rate. This optimum voltage increased with increasing of the liquid flow rate. Another important parameter considered was the nozzle material with different electric conductivity and liquid wettability. A stainless-steel nozzle (the material with high electric conductivity and high liquid wettability) and a silica nozzle (the electrically non-conducting material with low liquid wettability) were tested and compared; and more uniform drops could be obtained with the silica nozzle.

• Agricultural and Biosystems Engineering
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• 제3권1호
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• pp.29-34
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• 2002

Two charging methods of electrostatic nozzle, i.e. induction and ionized field corona charging, were designed and evaluated for orchard sprayer application. An artificial (metallic) target was constructed and used in this experiment. The charge-to-mass ratio for the induction electrode was measured by using the Faraday cage. Two conventional pressure-swirl nozzles have been employed with different orifice diameters under the same experimental operating conditions. A commercial pressure-swirl nozzle with orifice diameter of 1.0 was used for the conventional spray. The diameter of the electrostatic was 0.59 mm. The experiment was carried out for individual nozzle sprays at $0^{\circ}$, $20^{\circ}$ and $50^{\circ}$ oriented angles and three nozzles, sprayed simultaneously at a distance of 1.0 and 2.0 m from the nozzle tip to the target. The nozzles were mounted on a carriage with constant speed of 1.26 km/h with a blower attached. The weighing method was employed to evaluate for the spray deposition, ground loss and estimated drift. The results show more promising for the induction charging method, especially at $20^{\circ}$oriented angle at a distance of 1.0 m from the target for a single nozzle and when all three nozzles were operated simultaneously for spray deposition. The results of the induction charging method show promising with the developed electrostatic technique.

• 전기화학회지
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• 제6권2호
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• pp.153-157
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• 2003

전기이중층 축전용량(electric double layer capacitance)과 유사축전용량(pseudo-capacitance)을 함께 갖는 하이브리드 전기화학 축전기에 대한 연구를 수행하였다. 양극은 $Ni(OH)_2$ 활성탄소가 복합된 전극을 사용하였으며 음극은 활성탄소를 활물질로 사용하므로써 비대칭 전극 구조를 갖는다. 셀 실험을 위하여 $5\times5cm^2$ 크기인 전극을 제작 사용하였다. Cyclic voltammetry측정 및 교류 임피던스 측정실험을 통하여 각각의 셀들이 갖는 전기화학적 거동을 조사하였고 충 방전 실험을 통하여 양극과 음극의 최적 질량비를 조사하였다.

• 한국전기전자재료학회논문지
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• 제25권1호
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• pp.48-52
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• 2012

The charged particle type display device is a kind of the reflectivity type display and shows an image by absorption and reflection of external light source. The charged particle is important factor for driving of the display and quantity of charge per mass of the charged particle determines the driving voltage, contrast ratio, response time, etc. But it is easy for the charged particles to be damaged in the putting process of the display and the damages cause lumping phenomenon of the charged particles. Because the lumping phenomenon makes high driving voltage, low quality of optical properties, short life time, etc, so the charged particles must be filled by stable putting methods. In this paper, we filled the charged particles into the panels by electric fields to improve the electrical and optical characteristics of the display. Also, we analyzed the driving characteristics of the charged particles according to the applied putting voltages.