• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1703-1706
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• 1996

The purpose of this study is to research and develop polypyrrole(PPy) positive for thin film rechargeable lithium battery. We investigated cyclic voltammetry, AC impedance response and charge/discharge cycling of PPy/SPE/Li cells as a function of temperature. The redox capacity of $PPy/CF_{3}SO_{3}$ film was the most large. The discharge capacity of PPy/SPE/Li cell with $PPy/CF_{3}SO_{3}$ film was higher than those of $PPy/ClO_{4}$ and $PPy/AsF_6$ films at all cycles. The energy density of PPy/SPE/Li cells during 1st cycle was 73, 90 and 101Wh/kg at $25^{\circ}C$, $45^{\circ}C$ and $60^{\circ}C$, respectively. The improvement of energy density is due to reduction of charge-transfer resistance associated doping-undoping process in PPy film with Increasing temperature. $PPy/CF_{3}SO_{3}$ film shows a good property on charge/discharge cycling in PEO-$LiClO_4$-PC-EC electrolyte.

• Bulletin of the Korean Chemical Society
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• 제25권4호
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• pp.511-516
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• 2004

A Li$[Co_{0.17}Li_{0.28}Mn_{0.55}]O_2$ cathode compound was prepared by a simple combustion method. The X-ray diffraction pattern showed that this compound could be classified as ${\alpha} -NaFeO_2$ structure type with the lattice constants of a = 2.8405(9) ${\AA}$ and c = 14.228(4) ${\AA}$. According to XANES analysis, the oxidation state of Mn and Co ions in the compound were 4+ and 3+, respectively. During the first charge process, the irreversible voltage plateau at around 4.65 V was observed. The similar voltage-plateau was observed in the initial charge profile of other solid solution series between $Li_2MnO_3\;and\;LiMnO_2$ (M=Ni, Cr...). The first discharge capacity was 187 mAh/g and the second discharge capacity increased to 204 mAh/g. As the increase of cycling number, one smooth discharge profile was converted to two distinct sub-plateaus and the discharge capacity was slowly decreased. From the Co and Mn K-edge XANES spectra measured at different cyclic process, it can be concluded that irreversible transformation of phase is occurred during continuous cycling process.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국제학술편); Seoul National University, Seoul; 20-22 Oct. 1993
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• pp.298-301
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• 1993

In pneumatic systems the temperature changes during operation owing to air compression or expansion, friction of air movement and friction between solid interface. The temperature change usually ha undesirable influence on process. To attain higher quality of pneumatics, studies in thermo-fluid dynamics is needed. This paper presents experimental results anti theoretical analysis on the temperature change by air charge and discharge to cylinders, which has no piston yet. The temperature increase by charge shows a strong, dependence on axial location along the cylinder, which is proved in theoretical analysis. The temperature decreases by discharge shows rather uniform in the cylinder, which is also proved by theory.

• 전력전자학회:학술대회논문집
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• 전력전자학회 1999년도 전력전자학술대회 논문집
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• pp.210-213
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• 1999

A battery is the device that transforms the chemical energy into the direct-current electrical energy directly without a mechanical process. Unit cells are connected in series to obtain the necessary voltage, while being connected in parallel to organize capacity for load current and to decrease the internal resistance for corresponding the sudden shift of the load current. The circular-current, however, could be occurred when the system is driven in parallel. As a result, the new batteries are heated by over-change and discharge, and the over charge current makes to increase the rust of the positive grid and consequently the shortened life of the new batteris would be shown. In this paper, the internal resistance of charge and discharge will be balanced, through inserting the resistance into the system by way of calculation of the changed amount of internal resistance.

• 전기화학회지
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• 제2권2호
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• pp.106-111
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• 1999

[ $CaNi_5$ ] 수소저장합금의 전기화학적 충$\cdot$방전 특성에 미치는 MG(mechanical grinding) 영향이 Ar및 $H_2$ 가스분위기에서 조사되었다 MG공정중 $CaNi_5$ 합금은 표면 산화층의 파괴와 재생성 및 산화층 근방의 불균질화로 인하여 MG 15시간 이후부터 CaO와 Ni로 뚜렷한 상분리가 일어났다. $MG-CaNi_5$는 MG시간이 길어질수록 초기의 전기화학적 방전용량은 현저히 감소하였지만 충$\cdot$방전 싸이클의 증가에 따른 용량저하 속도는 $CaNi_5$합금에 비하여 낮았다. MG처리된 $CaNi_5$합금의 퇴화는 MG공정중의 상분리 및 불규칙화에 의한 수소의 가역반응 site의 감소 및 분극저항의 증가, KOH 전해질 내에서 합금 표면의 산화반응에 의한 부동태 피막형성에 기인하는 것으로 판단되었다.

• Korean Chemical Engineering Research
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• 제46권1호
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• pp.69-75
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• 2008

Mechanochemical process로 제조된 $LiCoO_2$ 전극의 경우에 4.3 V 이상의 전위영역에서 용량감소현상이 두드러지게 나타난 반면에, Zr을 피복한 $LiCoO_2$의 경우에는 4.5 V의 전위에서도 안정성을 유지하였다. 본 연구에서 제작한 Zr이 피복된 $LiCoO_2$ 전극은 3.0~4.5 V 구간에서 197 mAh/g의 용량을 나타내었으며, 50 사이클 후에 96%의 방전용량을 유지하므로 전지의 안정성을 확보하였다.

• 수산해양기술연구
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• 제41권2호
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• pp.165-170
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• 2005

Al-Zn alloy/$MnO_2$, seawater cell was considered as a primary aqueous cell with an average voltage range from 1.0 to 1.1V, and the electrolyte of seawater was uptaken into the cell. Eventually, the capacity of its usage will be used for long-term. However, the more use of this cell, the higher corrosion phenomenon of the electrode occurred. Due to its corrosion phenomenon, one main default has been observed with gradual decrease during a discharge process. In this research, a common-used active material for anode was $LiNiO_2$. An active material for cathode, $Zn_{X}FeS_2$ was synthesized in high temperature by uptaken a small amount of 1.3 wt% of ZnS into $FeS_2$, one of the transition-metal dichalcogenides in high temperature. Consequently, based on their usages shown above, this secondary aqueous lithium cell could be more developed. This cell was shown as remarkable charge/discharge performance during the charge/discharge processes. This cathode with active material was given a considerable efficiency of inserting $Li^+$ ions. Moreever, in accordance with the characteristic of the crystal structure for $Zn_{x}FeS_2$, a small amount of ZnS was added which made it possible to reduce prominently velocity of corrosion during the charge/discharge cycle. By applying those merits, Al-Zn alloy/$MnO_2$ seawater cell will be used as a fundamental data in order to transform into a secondary aqueous cell.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1999년도 춘계 학술발표회 논문집
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• pp.193-196
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• 1999

This paper describes one dimensional transient modeling of encapsulated ice storage tank and its experimental validation. This model simulates the performance of tile tank for charge and discharge process with brine mass flow operating conditions.

• 대한기계학회논문집B
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• 제24권6호
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• pp.753-759
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• 2000

Photoelectric charging is a very efficient way of charging small particles. This method can be applied to combustion measurement, electrostatic precipitator, metal separation and control of micro-contamination. To understand the photoelectric charging mechanism, particle charging of silver by exposure to ultraviolet is investigated in this study. Average charges and charge distributions are measured at various conditions, using two differential mobility analyzers, a condensation nucleus counter, and an aerosol electrometer. The silver particles are generated in a spark discharge aerosol generator. After that process, the generated particles are charged in the photoelectric charger using low-pressure mercury lamp that emits ultraviolet having wavelength 253.7 nm. The results show that ultra-fine particles are highly charged by the photoelectric charging. The average charges linearly increase with increasing particle size and the charge distribution change with particle size. These results are discussed by comparison with previous experiments and proposed equations. It is assumed that the coefficient of electron emission probability is affected by initial charge. The results also show that the charge distribution of a particle is dependent on initial charge. Single changed particle, uncharged particle and neutralized particle are compared. The differences of charge distribution in each case increase with increasing particle size.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 춘계학술대회 논문집 디스플레이 광소자 분야
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• pp.159-161
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• 2000

After the square type reset pulse, the condition of remaining wall charge has been experimentally investigated in AC-PDP with VDS (Versatile Driving Simulator) system, in which arbitrary driving waveform and sequence can be used. After the self-discharge process, almost wall charges are eliminated. But some wall charges are not and its quantity is dependent on the voltage of the reset pulse. When the voltage of the reset pulse is growing, its quantity is decreased. But if the voltage of the reset pulse is above 300V, the wall voltage due to remaining wall charge is constant and its value is found out 6V. Also it is found that its polarity is always same with the one made by the reset pulse. It means that the polarity is not changed by the self-discharge.