• Title/Summary/Keyword: Charge-discharge process

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Small-size PLL with time constant comparator (시정수 비교기를 이용한 작은 크기의 위상고정루프)

  • Ko, Gi-Yeong;Choi, Young-Shig
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.11
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    • pp.2009-2014
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    • 2017
  • A novel structure of phase locked loop (PLL) with a time constant comparator and a current compensator has been proposed. The proposed PLL uses small capacitors which are impossible for stable operation in a conventional PLL. It is small enough to be integrated into a single chip. The time constant comparator detects the loop filter output voltage variations using signals which are passed through small and large RC time constants. The signal from the large RC time constant node is the average of the loop filter output voltage. The output voltage of another node is approximately equal to the present loop filter voltage. The output of the time constant comparator controls a current compensator and charge/discharge small size loop filter capacitors. It makes the proposed PLL operate stably. It has been simulated and proved by HSPICE in a CMOS $0.18{\mu}m$ 1.8V process.

The Structural and Electrochemical Properties of Thermally Aged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 Cathodes

  • Park, Yong-Joon;Lee, Ju-Wook;Lee, Young-Gi;Kim, Kwang-Man;Kang, Man-Gu;Lee, Young-Il
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2226-2230
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    • 2007
  • As a cathode material of lithium rechargeable batteries, charged Li[Co0.1Ni0.15Li0.2Mn0.55]O2 electrodes, which were aged thermally at 25 oC and 90 oC respectively, were characterized by means of charge/discharger, impedance spectroscopy, and X-ray diffraction. The discharge capacity diminution of the electrodes aged at 25 oC and 90 oC for 1 week was 4% and 23%, respectively. The cell aged at 25 oC was recovered on cycling. However, the capacity loss after ageing at 90 oC was not recovered in a subsequent cycling test, which demonstrates that the reaction occurring during ageing at 90 oC is irreversible. A significant impedance increase of aged electrode at 90 oC is associated with irreversible capacity loss. The structural changes including phase transformation were not detected by XRD analysis, because it could be due to out of detection limit. After ageing, impedance was slightly decreased during subsequent cycling test. It could be explained the cyclic performance of aged sample is stable. The thermal stability was not deteriorated by ageing even at the high temperature of 90 oC.

Preparation of Core-Shell Structured Iron Oxide/Graphene Composites for Supercapacitors Application (코어-쉘 구조의 산화철/그래핀 복합체 제조 및 슈퍼커패시터 응용)

  • Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.14 no.3
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    • pp.65-72
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    • 2018
  • Core-shell structured $Fe_3O_4/graphene$ composites were synthesized by aerosol spray drying process from a colloidal mixture of graphene oxides and $Fe_3O_4$ nanoparticles. The structural and electrochemical performance of $Fe_3O_4/graphene$ were characterized by the field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, cyclic voltammetry, and galvanometric discharge-charge method. Core-shell structured $Fe_3O_4/GR$ composites were synthesized in different mass ratios of $Fe_3O_4$ and graphene oxide. The composite particles were around $3{\mu}m$ in size. $Fe_3O_4$ nanoparticles were encapsulated with a graphene. Morphology of the $Fe_3O_4/graphene$ composite particles changed from a spherical ball having a relatively smooth surface to a porous crumpled paper ball as the content of GO increased in the composites. The $Fe_3O_4/GR$ composite fabricated at the weight ratio of 1:4 ($Fe_3O_4:GO$) exhibited higher specific capacitance($203F\;g^{-1}$) and electrical conductivity than as-fabricated $Fe_3O_4/GR$ composite.

Performance Analysis for Regenerative Energy Storage System in Kyoung-bu High Speed Railway (경부고속철도 회생 에너지 저장시스템 성능 분석)

  • Jang, Min-Ju;Jeon, Yong-Joo;Lho, Young Hwan
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.9
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    • pp.1391-1397
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    • 2015
  • Recently, various researches are conducted in the application of regenerative energy produced during the operation of an electric locomotive. Regenerative energy is produced by a generator in the brake procedure. The generator is operated by kinetic energy of an electric railroad using an electric motor. The process of producing regenerative energy varies with the current type of a railroad and its running condition. The quality of electric power can be improved and electric energy can be utilized effectively, especially in the use of an energy storage system (ESS). Thus, it is necessary to apply ESS into AC section and high speed railway. This study analyses the composition of the regenerative ESS equipment installed in Yong-Jeong sectioning post, operational principle, charge and discharge algorithm and energy efficiency. The analysis shows that CO2 emissions can be reduced about 0.5 ton per a day. In addition, ESS helps saving the energy and the compensation of the voltage drop caused by the operation of high speed train when it is installed at the end of the feeder section. The number of high speed train will be increased continuously related to the electrification rate. Therefore, applying the ESS to high speed railway is expected to solve the instability of the feeder voltage and the equipment capacity problem caused by the high speed trains.

Pt Doping Mechanism of Vanadium Oxide Cathode Film Grown on ITO Glass for Thin Film Battery

  • Kim, Han-Ki;Seong, Tae-Yeon;Jeon, Eun-Jeong;Cho, Won-Il;Yoon, Young-Soo
    • Journal of the Korean Ceramic Society
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    • v.38 no.1
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    • pp.100-105
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    • 2001
  • An all solid-state thin film battery (TFB) was fabricated by growing, undoped and Pt-doped vanadium oxide cathode film ( $V_2$ $O_{5}$ ) on I $n_2$ $O_3$: Sn coated glass, respectively. Room temperature charge-discharge measurements based on Li/Lipon/ $V_2$ $O_{5}$ full-cell structure with a constant current clearly shows that the Pt-doped $V_2$ $O_{5}$ cathode film is superior, in terms of cyclibility. X-ray diffraction (XRD) results indicate that the Pt doping process induces a more random amorphous structure than an undoped $V_2$ $O_{5}$ film. In addition to its modified structure, the Pt-doped $V_2$ $O_{5}$ film has a smoother surface than the undoped sample. Compared to an undoped $V_2$ $O_{5}$ film, the Pt doped $V_2$ $O_{5}$ cathode film has a higher electron conductivity. We hypothesize that the addition of Pt alters electrochemical performance in a manner of making more random amorphous structure and gives an excess electron by replacing the $V^{+5}$. Possible mechanisms are discussed for the observed Pt doping effect on structural and electrochemical properties of vanadium oxide cathode films, which are grown on I $n_2$ $O_3$: Sn coated glass.

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A Fast-Switching Current-Pulse Driver for LED Backlight (LED 백라이트를 위한 고속 스위칭 전류-펄스 드라이버)

  • Yang, Byung-Do;Lee, Yong-Kyu
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.7
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    • pp.39-46
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    • 2009
  • A fast-switching current-pulse driver for light emitting diode (LED) backlight is proposed. It uses a regulated drain current mirror (RD-CM) [1] and a high-voltage NMOS transistor (HV-NMOS). It achieves the fast-response current-pulse switching by using a dynamic gain-boosting amplifier (DGB-AMP). The DGB-AMP does not discharge the large HV-NMOS gate capacitance of the RD-CM when the output current switch turns off. Therefore, it does not need to charge the HV-NMOS gate capacitance when the switch turns on. The proposed current-pulse driver achieves the fast current switching by removing the repetitive gate discharging and charging. Simulation results were verified with measurements performed on a fabricated chip using a 5V/40V 0.5um BCD process. It reduces the switching delay to 360ns from 700ns of the conventional current-pulse driver.

Combustion Characteristics of Ionized Fuels for Battery System Safety (배터리 시스템 안전을 위한 이온화 연료의 연소 특성)

  • Ko, Hyeok Ju;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.33 no.1
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    • pp.22-27
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    • 2018
  • Many electronic devices are powered by various rechargeable batteries such as lithium-ion recently, and occasionally the batteries undergo thermal runaway and cause fire, explosion, and other hazards. If a battery fire should occur in an electronic device of vehicle and aircraft cabin, it is important to quickly extinguish the fire and cool the batteries to minimize safety risks. Attempts to minimize these risks have been carried out by many researchers but the results have been still unsatisfied. Because most rechargeable batteries are operated on the ion state during charge and discharge of electricity and the combustion of ion state has big difference with normal combustion. Here we focused on the effect of ions including an electron during combustion process. The effects of an ionized fuel on the flame stability and the combustion products were experimentally investigated in the propane jet diffusion flames. The burner used in this experiment consisted of 7.5 mm diameter tube for fuel and the propane was ionized with th ionizer (SUNJE, SPN-11). The results show that toe overall flame stability and shape such as flame length has no significant difference even in the higher ion concentration. However the fuel ionization affects to the pollutant emissions such as NOx and soot. NOx and CO emissions measured in post flame region decreased by fuel ionization, especially high fuel velocity, i.e. high ion density. TGA analysis and morphology of soot by TEM indicates that the fuel ionization makes soot to be matured.

Electrochemical Characteristics of Hybrid Capacitor using Core-shell Structure of MCMB/Li4Ti5O12 Composite (Core-shell 구조의 MCMB/Li4Ti5O12 합성물을 사용한 하이브리드 커패시터의 전기화학적 특성)

  • Ko, Hyoung Shin;Choi, Jeong Eun;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.52 no.1
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    • pp.52-57
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    • 2014
  • The MCMB-$Li_4Ti_5O_{12}$ with core-shell structure was prepared by sol-gel process to improve low cycle capability of MCMB in this study. The electrochemical characteristics were investigated for hybrid capacitor using MCMB-$Li_4Ti_5O_{12}$ as the negative electrode and $LiMn_2O_4$, Active carbon fiber as the positive electrode. The electrochemical behaviors of hybrid capacitor using organic electrolytes ($LiPF_6$, EC/DMC/EMC) were characterized by charge/discharge, cyclic voltammetry, cycle and impedance tests. The hybrid capacitor using MCMB-$Li_4Ti_5O_{12}/LiMn_2O_4$ electrodes had better capacitance than MCMB hybrid systems and was able to deliver a specific energy with 67 Wh/kg at a specific power of 781 W/kg.

SiOC Anode Material Derived from Poly(phenyl carbosilane) for Lithium Ion Batteries

  • Lee, Yoon Joo;Ryu, Ji Yeon;Roh, Kwang Chul;Kim, Soo Ryong;Kwon, Woo Teck;Shin, Dong-Geun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.480-484
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    • 2013
  • Since SiOC was introduced as an anode material for lithium ion batteries, it has been studied with different chemical compositions and microstructures using various silicon based inorganic polymers. Poly(phenyl carbosilane) is a SiOC precursor with a high carbon supply in the form of the phenyl unit, and it has been investigated for film applications. Unlike any other siloxane-based polymers, oxygen atoms must be utilized in an oxidation process, and the amount of oxygen is controllable. In this study, SiOC anodes were prepared using poly(phenyl carbosilane) with different heat treatment conditions, and their electrochemical properties as an anode material for lithium ion batteries were studied. In detail, cyclic voltammetry and charge-discharge cycling behavior were evaluated using a half-cell. A SiOC anode which was prepared under a heat treatment condition at $1200^{\circ}C$ after an oxidation step showed stable cyclic performance with a reversible capacity of 360 mAh/g.

The Literature Study Medical History of Medieval Obstetrics and Gynecology (중세(中世) 부산과(婦産科)의 의사학적(醫史學的) 연구(硏究))

  • Cho, Myun-Hwi;Park, Hyun-Kuk
    • The Journal of Dong Guk Oriental Medicine
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    • v.5
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    • pp.231-271
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    • 1996
  • Obstetrics and Gynecology include gynecology which is concerned with the treatment for the disease based on physiology and pathology of women, and obstetrics which is concerned with pregnancy delivery. These obstetics and gynecology can be said to date from the birth of human beings. This paper has carried on the studies about the generating and developing process of obstetics and gynecology. The results of this study are as follows : Distinction in Northern and Southern Dynasties were much more Obstetrics and Gynecology studying the Obstetrics and Gynecology books in that time, the study about "oncosis" (腫瘤) and forms of drug, pill, powder, pIaster were carried on. The highest distinction in Sui age were research and development on pathogenesis and cause of disease about Obstetrics and Gynecology disease and it was appeared representatively in "Zhubingyuanhoulun""諸病源候論" which was special book on cause of disease and pathogenesis and syndrome, And it was explained about abnormal vaginal discharge in this book. Obstetrics and Bynecology were developed on theory and clincis in Tang age when "Taiyshu"(太醫暑) was established. "Taiyshu"(太醫暑) taked complete charge of medical operation and education, published much excellent Obstetrics and Gynecology books than the past. Among them specially "Qianjinyaofang""千金要方" explained Obstetrics and Gynecology matter first in three volumes and "Qianjinyifang""千金翼方" explained this matter first in four volumes. This point indicate that Obstetrics and Gynecology's importance was established in Tang age, so Obstetrics and Gynecology's developmental history, Song age was the acme period. "Taiyju"(太醫局) was established in "xining""熙?" 9 year and Obstetrics belonged to one of nine departments under "Taiyun"(太醫局), so Obstetrics and Gynecology was separated from the other medical parts and it was prepared of it's progressing bases independently and appeared of changes in quality and increase in quantity about theory and prescription of Obstetrics and Gynecology, specially determination of treatment based on the differentiation of symptoms and sighs was taked a serious view. Besides four great physicians in Jing and Yuan dynasies diversified Obstetrics and Gynecology contents through their only medical theory and clinical treatment.

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