• Title/Summary/Keyword: Charge-Transfer

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Design and Implementation of a 100 W Receiver for Wireless Power Transfer Using Coupled Magnetic Resonance (자기공명 무선전력전송용 100 W급 수신기 설계 및 제작)

  • Kim, Seong-Min;Cho, In-Kui;Choi, Hyun-Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.1
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    • pp.84-87
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    • 2016
  • In this paper, a receiver for wireless power transfer is proposed. The receiver consists of a 100 W rectifier in 1.8 MHz frequency band, and a constant current charger. In particular, two kinds of protection circuits are installed in the rectifier. They are a over-voltage protection circuit which block the input voltages greater than 30 V and a active-dummy load which maintains the receiver input impedance by automatically consuming the remaining input power. The constant current charger is designed to charge the battery with a charging current of up to 1 A. A wireless charging system is fabricated using the proposed receiver. The system is composed of a 130 W transmitter, two magnetic resonator, and proposed receiver for charging a 48 V Li-Ion battery using the coupled magnetic resonance method. By the measurement result, the system efficiency is about 54 %.

Performance Simulation of Planar Solid Oxide Fuel Cells Characteristics: Computational Fluid Dynamics (전산 유체 모델링을 이용한 평판형 고체산화물 연료전지 작동특성 전산모사)

  • Woo Hyo Sang;Chung Yong-Chae
    • Journal of the Korean Electrochemical Society
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    • v.7 no.2
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    • pp.69-79
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    • 2004
  • To correctly simulate performance characteristics of fuel cells with a modeling method, various physical and chemical phenomena must be considered in fuel cells. In this study, performance characteristics of planar solid oxide fuel cells were simulated by a commercial CFD code, CFD-ACE+. Through simultaneous considerations for mass transfer, heat transfer and charge movement according to electrochemical reactions in the 3-dimensional planar SOFC unit stack, we could successfully predict performance characteristics of solid oxide fuel cells under operation for structural and progress variables. In other words, we solved mass fraction distribution of reactants and products for diffusion and movement, and investigated qualitative and quantitative analysis for performance characteristics in the SOFC unit stack through internal temperature distribution and polarization curve for electrical characteristics. Through this study, we could effectively predict performance characteristics with variables in the unit stack of planar SOFCs and present systematic approach for SOFCs under operation by computer simulation.

Study for Reducement of Polymerization Time and Improvement of Stability in Manufacturing Carboxylated Styrene-butadiene Latex (카르복실화 스티렌-부타디엔 라텍스의 중합시간 단축과 안정성 개선을 위한 연구)

  • Cho, Ur-Ryong
    • Elastomers and Composites
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    • v.37 no.1
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    • pp.31-38
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    • 2002
  • Polymerization of carboxylated styrene-butadiene latex takes longer time than that of acrylic emulsion due to delocalization of radical in butadiene unit having conjugated double bond. A latex stability is the most important properties owing to use intact without separating polymer from base latex. For reducing polymerization time without decreasing any properties of latex, carbon tetra-chloride which has been used as the most popular chain transfer agent was replaced to combination of tert-dodecylmercaptane and ${\alpha}$-methylstyrene dimer. The replacement yielded reducement or 2 hr in polymerization time. In the increment step, charge amount of acrylic acid was limited to 0.3 part to restrain viscosity enhancement. Just after initial step, addition of 0.1 part acrylamide prevent polymer chain from diffusing between two region followed by giving hardness and final good adhesive force to latex particles.

Synthesis and Characterization of the Mixed-valence $[Fe^{II}Fe^{III}BPLNP(OAc)_2](BPh_4)_2$ Complex As a Model for the Reduced Form of the Purple Acid Phosphatase

  • Lee, Jae Seung;Jung, Dong J.;Lee, Ho Jin;Lee, Gang Bong;Heo, Nam Hoe;Jang, Ho G.
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.969-972
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    • 2000
  • [Fe II Fe III $BPLNP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)ami-no)methyl]-4-nitrophenol (HBPLNP) . Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electrochemical methods. Complex 1 exhibits two strong bands at 498 nm $(\varepsilon=$ 2.6 ${\times}10^3M-^1cm-^1)$ and 1363 nm $(\varepsilon=$ 5.7 ${\times}10^2M-^1cm-^1)$ in $CH_3CN.$ These are assigned to phenolate-to-FeIII and intervalence charge-transfer transitions, respectively. NMR spectrum of complex 1 exhibits sharp isotropically shifted resonances, which number is half of those expected for a valence-trapped species, indicating that electron transfer between FeⅡ and FeⅢ centers is faster than NMR time scale at room temperature. Complex 1 undergoes quasireversible one-electron redox processes. The $FeIII_2/FeIIFeIII$ and $FeIIFeIII/FeII_2$ redox couples are at 0.807 and 0.167 V ver-sus SCE, respectively. It has Kcomp = 5.9 ${\times}$10 1s(acetato) ligand combination sta-bilizes a mixed-valence FeIIFeIII complex in the air. Interestingly, complex 1 exhibits intense EPR signals at g = 8.56, 5.45, 4.30 corresponding to mononuclear high-spin FeⅢ species, which suggest a very weak magnetic coupling between the iron centers. Magnetic susceptibility study shows that there is a very weak antiferromag-netic coupling (J = $-0.78cm-^1$, H = $-2JS_1${\times}$S_2)$ between FeII and FeIII centers. Thus, we can suggest that complex 1 has a very weak antiferromagnetic coupling between the iron centers due to the electronic effect of the nitro group in the bridging phenolate ligand.

A New Model for the Reduced Form of Purple Acid Phosphatase: Structure and Properties of $[Fe_2BPLMP(OAc)_2](BPh_4)_2$

  • 임선화;이진호;이강봉;강성주;허남휘;Jang, Ho G.
    • Bulletin of the Korean Chemical Society
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    • v.19 no.6
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    • pp.654-660
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    • 1998
  • $[Fe^{II}Fe^{III}BPLMP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)amino) methyl]-4-methylphenol (HBPLMP). Complex I has been characterized by X-ray diffraction method as having (μ-phenoxo)bis(acetato)diiron core. Complex 1 was crystallized in the monoclinic space group C2/c with the following cell parameters: a=41.620(6) Å, b=14.020(3) Å, c=27.007(4) Å, β=90.60(2)°, and Z=8. The iron centers in the complex 1 are ordered as indicated by the difference in the Fe-O bond lengths which match well with typical $Fe^{III}-O\; and\; Fe^{II}-O$ bond lengths. Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electochemical methods. Complex 1 exhibits strong bands at 592 nm, 1380 nm in $CH_3CN$ (ε = 1.0 × 103 , 3.0 × 102). These are assigned to $phenolate-to-Fe^{III}$ and intervalence charge-transfer transitions, respectively. Its NMR spectrum exhibits sharp isotropically shifted resonances, which number half of those expected for a valence-trapped species, indicating that electron transfer between $Fe^{II}\;and\;Fe^{III}$ centers is faster than NMR time scale. This complex undergoes quasireversible one-electron redox processes. The $Fe^{III}_2/Fe^{II}Fe^{III}\;and\;Fe^{II}Fe^{III}/Fe^{II}_2$ redox couples are at 0.655 and -0.085 V vs SCE, respectively. It has $K_{comp}=3.3{\times}10^{12}$ representing that BPLMP/bis(acetate) ligand combination stabilizes a mixed-valence $Fe^{II}Fe^{III}$ complex in the air. Complex 1 exhibits a broad EPR signal centered near g=1.55 which is a characteristic feature of the antiferromagnetically coupled high-spin $Fe^{II}Fe^{III}$ system $(S_{total}=1/2)$. This is consistent with the magnetic susceptibility study showing the weak antiferromagnetic coupling $(J= - 4.6\;cm^{-1},\; H= - 2JS_1{\cdot}S2)$ between $Fe^{II}\; and \;Fe^{III}$center.

Design and Evaluation of the Internet-Of-Small-Things Prototype Powered by a Solar Panel Integrated with a Supercapacitor

  • Park, Sangsoo
    • Journal of the Korea Society of Computer and Information
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    • v.26 no.11
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    • pp.11-19
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    • 2021
  • In this paper, we propose a prototype platform combined with the power management system using, as an auxiliary power storage device, a supercapacitor that can be fast charged and discharged with high power efficiency as well as semi-permanent charge and discharge cycle life. For the proposed platform, we designed a technique which is capable of detecting the state of power cutoff or resumption of power supplied from the solar panel in accordance with physical environment changes through an interrupt attached to the micro-controller was developed. To prevent data loss in a computing environment in which continuous power supply is not guaranteed, we implemented a low-level system software in the micro-controller to transfer program context and data in volatile memory to nonvolatile memory when power supply is cut off. Experimental results shows that supercapacitors effectively supply temporary power as auxiliary power storage devices. Various benchmarks also confirm that power state detection and transfer of program context and data from volatile memory to nonvolatile memory have low overhead.

Joint Optimization of Mobile Charging and Data Gathering for Wireless Rechargeable Sensor Networks

  • Tian, Xianzhong;He, Jiacun;Chen, Yuzhe;Li, Yanjun
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.13 no.7
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    • pp.3412-3432
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    • 2019
  • Recent advances in radio frequency (RF) power transfer provide a promising technology to power sensor nodes. Adoption of mobile chargers to replenish the nodes' energy has recently attracted a lot of attention and the mobility assisted energy replenishment provides predictable and sustained power service. In this paper, we study the joint optimization of mobile charging and data gathering in sensor networks. A wireless multi-functional vehicle (WMV) is employed and periodically moves along specified trajectories, charge the sensors and gather the sensed data via one-hop communication. The objective of this paper is to maximize the uplink throughput by optimally allocating the time for the downlink wireless energy transfer by the WMV and the uplink transmissions of different sensors. We consider two scenarios where the WMV moves in a straight line and around a circle. By time discretization, the optimization problem is formulated as a 0-1 programming problem. We obtain the upper and lower bounds of the problem by converting the original 0-1 programming problem into a linear programming problem and then obtain the optimal solution by using branch and bound algorithm. We further prove that the network throughput is independent of the WMV's velocity under certain conditions. Performance of our proposed algorithm is evaluated through extensive simulations. The results validate the correctness of our proposed theorems and demonstrate that our algorithm outperforms two baseline algorithms in achieved throughput under different settings.

Effects of P2O5-doped on the Surface of MgO Particles for Hydrolysis, Water Repellency, and Insulation Behavior (MgO입자 표면에 도핑된 P2O5가 가수분해, 발수성, 그리고 절연거동에 미치는 영향)

  • Choi, Jin Sam
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.588-593
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    • 2022
  • The effects of P2O5-doped on the surface of MgO particles on hydrolysis, water repellency, and insulation behavior were investigated. P2O5-doped MgO has exhibited a unique electrical property, which is significant insulation behavior due to both the suppression of the hydrolysis reaction by P2O5 and water repellency. Therefore, the insulation behavior was inversely proportional to the hydrophilicity and the Mg(OH)2 and OH-charge transfer ratio by the surface hydration reaction of MgO. The insulation of MgO according to aging was strongly influenced by the surface hydration reaction, the band gap of the added dopant species, and the hydrophilicity and hydrophobicity of the dopant. Finally, it was to show electrical insulation by inhibiting the surface hydration reaction of the hydrophilic MgO, which has a great potential for use in heat transfer medium applications.

Experimental Study on the Working Fluid Selection of Medium Temperature Heat Pipe (중온 히트파이프에서 작동유체 선정에 관한 실험적 연구)

  • Lee, Young-Soo;Park, Ki-Ho;Baik, Young-Jin
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.3 no.2
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    • pp.1-7
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    • 2007
  • This paper is concerned with the selection of proper working fluids for medium temperature range heat pipe. The heat pipe which is made of SUS 316L has a total length of 700 mm as well as an outside diameter of 27.2 mm and a thickness of 2.1 mm respectively. Working fluids used in this study were Naphthalene, Biphenyl and Dowtherm A. Their charge amounts were about 40% of the inside volume of evaporator section. Experimental results shows that the Dowtherm A is good for $200^{\circ}C{\sim}300^{\circ}C$temperature range, while the Naphthalene is proper for $300^{\circ}C{\sim}430^{\circ}C$. In the case of the Naphthalene heat pipe, the heat transfer rate reaches 1500 W along with a vapor temperature of $430^{\circ}C$.

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An Effective Wireless Power Transfer Technique using Permalloy (Permalloy를 이용한 효율적 인 무선 전력송신 기술)

  • Hwang, Jae-Young;Chung, Yeon-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.3
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    • pp.678-683
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    • 2010
  • This paper presents a wireless (contactless) charging technique with a new core material called permalloy. For charging portable devices wirelessly, ferrosilicon or ferrite has been conventionally used. Due to high permeability of permalloy, charging efficiency can be significantly improved and subsequently this high efficiency increases charging distance between charger and portable devices. Comparative experimental studies demonstrate that the charging performance and efficiency with permalloy employed are significantly improved. The proposed wireless charging techniques can be used to charge portable devices efficiently.