• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.14 no.8
• /
• pp.617-625
• /
• 2002

In this study, effects of refrigerant and oil charges on the performance of a refrigeration system simulating an automobile air conditioner have been experimentally investigated using R134a and PAG oil. Measurements were taken in a breadboard type refrigeration test unit with a compressor used for a commercial automobile air-conditioner under a set of condition imposed upon normally to automobile air conditioners. Both the COP and capacity decreased rapidly as the oil charge increased because of the decrease in vapor pressure of the circulating refrigerant/oil mixture. The excess oil left in the evaporator also caused heat transfer degradation resulting in a decrease in capacity and in turn COP. It was found that there is an optimum refrigerant charge at which the COP becomes the maximum. Below this optimum charge, both the capacity and COP increased as the refrigerant charge increased and above the optimum charge, both of them remained almost constant. Hence, the COP seems to be the most important factor in determining the optimum refrigerant charge. When the system was undercharged, the refrigerant at the condenser exit lost subcooling and showed a sign of poor miscibility.

• KIEE International Transactions on Electrophysics and Applications
• /
• v.3C no.5
• /
• pp.189-193
• /
• 2003

Initial irreversible capacity (IIC) can be defined by means of the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface (IICs) with the linear-fit range of the intercalation so as to precisely express the irreversibility of an electrode-electrolyte system. Their relationship was IIC = Qc - Q$_{D}$ = (IIE$^{-1}$ - 1) Q$_{D}$ + IICs in the linear-fit range of IIE. Here, Qc and Qd signify charge and discharge capacity, respectively, based on a complete lithium ion battery cell. Charge indicates lithium insertion to carbon anode. Two terms of IIE and IICs depended on the types of active materials and compositions of the electrode and electrolyte but did not change with charging state. In an ideal electrode-electrolyte system, IIE and IICs would be 100%, 0 mAh/g for the electrode and mAh for the cell, respectively. These properties can be easily obtained by the Gradual Increasing of State of Charge (GISOC).OC).

• Journal of the Korean Ceramic Society
• /
• v.37 no.2
• /
• pp.128-133
• /
• 2000

In this work, soft carbons produced by pyrolysis of petroleum and coal-tar pitch were used as the negative electrode for Li-ion batteries. We studeid the charge/discharge capacity and the interfacial reaction of these electrodes by constructing a half cell. Charge/discharge property was studied by a constant-current step and the interfacial reaction between the electrolyte and the surface of a carbon electrode was studied by the cyclic voltammetry. The initial charge/discharge capacity for the coal-tar pitch carbon increased exceedingly with the heat treatment temperature. On hte other hand, the capacity of the petroleum pitch carbon increased with temperature up to 1000$^{\circ}C$, thereafter decreased continuously. While the charge capacity decreased with the cycle number, the reversibility increased above 90%. In addition, the thermal stability and crystallization of petroleum and coal-tar pitches were analyzed by TGA and XRD, respectively.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.11 no.1
• /
• pp.133-146
• /
• 1999

The charge operation of an ice storage system has been analyzed in this paper. The thermal characteristics of major components of the ice storage system. i.e., the refrigerator and the ice storage tank are evaluated from performance tests on an existing ice storage system. Based on the measured data for thermal characteristics, a simulation is carried out for the charge operation and the effect of the refrigerator size on the system performance is investigated. The results indicate that the larger the refrigerator size for a given storage capacity, the lower the inlet temperature of the ice storage tank so that the lower the efficiency of charge operation. It is also found that there exists an optimal size of the refrigerator with which the ice storage at the end of the charge operation is maximized, but the complete charge is not possible even with the optimally sized refrigerator. This leads to the result that the design capacity of the storage tank should be larger than the required amount of cold energy for the daytime cooling considering the practically chargeable amount of cold energy during the nighttime. Where the cooling load sharing of the storage is 40%, the nominal capacity of an ice storage tank needs to be larger than the required storage amount by 30%.

• 한국전기화학회:학술대회논문집
• /
• 1998.12a
• /
• pp.7-27
• /
• 1998

In order to design capacity of lithium ion battery, some calculations were carried out based on the characteristics of materials by the given battery shape and dimension. The principle of design was built by the interpretation of the correlation of material, electrochemical and battery factors. Parameters of materials are fundamental physical properties of constituent such as cathode. separator, anode, current collectors and electrolyte. Electrochemical factor includes potential pattern as a function of specific capacity, specific discharge capacity(or initial irreversible specific capacity or Ah efficiency) as a function of specific charge capacity and material balancing. Parameters of battery are dimension, construction hardware and performance. Battery capacity was simulated for a lithium cobalt dioxide as cathode and a hard carbon as anode to achieve 1100 mAh for the charge limit voltage of 4.2V, the weight ratio(+/-) of 2.4 and ICR18650. A fabricated test cell (ICR18650) which have weight ratio(+/-) of 2.4 discharged to 1093 mAh for the charge limit voltage of 4.2V. The sequential discharge capacity show good correspondence with designed capacity.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.19 no.7
• /
• pp.636-643
• /
• 2006

Si-C materials were synthesized by the heating the mixture of silicon and polyvinylidene fluoride (PVDF). The electrochemical properties of the Si-C materials as the high capacitive anode materials of lithium secondary batteries were evaluated by the galvanostatic charge-discharge test through 2032 type $Si-C{\mid}Li$ coin cells. Charge-discharge tests were performed at C/10 hour rate(C = 372 mAh/g). Initial discharge and charge capacities of $Si-C{\mid}Li$ cell using a Si-C material derived from PVDF(20wt.%) were found to be 1,830 and 526 mAh/g respectively. The initial discharge-charge characteristics of the developed Si-C electrode were analyzed by the electrochemical galvanostatic test adopting the capacity limited charge cut-off condition(GISOC). The range of reversible specific capacity IIE(intercalation efficiency at initial discharge-charge) and IICs(surface irreversible specific capacity) were 216 mAh/g, 68 % and 31 mAh/g, respectively.

• Journal of Electrical Engineering and Technology
• /
• v.13 no.2
• /
• pp.733-741
• /
• 2018

Capacity estimation is indispensable to ensure the safety and reliability of lithium-ion batteries in electric vehicles (EVs). Therefore it's quite necessary to develop an effective on-board capacity estimation technique. Based on experiment, it's found constant current charge time (CCCT) and the capacity have a strong linear correlation when the capacity is more than 80% of its rated value, during which the battery is considered healthy. Thus this paper employs CCCT as the health indicator for on-board capacity estimation by means of relevance vector machine (RVM). As the ambient temperature (AT) dramatically influences the capacity fading, it is added to RVM input to improve the estimation accuracy. The estimations are compared with that via back-propagation neural network (BPNN). The experiments demonstrate that CCCT with AT is highly qualified for on-board capacity estimation of lithium-ion batteries via RVM as the results are more precise and reliable than that calculated by BPNN.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.05a
• /
• pp.18-22
• /
• 2001

Spinel $LiMn_{2-y}Mn_{y}O_4$ powder was prepared solid-state method by calcining the mixture of $LiOH{\cdot}H_2O$, $MnO_2$ and MgO at $800^{\circ}C$ for 36h. To investigate the effect of temperature for cycle behaviour of cathode material during cycling, charge-discharge experiments and initial impedance spectroscopy performed by the condition of the charge-discharge temperature. Initial charge-discharge capacity was gradually increased by rising charge-discharge temperature. However, capacity was suddenly decreased at high temperature during cycling. Capacity at low temperature was almost constant during cycling. It confirmed because Mn dissolution is more serious at high temperature than at low temperature.

• Journal of the Korea Safety Management & Science
• /
• v.2 no.2
• /
• pp.187-200
• /
• 2000

The charge and discharge current in EPR(Ethylene Propylene Rubber), which were irradiated with the radiant capacity of 0~600 ［kgy/h］, have been measured in order to investigate the influence of the atmosphere (oxygen, air and vacuum) on electrical properties. It has been shown that the charge and discharge current increase as the amount of radiant capacity increases in air and vacuum atmosphere. This electrical property degradation can be speculated due to that the C＝O radicals or impurities, which comes from during shaping process, may act as dipoles. On the other hand, the charge and discharge current are shown to be higher in the amount of 1［kgy/h］ than these in 10［kgy/h］ in air atmosphere, because the charge and discharge current can be increased as the exposure time is extended with slower rate. Under the same amount of irradiation, the charge and discharge current in oxygen atmosphere are shown to be higher than those in vacuum. This is possibly due to that the main chain can be broken by oxidation when it is exposed to the $\gamma$ -rays.

• Journal of Electrical Engineering and Technology
• /
• v.10 no.3
• /
• pp.1102-1106
• /
• 2015

A hybrid supercapacitor (HS) is an energy storage device used to enhance the low weight energy density (Wh/kg) of a supercapacitor. On the other hand, a sudden decrease in capacity has been pointed out as a reliability problem after many charge/discharge cycles. The reliability problem of a HS affects the early aging process. In this study, the capacity performance of a HS was observed after charge/discharge. For detailed analysis of the initial charge/discharge cycles, the charge and discharge curve was measured at a low current density. In addition, a solid electrolyte interphase (SEI) layer was confirmed after the charge/discharge. A HC composed of a lithium titanate (LTO) anode and active carbon cathode was used. The charge/discharge efficiency of the first cycle was lower than the late cycles and the charge/discharge rate was also lower. This behavior was induced by SEI layer formation, which consumed Li ions in the LTO lattice. The formation of a SEI layer after the charge/discharge cycles was confirmed using a range of analysis techniques.