• Title/Summary/Keyword: Charge Exchange

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A Study on the condition for the Sustainable Exchanges Between Cities and Rural Areas - Focused on the case of Setagaya Ward and Gawaba Village in Japan - (지속적인 도농교류의 조건에 관한 관찰 - 일본의 세타가야구(世田谷區)와 가와바촌(川場村) 사례를 중심으로 -)

  • Bae, Jung-Nam
    • Journal of Korean Society of Rural Planning
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    • v.16 no.1
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    • pp.73-80
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    • 2010
  • This study aims at providing necessary resources in developing the sustainable project of the exchanges between cities and rural areas in Korea. And so I investigated and analyzed the model of the Setagaya Ward and the Gawaba Village in Japan, which has successively continued the exchanges between city and rural areas for thirty years, with the documentation, field work, interviews and field investigation. The two local autonomous entities have promoted the project of the exchanges between cities and rural areas by keeping in touch with a making the second home and linking agriculture with sightseeing. They passed an agreement of mutual help and established regulations to push forward the agreement in order to carry out the agreement. And they have operated a section which will do nothing but focus on this, established a management company which takes charge of the stronghold facilities of the exchange between city and rural areas, operated a caucus to examine the project steadily and to develop new programs, and made a publicity work continually for thirty years. In conclusion, I think we should promote the joint capital stronghold facilities of the exchange between city and rural areas which is based upon the agreements. And we should promote the infrastructure like a management company which takes charge of the facilities and build the proper foundation which can develop the various programs for the exchange between city and rural areas and operate them.

A Study on the Electrochemical Hydrogenation Reaction Mechanism of the Laves Phase Hydrogen Storage Alloys (Laves phase계 수소저장합금의 전기화학적 수소화 반응 매카니즘에 관한 연구)

  • Lee, Ji-Youl;Kim, Chan-Jung;Kim, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.1
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    • pp.31-41
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    • 1997
  • In order to investigate the mechanism of electrochemical hydrogenation reaction on Zr-based Laves phase hydrogen storage alloy electrodes, electrochemical charge/discharge characteristics, potentiostatic/dynamic polarizations and electrocehmical impedance spectroscopy(EIS) of Zr-Ti-Mn-Ni and Zr-Ti-Mn-Ni-M(M=Fe, Co, Al) alloys were examined. Electrochemical discharge capacities of the alloys were quite different with gas charge capacities. Therefore, it was considered that discharge capacities of the alloys depend on electrochemical kinetic factors rather then thermodynamic ones. Discharge efficiencies were increased linearly with exchange current densities. The results of potentiostatic/dynamic polarization measurements showed that electrochemical charge and discharge reaction of Zr-based Laves phase hydrogen storage alloys is controlled by charge transfer process at the electrode surface. The EIS measurements also confirmed this result.

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Cation Exchange Capacity and Zeta Potential Characteristics of Kaolinite Contaminated with Lead (납으로 오염된 카올리나이트의 양이온교환능력 및 계면동전위 특성)

  • 장경수;강병희
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.38-43
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    • 2002
  • A series of tests were performed to investigate the effects of pH and contamination level on cation exchange capacity and zeta potential in kaolinite loaded with lead. Test results show that cation exchange capacity of kaolinite is found to be in the range from 4 to 20meq/100g and it increased with increasing pH up to the converged number about 20meq/100g over pH 8. And then CEC has a tendency to reduce and converge to zero with increasing the concentration of Pb in the kaolinite surface. Moreover, zeta potential of kaolinite contaminated with lead is found to be in the range from -10 to 5mV, and zero point of charge is measured at about pH 3.5. Zeta potential of kaolinite contaminated with lead decreases with increasing pH values and decreasing Pb concentration of kaolinite.

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A Numerical Solution of Transport of Mono- and Tri-valent Cations during Steady Water Flow in a Binary Exchange System

  • Ro, Hee-Myong;Yoo, Sun-Ho
    • Journal of Applied Biological Chemistry
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    • v.43 no.1
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    • pp.18-24
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    • 2000
  • A one-dimensional transport of displacing monovalent ion, $A^+$, and a trivalent ion being displaced, $B^{3+}^ in a porous exchange system such as soil was approximated using the Crank-Nicolson implicit finite difference technique and the Thomas algorithm in tandem. The variations in the concentration profile were investigated by varying the ion-exchange equilibrium constant (k) of ion-exchange reactions, the influent concentrations, and the cation exchange capacity (CEC) of the exchanger, under constant flux condition of pore water and dispersion coefficient. A higher value of k resulted in a greater removal of the native ion, behind the sharper advancing front of displacing ion, while the magnitude of the penetration distance of $A^+$ was not great. As the CEC increased, the equivalent fraction of $B^{3+}^ initially in the soil was greater, thus indicating that a higher CEC adsorbed trivalent cations preferentially over monovalent ions. Mass balance error from simulation results was less than 1%, indicating this model accounted for instantaneous charge balance fairly well.

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Preparation and Electrochemical Applications of Pore-filled Ion-exchange Membranes with Well-adjusted Cross-linking Degrees: Part I. All Vanadium Redox Flow Battery (가교도가 조절된 세공충진 이온교환막의 제조 및 전기화학적 응용: Part I. 전 바나듐 레독스 흐름전지)

  • Lee, Ji-Eun;Park, Ye-Rin;Kim, Do-Hyeong;Kang, Moon-Sung
    • Membrane Journal
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    • v.27 no.5
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    • pp.406-414
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    • 2017
  • In this study, we have developed pore-filled ion-exchange membranes (PFIEMs) filled with ionomer in a thin polyethylene porous film (thickness = $25{\mu}m$) and investigated the charge-discharge characteristics of the all vanadium redox flow battery (VRFB) employing them. Especially, the degree of crosslinking and free volume of the PFIEMs were appropriately controlled to produce ion-exchange membranes exhibiting both the low membrane resistance and low vanadium permeability by mixing crosslinking agents having different molecular size. As a result, the prepared PFIEMs exhibited excellent electrochemical properties which are comparable to those of the commercial membranes. Also, it was confirmed through the experiments of vanadium ion permeability and VRFB performance evaluation that the PFIEMs showed low vanadium ion permeability and high charge-discharge efficiency in comparison with the commercial membrane despite their thin film thickness.

Dynamic Transient Phenomena of Proton Exchange Membrane Fuel Cell

  • Lee, Ying;Choi, Yong-Sung;Zhang, You-Sai;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.9-9
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    • 2010
  • The proton exchange membrane fuel cell (PEMFC) holds great promise of clean power. However, in practical applications which use the PEMFC as the power source, the output voltage from the fuel cell undergoes transient response especially during acceleration and deceleration. This paper presents the relationships between the internal voltage drop, voltage of time constant, time constant of FC1 and FC2 (in series and in parallel) charge curves and discharge curves respectively.

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Dynamic Transient Phenomena of a Proton Exchange Membrane Fuel Cell

  • Lee, Ying;Choi, Yong-Sung;Zhang, You-Sai;Lee, Kyung-Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.7
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    • pp.530-533
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    • 2010
  • The proton exchange membrane fuel cell (PEMFC) holds great promise of clean power. However, in practical applications which use the PEMFC as the power source, the output voltage from the fuel cell undergoes a transient response especially during acceleration and deceleration. This paper presents the relationships between the charge curves of the internal voltage rise, discharge curves of the internal voltage drop, the voltage with a time constant $V_{\tau}$ and finally, the load and time constant $\tau$ of $FC_1$ and $FC_2$, connected both in series and in parallel.

SPECTRAL DIAGNOSTICS OF NON-THERMAL PARTICLES IN THE SOLAR CHROMOSPHERE

  • FANG C.;XU Z.;DING M. D.
    • Journal of The Korean Astronomical Society
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    • v.36 no.spc1
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    • pp.55-61
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    • 2003
  • There are at least three effects of the non-thermal particle bombardment on the solar atmosphere: (1) non-thermal ionization and excitation; (2) proton-hydrogen charge exchange; (3) impact line polarization. Due to the non-thermal ionization and excitation effects of electron bombardments in flares, H$\alpha$ line is widely broadened and shows a strong central reversal. Significant enhancements at the line wings of Ly$\alpha$ and Ly$\beta$ are also predicted. In the case of proton bombardment, less strong broadening and no large central reversal are expected. However, due to proton-hydrogen charge exchange, the enhancements at the red wings of Ly$\alpha$ and especially of Ly$\beta$ lines at the early impulsive phase of flares are significant. Electron beam can also in some cases generates visible and UV continuum emission in white-light flares. However, at the onset phase, a negative 'black' flare may appear in several seconds, due to the increase of the $H^-$ opacity. The impact polarization of atomic lines can provide complementary information on the energetic particles, the energy transport and deposit in the solar chromosphere. New results of spectropolarimetric analysis for the major flare on July 23, 2002 are also given in the paper.