• Title/Summary/Keyword: Charge/discharge cycle

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Development of a new Li-Ion Pack-Battery for improving the electrical properties (전기적인 특성향상을 위한 리튬이온전지팩 개발)

  • Gang, Young-Gu;Kweon, Hyun-Kyu;Seo, Myung-Su;Park, Chang-Yong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.8 no.2
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    • pp.90-95
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    • 2009
  • This paper presents a new lithium ion unit-cell and pack battery by using a new formulation ratio of material. The three types of formulation ratio for the unit-cell were used. The life cycle and basic properties of the lithium ion unit-cell$({\Psi}18{\times}65(mm))$ about one of them were acquired by the charge-discharge experiment. The nominal voltage, nominal capacity and cycle life output of the lithium ion unit-cell is respectively 3.7V, 2.4Ah, and above 500cycle. Pack type lithium ion battery has the size of $29.5{\times}73.5{\times}115(mm)$ and the weight of 300g. As the results, the weight and bulk of lithium ion battery used to a safety lamp were decreased to 1/4 and 1/7. In addition, the comparison of the new lithium ion battery and lead storge battery for confirming the effectiveness of the new lithium ion battery have been performed.

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A Study on the Design and Implementation of Charge and Discharge-Tester for Capacitors (콘덴서 양부판정용 충·방전 시험기 설계와 구현에 관한 연구)

  • Moon, Jong-Hyun;Kim, Geum-Soo;Park, Jae-Wook;Seo, Chul-Sik;Kim, Dong-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.9
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    • pp.71-78
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    • 2010
  • The existing capacitor-testers could only judge the condition of capacitor is normal or abnormal, and could not inform the real characteristics of the tested capacitors. In this research, it has designed the real-time observation of the new capacitor in charge and discharge tester for showing capacitor conditions and classification through wide voltages by regular cycle-tests. And proposed the quality classification algorithm of capacitors for more simple and practical, and approve them by test.

A Novel Sulphur Cathode Materials for Rechargeable Lithium Batteries

  • Jin, Bo;Park, Kyung-Hee;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.4
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    • pp.157-160
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    • 2007
  • Lithium-sulphur batteries were fabricated in a dry room, and their electrochemical properties were analyzed by scanning electron microscopy (SEM), cyclic voltammetry (CV), and charge-discharge tests. SEM results showed that sulphur and nanocarbon powders were mixed homogeneously, and sulphur powders were enwrapped by a large amount of carbon powders. The charge-discharge test results demonstrated that the lithium-sulphur battery displayed excellent reversibility and cycling performance, which supplied a discharge capacity of $788.1mAh\;g^{-1}$ at the first cycle and $796.4mAh\;g^{-1}$ after 71 cycles at room temperature, respectively.

Charge/discharge Properties of $V_{2}O_{5}$ Composite with different Voltage range for Supercapacitor (Supercapacitor용 $V_{2}O_{5}$ Composite의 전압영역에 따른 충방전 특성)

  • 김명산;김종욱;구할본;박복기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.507-510
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    • 2000
  • The purpose of this study is to research and developV$_2$O$_{5}$-SP270 composite electrode for supercapacitor. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-carbon composite electrode for supercapacitor with different voltage range. Suprcapacitor cell of V$_2$O$_{5}$-SP270 composite electrode with 25PVDFLiC1O$_4$PC$_{10}$ polymer electrolyte bring out good capacitor performance below 3V. The discharge capacitance of SP270 in 1st cycles was 13F/g at 0.1mA/cm$^2$, 3V. We performed cycle voltammogram, charge/discharge property.y.rty.y.

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Charge/Discharge Properties of $V_{2}O_{5}$-Flyash Composite electrode for Supercapacitor (Supercapcitor용 $V_{2}O_{5}$-Flyash Composite 전극의 충방전 특성)

  • 김명산;김종욱;구할본;박복기
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.335-338
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    • 2000
  • Carbon is an attractive candidate for use in eletrochemical supercapacitors that depend on charge storage in the electrode/electrolyte international double layer. Property of an electrical double layer capacitor depend both on the technique used to prepare the electrode and on the current collector structure. The study is to research that V$_2$O$_{5}$-flyash-AC composite electrode for supercapacitor. The discharge capacitance of V$_2$O$_{5}$-flyash-AC(70wt%) in 1st and 50th cycle was 18.6F/g and 15.13F/g at current density of 0.5mA/cm$^2$. The discharge process of V$_2$O$_{5}$-flyash (3 : 97)-AC composite electrode is larger than that others.thers.

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The electrochemical properties of $LiFe_xMn_{1-x}PO_4$ cathode materials for lithium polymer batteries (리튬 폴리머 전지용 $LiFe_xMn_{1-x}PO_4$ 정극활물질의 전기화학적 특성)

  • Jun, Dae-Kyoo;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.424-425
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    • 2005
  • The purpose of this study is to research and develop $LiFe_xMn_{1-x}PO_4$ cathode for lithium polymer batteries. $LiFe_xMn_{1-x}PO_4$ cathode active materials were prepared using a solid-state reaction by adding carbon black to the synthetic precursors. We investigated cyclic voltammetry and charge/discharge cycling of $LiFe_xMn_{1-x}PO_4$/SPE/Li cells. The discharge capacity of $LiFe_{0.5}Mn_{0.5}PO_4$ was l26mAh/g and 110mAh/g at 1st and 10th cycle.

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Charge-discharge Behaviour of Lithium Ion Secondary Battery Using LiCo$O_2$ Synthesized by a Solution Phase Reaction (액상 반응에 의해 합성한 리튬코발트산화물을 이용한 Lithium ion 2차전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수;심윤보
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.1049-1054
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    • 1998
  • The LiCo$O_2$ powder was synthesized by a solution phase reaction. This shows a high (003) peak intensity and low (104) or (101) peak intensities in X-ray diffraction spectra. The LiCo$O_2$/Li cell shows an initial discharge capacity of 102.9mAh/g and an average discharge potential or 3.877V at a current density of 50mA/g between 3.0~4.2V. The peaks of dQ/dV plot are associated with Li ion intercalation/deintercalation reaction. To evaluate the cycleability of an actual battery system, cylindrical lithium ion cell was manufactured using graphitized MPCF anode and LiCoO$_2$ cathode. After 100th cycle, this cel maintains 80% capacity of 10th cycle value. The LiCoO$_2$/MPCF cell has a high discharge voltage of 3.6~3.7V and a good cycle life performance on cycling between 4.2~2.7V.

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The Electrode Characteristics of the Zr-based Hydrogen Absorbing Alloy Fabricated by the Rapid Solidification Process (급속응고법으로 제작한 Zr기 수소저장합금의 전극특성)

  • Han, Dong-Su;Jeong, Won-Seop;Kim, In-Gon
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.386-391
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    • 1999
  • The charge-discharge, the high-rate dischargeability, and the self discharge characteristics of the electrodes composed of rapidly solidified ZrV\ulcornerMn\ulcornerMo\ulcornerNi\ulcorneralloy, which has the form of partial substitution of Mn, Mo, Ni for V in $ZrV_2$ were studied. The alloys were prepared using Arc & RSP(Rapid Solidification Process) at the rotating roller speed of 2000 and 5000 rpm. Some of them were received heat treatment at$ 560 ^{\circ}C$ for 1 hour after the solidification to investigate the effect of the heat treatment. It was fond that cycle life was significantly improved by RSP, whereas discharge capacity, activation rte and high rate dischargeability were decreased compared with the conventional arc melting method. The capacity loss seems to be due to the loss of the crystallinity and the increase of the cycle life ascribed to the presence of the amporphous phase as well as the refined grain size of less than 0.2$\mu\textrm{m}$. Heat treatment of the alloy cooled at 2000 rpm improved the cycle life. In case of the alloys cooled at 5000 rpm, both the discharge capacity and the activation rate were significantly improved by the heat treatment.

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Electrochemical Properties of Graphene Composite for Lithium Polymer Battery (리튬 폴리머전지용 Graphene Composite의 전기화학적 특성)

  • 김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.359-362
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    • 2000
  • The purpose of this study is to research and develop graphene composite for lithium polymer battery. VO(graphene) composite is one of the promising material as a electrode active material for lithium polymer battery(LPB). We investigated AC impedance response and charge/discharge cycling of VO(graphene)/SPE/Li cells. The first discharge capacity of VO(graphene) cathode with 50wt.% V$_2$O$\sub$5/ was 150mAh/g, while that of VO(graphene) cathode with 85wt.% V$_2$O$\sub$5/ was 248mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The discharge capacity of VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ was 718 and 266mAh/g at cycle 1 and 10 at room temperature, respectively. The VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ in PVDF-PAN-PC-EC-LiC1O$_4$ electrolyte showed good capacity with cycling.

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The electrochemical property of $LiMg_xMn_{2-x}O_4$cathode materials substituted Mg (Mg 치환된 $LiMg_xMn_{2-x}O_4$정극 활물질의 전기화학적 특성)

  • 정인성;박계춘;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.387-390
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    • 1999
  • To improve the cycle performance LiM $n_2$ $O_4$as the cathode of 4V class lithium secondary batteries, the cathode properties of the cubic spinel phases LiM $g_{x}$ /M $n_{2-x}$/ $O_4$ synthesized at 80$0^{\circ}C$ were examined. All cathode material showed spinel phase based on cubic phase in X-ray diffraction however. other peaks gradually exhibited and became intense with the increase of x value in LiM $g_{x}$ /M $n_{2-x}$/ $O_4$. The cycle performance of the LiM $g_{x}$ /M $n_{2-x}$/ $O_4$was improved by the substitution of $Mg^{2+}$ for M $n^{3+}$ in the octahedral sites. Specially LiM $g_{0.1}$/M $n_{1.9}$ / $O_4$cathode materials showed the charge and discharge capacity of about 130~125mAh/g at first cycle and about 105mAh/g after 50th cycle. It is excellent than that of pure LiM $n_{2}$/ $O_4$ which 125mAh/g at first cycle 70mAh/g at 50th. In addition cathode material prepared at 80$0^{\circ}C$ for 24hr and 42hr in the charge and discharge capapcity as well as the cycle stability.ility.y.y.

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