• 한국고분자학회:학술대회논문집
• /
• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
• /
• pp.249-249
• /
• 2006

We have prepared an amphiphilic wedge-coil molecule consisting of a hydrophobic wedge-like segment and a hydrophilic poly(ethylene oxide) (PEO) segment. The wedge-coil block molecule self-assembles into cylindrical nanofibers in both polar as well as nonpolar solvents. Remarkably, the resulting nanofibers, as solvent polarity change from water to n-hexane, change from highly flexible coil-like to stiff rod-like characteristics. This dynamic switching in the stiffness of the nanofibers in response to solvent polarity is attributed to the structural inversion of cylindrical core from bulky dendritic segments with amorphous nature to crystallizable linear PEO segments.

• Carbon letters
• /
• 제13권4호
• /
• pp.248-253
• /
• 2012

Dielectrophoretic filtering and alignment of single-walled carbon nanotubes (SWCNTs) were tested using deuterium oxide as a solvent. A solution of deuterium oxide-SWCNTs was dropped on top of a silicon chip and an ac electric field was applied between pre-defined electrodes. Deuterium oxide was found to be a better solvent than hydrogen oxide for the dielectrophoresis process with higher efficiency of filtering. This was demonstrated by comparing Raman spectra measured on the initial solution with those measured on the filtered solution. We found that the aligned nanotubes along the electric field were not deposited on the substrate but suspended in solution, forming chain-like structures along the field lines. This so-called pearl chain formation of CNTs was verified by electrical measurements through the aligned tubes. The solution was frozen in liquid nitrogen prior to the electrical measurements to maintain the chain formation. The current-voltage characteristics for the sample demonstrate the existence of conduction channels in the solution, which are associated with the SWCNT chain structures.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1995년도 추계학술대회 논문집 학회본부
• /
• pp.395-397
• /
• 1995

To investigate the effects of solvent extraction on electrical properties of LDPE, charge distribution, electrical conduction, and FT-IR experiments are carried out for three kinds of LDPE which are same for melt index (MI) and density. The effects of short chains for the charge distribution are quite different. For the electrical conduction, the electrical conduction mechanism remains unchanged, as the solvent extraction temperature is increased.

• 한국분말재료학회지
• /
• 제9권4호
• /
• pp.218-226
• /
• 2002

The purpose of the present study is to investigate the influence of thermal debinding and sintering conditions on the sintering behavior and mechanical properties of PIMed 316L stainless steel. The water atomized powders were mixed with multi-component wax-base binder system, injection molded into flat tensile specimens. Binder was removed by solvent immersion method followed by thermal debinding, which was carried out in air and hydrogen atmospheres. Sintering was done in hydrogen for 1 hour at temperatures ranging from 1000℃ to 1350℃ The weight loss, residual carbon and oxygen contents were monitored at each stage of debinding and sintering processes. Tensile properties of the sintered specimen varied depending on the densification and the characteristics of the grain boundaries, which includes the pore morphology and residual oxides at the boundaries. The sinter density, tensile strength (UTS), and elongation to fracture of the optimized specimen were 95%, 540 MPa, and 53%, respectively.

• 한국기계가공학회지
• /
• 제10권2호
• /
• pp.61-66
• /
• 2011

The purpose of this paper is to design a hydraulic actuator to operate under high pressure conditions. The flow characteristics under design conditions of hydraulic actuator were numerically conducted by commercial fluid dynamic code(ANSYS CFX V11). The numerical analysis was performed by transient technique according to the variation of stroke times, which was changed from 0 to 1 second by interval of 0.01. Turbulence model, $k-\omega$ SST was selected to secure more accurate prediction of hydraulic oil flow. The ICEM-CFD 11 and CFXMesher, reliable grid generation software was also adapted to secure high quality grid necessary for the reliable analysis. According to the simulation results, the flow rate which was supplied to the hydraulic actuator was 30.4l/min. These results are in good agreement with design results within 3.5% error.

• 대한화학회지
• /
• 제16권3호
• /
• pp.149-156
• /
• 1972

메타놀, N,N-디메칠포름아미드 및 아세토니트릴 속에서 유리전극의 pH 응답성을 여러가지 pH의 완충용액으로 시험한 바 전극을 물속에 보관하는 것보다 측정하고저 하는 용매속에 보관하는 것이 더 빨리 전위가 안정되었다. 같은 용매에서 용액의 염기성에 비례하여 응답속도가 느리고 강염기성 용액에서는 안정한 전위를 얻기 어려웠다. 산성용액에서의 pH 응답성은 보다 빠르나 같은 용액의 pH 측정에서도 전극의 사용한 이력에 따라 응답성과 측정치에 차이가 생겼다.

• Bulletin of the Korean Chemical Society
• /
• 제32권7호
• /
• pp.2212-2216
• /
• 2011

An ionic liquid-based ultrasonic-assisted extraction method has been successfully applied to the effective extraction of phenolic compounds from Laminaria japonica Aresch. Three kinds of 1-alkyl-3-methyl-imidazolium with different cations and anions were evaluated for extraction efficiency. The results showed that both the characteristics of anions and cations have remarkable effects on the extraction efficiency. In addition, the ionic liquid-based ultrasonic-assisted extraction procedure was also optimized on some extraction parameters, such as ultrasonic power, extraction time and solid-liquid ratio. Compared with the conventional solvent, the optimum approach gained the highest extraction efficiency within the shortest extraction time. Average recoveries of phenolic compounds were from 75.5% to 88.3% at three concentration levels.

• 한국염색가공학회지
• /
• 제14권2호
• /
• pp.109-109
• /
• 2002

A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

• 한국염색가공학회지
• /
• 제14권2호
• /
• pp.33-39
• /
• 2002

A study has been made of the dry-jet-wet spinning of PAN copolymer fibers using 60% aqueous zinc chloride solution as solvent and 25∼40% aqueous zinc chloride solution as non-solvent. The technological characteristics of this method were that small streams of dope were extruded from the die and allowed to pass through a short distance of air gap(about 10mm) before entering the spinning bath for full coagulation. This work showed the importances which coagulation condition, stretch ratio and fiber tenacity up to 10.5 g/d could be obtained with elongation of 11∼16%. Individual fibers were evaluated on the basis of density and mechanical properties such as tenacity and elongation etc.

• 공업화학
• /
• 제26권3호
• /
• pp.275-279
• /
• 2015

전도성 고분자인 poly(3,4-ethylenedioxythiophene) : poly(styrenesulfonate) (PEDOT : PSS)는 우수한 전기 전도도와 광투과도, 유연성을 가지고 있기 때문에 유기태양전지와 유기발광소자의 투명전극으로서 많은 각광을 받고 있다. PEDOT : PSS의 전기 전도도는 솔벤트를 도핑함에 따라 큰 폭으로 증가한다는 사실은 잘 알려져 있다. 본 연구에서는 다양한 솔벤트의 도핑과 솔벤트 후처리 공정에 따른 PEDOT : PSS 박막의 전기 전도도와 구조적 특성 변화를 연구하였다. 솔벤트 도핑으로 PEDOT : PSS의 전도도는 884 S/cm까지 증가하였고, 후처리 공정을 통해서 1131 S/cm의 전도도 값을 얻을 수 있었다. 이러한 전도도의 증가는 PSS 물질이 빠져나가거나 구조적인 재배열에 따른 전도성 PEDOT 입자의 접촉 면적이 증가함에 따른 것으로 사료되고, 광학적인 방법으로 PSS의 추출을 관찰하였다. 솔벤트 후처리 공정은 PEDOT : PSS 박막의 전도도를 향상하는 매우 효과적인 방법으로 확인되었고, 저가형 플렉서블 유기전자소자의 투명전극으로써의 사용이 적합할 것으로 예상된다.