• Environmental Engineering Research
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• v.17 no.3
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• pp.145-150
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• 2012

Pb-contaminated soil at a clay shooting range was analyzed by the sequential extraction method to identify metal binding properties in terms of detrital and non-detrital forms of the soil. Most of the metals in the soils existed as non-detrital forms, exchangeable and carbonate-bound forms, which could be easily released from the soil by a washing method. Therefore, the characteristics of Pb desorption for remediation of the Pb-contaminated soil were evaluated using hydrochloric acid (HCl) by a washing method. Batch experiments were performed to identify the factors influencing extraction efficiency. The effects of the solid to liquid (S/L) ratio (1:2, 1:3, and 1:4), soil particle size, and extraction time on the removal capacity of Pb by HCl were evaluated. Soil samples were collected from two different areas: a slope area (SA) and a land area (LA) at the field. As results, the optimal conditions at 2.8 to 0.075 mm of particle size were 1:3 of the S/L ratio and 10 min of extraction time for SA, and 1:4 of the S/L ratio and 5 min of extraction time for LA. The characteristics of Pb desorption were adequately described by two-reaction kinetic models.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.11 no.5
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• pp.394-399
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• 1998

High power characteristics with vibration velocity were studied in $Pb(Y_{2/3}W_{1/3})O_3-Pb(Zr,Ti)O_3$(PYW-PZT) ceramics by using the constant current method. Young s modulus $Y_0^E$ and mechanical quality factor $Q_m$ are a function of the square of effective vibration velocity \upsilon_0$. The nonlinear proportional constants of the above functions indicate the degree of stability under the vibration level change. The stability of PYW-PZT ceramics estimated by these constants coincides with the results obtained through the heat generation. It was found that $Q_m$ was markedly decreased with increasing the vibration velocity, accompanying a lot of heat generation. The vibration hysteresis and dielectric loss according to the vibration velocity was reduced by doping $Fe_2O_3$to the ceramics. On the contrary, these losses was increased by doping $Nb_2O_5$.

• Proceedings of the Korean Ceranic Society Conference
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• 2002.10a
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• pp.161.2-161
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• 2002

• Journal of the Korean Ceramic Society
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• v.39 no.9
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• pp.863-870
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• 2002

The Single phase $Pb(Fe_{1/2}Ta_{1/2})O_3$ (x=0.0∼1.0) solid solutions were successfully synthesized and their ordering structures as well as dielectric properties were investigated ${{r(Nb^{5+})=r(Ta^{5+})=0.78 {\AA},\;AW(Nb^{5+})=92.91,\;AW(Ta^{5+})=180.95}}$. While $Pb(Fe_{1/2}Ta_{1/2})O_3$ showed typical relaxor ferroelectric characteristics such as dielectric relaxation and diffuse phase transition, the sharpeness of the phase transition increased as $Ta^{5+}$ was replaced by $Nb^{5+}$ and finally $Pb(Fe_{1/2}Nb_{1/2})O_3$ showed normal ferroelectric characteristics with no dielectric relaxation. By using Raman spectroscopy, it was revealed that the $Fe^{3+}\;and\;Ta^{5+}\;of\;Pb(Fe_{1/2}Ta_{1/2})O_3$ were stoichiometrically 1:1 ordered within the short range which can be hardly probed even by TEM. Also, The degree of ordering in $Pb(Fe_{1/2}Ta_{1/2})O_3$ decreased as $Ta^{5+}$ was replaced by $Nb^{5+}$ and finally $Fe^{3+}\;and\;Nb^{5+}\;of\;Pb(Fe_{1/2}Nb_{1/2})O_3$ were completely disordered. The relaxor ferroelectric characteristics of $Pb(Fe_{1/2}Ta_{1/2})O_3$ could be correlated with the stoichiometric 1:1 ordering of B-site cations within the short range which can be hardly probed even by TEM. Also, the decrease of the relaxor ferroelectric characteristics with the replacement of $Ta^{5+}\;by\;Nb^{5+}$ could be correlated with the weakening of the ordering and the normal ferroelectric characteristics of $Pb(Fe_{1/2}Nb_{1/2})O_3$ could be correlated with the complete disordering of B-site cations.

• Korean Journal of Materials Research
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• v.17 no.1
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• pp.43-49
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• 2007

Electrochemical migration phenomenon is correlated with ionization of anode electrode, and ionization of anode metal has similar mechanism with corrosion phenomenon. In this work, in-situ water drop test and evaluation of corrosion characteristics for SnPb solder alloys in $Na_2SO_4$ solutions were carried out to understand the fundamental electrochemical migration characteristics and to correlate each other. It was revealed that electrochemical migration behavior of SnPb solder alloys was closely related to the corrosion characteristics, and Sn Ivas primarily ionized in ${SO_4}{^2-}$ solutions. The quality of passive film formed at film surface seems to be critical not only for corrosion resistance but also for electrochemical migration resistance of solder alloys.

• Proceedings of the KIEE Conference
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• 1987.11a
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• pp.187-190
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• 1987

This paper is for the charge storage effect and C-V characteristics of MIS type diode which is the basic structural unit of charge-coupled device after growing the $Pb_{1-x}Sn_xTe$ crystal. $Pb_{1-x}Sn_xTe$ singlecrystal dbtained from the horizental furnace using Bridgman method. To judge whether the grown singlecrystal is suitable for specimen or not, it was investigated by X-ray diffraction analysis, thermogravimetry and differential thermal analysis. The C-V characteristics of the specimen caused to anodic oxidation was the best when the insulator film's depth was 250[$\AA$]. Measuring the C-V characteristics aftermanufacturing MIS type diode resulted that the whole capacitance was the largest when the supply voltage was low, 0.3[V] and the capacitance also varied according to the variance frequence when the supply voltage is over 0.5[V]. From the above result, even if the supply voltage is low, the $Pb_{1-x}Sn_xTe$ also have a good charge storage effect.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.11a
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• pp.13-16
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• 1994

In this paper, xPb(Zn$_{1/3}Nb_{2/3}$)$O_3$-yPbTiO$_3$-zPbZrO$_3$-(0.5wt%)MnO$_2$ ceramics were fabricated by the mixed oxide method sintered at $1250^{\circ}C$ for 2[hr] and then the deielectric, electromechanical coupling factor($K_{p}$ and mechanical coupling factor(Qm) properties were investigated. In 0.1PZN-0.45PT-0.45PZsample, dielectric properties and electromechanical coupling factor were 829 and 29%. In the case of 0.5PZN-0.45PT-0.50PZ sample, that was 101 according to mechanical quality facotr. molphotropic phase boundary(MPB) certained area which $PbTiO_3$addition quatity 40∼50[㏖%].

• Journal of the Korean Ceramic Society
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• v.23 no.3
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• pp.21-26
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• 1986

In this study the system of $Pb(Mn_{1/3} Nb_{2/3})O_3-PbTiO_3-PbZrO_3$ piexoelectric ceramics was made in the radial mode disk and attenuation characteristic of the desinged ladder type filter was investigated. What is more temperature dependance of resonant frequency and variation of resonant frequency was examined by chan-ging the electrode diameter of piezoelectric resonator. (A Group : De=11mm, B Group : De=7.5mm and C Gro-up : De=5.5mm) Upon investigation it was the following. The center frequency of A, B and c filter showed up in the 200KHz, 270KHz and 380KHz respectively. As the electrode diameter decreased center frequency in creased abruptly. As the Co_2/Co1 increased attenuation characteristics and selectivity was improved. As the x=50. resonant frequ-ency invaried with variation of temperature.

• Journal of the Korean Ceramic Society
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• v.30 no.7
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• pp.543-548
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• 1993

Stability and formation of Pb(Mg1/3Nb2/3)O3 (PMN) phase synthesized in Li2SO4-Na2SO4 molten salts have been investigated. And powder characteristics of PMN have been studied with a variation of processing parameters such as temperature, time, amount of the salts, and excess PbO. More ratio of Li2SO4 to Na2SO4 influences the percentage of perovskite phase due to the difference of the eutectic point of the salts, but does not influence the powder characteristics. The shape of PMN particles shows faceted morphology with bimodal distribution consisting with large and submicron parts. Particle size of PMN increased greatly with increasing soaking time or amount of salts rather than temperature. The addition of excess PbO resulted in round PMN crystallites without submicron particles. These results are discussed by XRD, SEM and thermal analyses.

• Korean Journal of Materials Research
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• v.5 no.8
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• pp.905-912
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• 1995

Influences of the starting salts on the phase and morphology of the Pb(Zr, T)O$_3$powders prepared by ultrasonic spray pyrolysis were studied. The Phases of the Powders Prepared from the combination of metal nitrate(or oxynitrate), acetate(or oxyacetate), and alkoxide were the Pb(Zr, Ti)O$_3$with or without minor PbTiO$_3$. The pores on the surface of the spherical particles increased with the nitrate content in the starting solution and their formation was thought to result from the decomposition characteristics of metal nitrate. Pb acetate, Zr oxyacetate, Ti oxynitrate, and Ti (isopropoxide+acetylacetonate) was suitable as the starting salts for the preparation of Pb(Zr, Ti)O$_3$powders by ultrasonic spray pyrolysis in the viewpoint of the phase and morphology of the powders.