• Title/Summary/Keyword: Characteristic Pressure

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A Study on the Reaction Characteristics of Carbon Dioxide Methanation Catalyst for Full-Scale Process Application (이산화탄소 메탄화 공정 적용을 위한 Ni/CeO2-X 촉매의 반응 특성 연구)

  • Lee, Ye Hwan;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.323-327
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    • 2020
  • The reaction characteristics of Ni/CeO2-X which is highly efficient at a low temperature was investigated for an application to carbon dioxide methanation process. The CeO2-X support was obtained by the heat treatment of Ce(NO3)3 at 400 ℃ and the catalyst was prepared by impregnation process. The operating parameters of the experiment were the internal pressure of the reactor, the composition of oxygen, methane, and hydrogen sulfide in the inlet gas and the reaction temperature. When Ni/CeO2-X was used for the carbon dioxide methanation reaction, the CO2 conversion rate increased by more than 25% as the pressure increased from 1 to 3 bar. The increase was large at a low reaction temperature. When both oxygen and methane were in the inlet gas, the CO2 conversion rate of the catalyst decreased by up to 16 and 4%, respectively. As the concentration of oxygen and methane increased, the reduction rate of the CO2 conversion rate tended to increase. In addition, the hydrogen sulfide in the inlet gas reduced the CO2 conversion rate by up to 7% and caused catalyst deactivation. The results of this study will be useful as basic data for the carbon dioxide methanation process.

Study on Evaluation of Effective Thermal Conductivity of Unsaturated Soil Using Average Capillary Pressure and Network Model (평균 모세관압과 네트워크 모델을 이용한 불포화토의 유효 열전도도 산정에 관한 연구)

  • Han, Eunseon;Lee, Chulho;Choi, Hyun-Jun;Choi, Hangseok
    • Journal of the Korean Geotechnical Society
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    • v.29 no.1
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    • pp.93-107
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    • 2013
  • Thermal conduction of the particulate composites or granular materials can be widely used in porous materials and geotechnical engineering. And it has continued to develop "effective thermal conductivity" of medium by modeling energy relationship among particles in medium. This study focuses on the development of the effective thermal conductivity at the unsaturated conditions of soils using the modified network model approach assisted by synthetic 3D random packed systems (DEM method, Discrete Element Method) at the particle scale. To verify the network model, three kinds of glass beads and the Jumunjin sand are used to obtain experimental values at various unsaturated conditions. The PPE (Pressure Plate Extractor) test is then performed to obtain SWCC (Soil-Water Characteristic Curve) of soil samples. In the modified network model, SWCC is used to adjust the equivalent radius of thermal cylinder at contact area between particles. And cutoff range parameter to define the effective zone is also adjusted according to the SWCC at given conditions. From a series of laboratory tests and the proposed network model, the modified network model which adopts a SWCC shows a good agreement in modeling thermal conductivity of granular soils at given conditions. And an empirical correlation between the fraction of the mean radius (${\chi}$) and thermal conductivity at given saturated condition is provided, which can be used to expect thermal conductivity of the granular soils, to estimate thermal conductivity of granular soils.

CHARACTERISTICS OF HETEROEPITAXIALLY GROWN $Y_2$O$_3$ FILMS BY r-ICB FOR VLSI

  • Choi, S.C.;Cho, M.H.;Whangbo, S.W.;Kim, M.S.;Whang, C.N.;Kang, S.B.;Lee, S.I.;Lee, M.Y.
    • Journal of Surface Science and Engineering
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    • v.29 no.6
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    • pp.809-815
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    • 1996
  • $Y_2O_3$-based metal-insulator-semiconductor (MIS) structure on p-Si(100) has been studied. Films were prepared by UHV reactive ionized cluster beam deposition (r-ICBD) system. The base pressure of the system was about $1 \times 10^{-9}$ -9/ Torr and the process pressure $2 \times 10^{-5}$ Torr in oxygen ambience. Glancing X-ray diffraction(GXRD) and in-situ reflection high energy electron diffracton(RHEED) analyses were performed to investigate the crystallinity of the films. The results show phase change from amorphous state to crystalline one with increasingqr acceleration voltage and substrate temperature. It is also found that the phase transformation from $Y_2O_3$(111)//Si(100) to $Y_2O_3$(110)//Si(100) in growing directions takes place between $500^{\circ}C$ and $700^{\circ}C$. Especially as acceleration voltage is increased, preferentially oriented crystallinity was increased. Finally under the condition of above substrate temperature $700^{\circ}C$ and acceleration voltage 5kV, the $Y_2O_3$films are found to be grown epitaxially in direction of $Y_2O_3$(1l0)//Si(100) by observation of transmission electron microscope(TEM). Capacitance-voltage and current-voltage measurements were conducted to characterize Al/$Y_2O_3$/Si MIS structure with varying acceleration voltage and substrate temperature. Deposited $Y_2O_3$ films of thickness of nearly 300$\AA$ show that the breakdown field increases to 7~8MV /cm at the same conditon of epitaxial growing. These results also coincide with XPS spectra which indicate better stoichiometric characteristic in the condition of better crystalline one. After oxidation the breakdown field increases to 13MV /cm because the MIS structure contains interface silicon oxide of about 30$\AA$. In this case the dielectric constant of only $Y_2O_3$ layer is found to be $\in$15.6. These results have demonstrated the potential of using yttrium oxide for future VLSI/ULSI gate insulator applications.

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A Study on the Torsional Vibration Characteristics of Super Large Two Stroke Low Speed Diesel Engines with Tuning Damper (튜닝댐퍼를 갖는 초대형 저속 2행정 디젤엔진의 비틀림진동 특성에 관한 연구)

  • Lee, Don-Chool;Barro, Ronald D.
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.1
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    • pp.64-75
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    • 2009
  • The shipbuilder's requirement for a higher power output rating has led to the development of a super large two stroke low speed diesel engines. Usually a large-sized bore engine ranging from $8{\sim}14$ cylinders, this engine group is capable of delivering power output of more than 100,000 bhp at maximum continuous rating(mcr). Other positive aspects of this engine type include higher thermal efficiency, reliability, durability and mobility. This plays a vital role in meeting the propulsion requirement of vessels, specifically for large container ships, of which speed is a primary concern to become more competitive. Consequently, this also resulted in the modification of engine parameters and new component designs to meet the consequential higher mean effective pressure and higher maximum combustion pressure. Even though the fundamental excitation mechanisms unchanged, torsional vibration stresses in the propulsion shafting are subsequently perceived to be higher. As such, one important viewpoint in the initial engine design is the resulting vibration characteristic expected to prevail on the propulsion shafting system(PSS). This paper investigated the torsional vibration characteristics of these super large engines. For the two node torsional vibration with a nodal point on the crankshaft, a tuning damper is necessary to reduce the torsional stresses on the crankshaft. Hence, the tuning torsional vibration damper design and compatibility to the shafting system was similarly reviewed and analyzed.

A Study On The Thermal Movement Of The Reactor Coolant System For PWR (가압 경수로의 냉각재 계통 열팽창 거동에 관한 연구)

  • Yoon, Ki-Seok;Park, Taek sang;Kim, Tae-Wan;Jeon, Jang-Hwan
    • Nuclear Engineering and Technology
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    • v.27 no.3
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    • pp.393-402
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    • 1995
  • The structural analysis of the reactor coolant system mainly consist of too fields. The one is the static analysis considering the impact of pressure and temperature built up during normal operation. The other is the dynamic analysis to estimate the impact of postulated events such as the seismic loads or postulated branch line pipe breaks event. Since the most important goal of the RCS structural analysis is to prove the safety of the RCS during normal operation or postulated events, a widely proven theory having enough conservatism is adopted. The load occurring on the RCS during normal operation is considered as the basic design loading condition throughout whole plant life time. The most typical characteristic of the RCS during normal operation is the thermal expansion of the RCS caused by reactor coolant with high temperature and pressure. Therefore, the exact estimation on the thermal movement of the RCS is needed to get more clear understanding on the thermal movement behavior of the RCS. In this study, the general structural analysis concept and modeling method to evaluate the thermal movement of the RCS under the normal plant operation condition are presented. To discuss the validation of the suggested analysis, analysis results are compared with the measured data which ore referred from the standardized 1000 MWe PWR plant under construction.

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Dynamic Structural Response Characteristics of Stiffened Blast Wall under Explosion Loads (폭발 하중을 받는 보강된 방폭벽의 동적 구조 응답 특성에 관한 연구)

  • Kim, Sang Jin;Sohn, Jung Min;Lee, Jong Chan;Li, Chun Bao;Seong, Dong Jin;Paik, Jeom Kee
    • Journal of the Society of Naval Architects of Korea
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    • v.51 no.5
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    • pp.380-387
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    • 2014
  • Piper Alpha disaster drew attention to the damage likely to arise from explosions and fires on an offshore platform. And great concerns have been increased to prevent these hazards. Blast wall is one of the passive safety systems; it plays a key part of minimizing the consequences. However, a buckling due to explosion loads is a factor which can reduce the strength of blast wall. The buckling often occurs between web and flange at the center of blast wall. This study aims to find a solution for reinforcing its strength by installing a flat plate at the spot where the buckling occurs. First of all, ANSYS finite element method is adopted to numerically compute the structural resistance characteristic of blast wall by using a quasi-static approach. Sequentially, the impact response characteristics of blast wall are investigated the effect on thickness of flat plate by using ANSYS/LS-DYNA. Finally, pressure-impulse diagrams (P-I diagram) are presented to permit easy assessment of structural response characteristics of stiffened blast wall. In this study, effective use is made to increase structural intensity. of blast wall and acquired important insights have been documented.

Effects of Various Extraction Methods on Quality Characteristics of Duck Feet Gelatin

  • Park, Jae-Hyun;Choe, Ju-Hui;Kim, Hyun-Wook;Hwang, Ko-Eun;Song, Dong-Heon;Yeo, Eui-Joo;Kim, Hack-Youn;Choi, Yun-Sang;Lee, Sang-Hoon;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.33 no.2
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    • pp.162-169
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    • 2013
  • We determined the optimum pretreatment conditions such as pH and time for swelling duck feet and investigated the effects of the extracting method, such as water bath (WB), pressure cooker (PC), and microwave oven (MO), on quality characteristics of the duck feet gelatin for improving utilization of duck feet as a novel source of gelatin. The soaking solution of pH 1 among pH 1-14 with unit intervals was selected due to the highest yield. The quality characteristics of the gelatin tested were color, pH, gel strength, viscosity, and melting point. For the extracted gelatin with different methods, the CIE $L^*$, $a^*$ and $b^*$ values were in the following order: MO>PC>WB (p<0.05), WB>PC>MO (p<0.05) and PC>MO>WB (p<0.05), respectively. The gelatin extracted using WB showed the highest pH and that extracted using MO showed the lowest pH (p<0.05). The gel strength, viscosity, and melting point were the highest for MO (p<0.05). The gel strength and melting point were the lowest for PC (p<0.05). No significant difference was found in viscosity between the gelatins extracted using WB and PC (p>0.05). The quality characteristic of duck feet gelatin was affected by extracting methods, and MO extraction can be one of the effective methods for duck feet gelatin.

Analysis on the characteristics of the earth pressure distribution induced by the integrated steel pipe-roof construction (일체형 강관 파이프루프 시공에 따른 주변 지반의 토압 분포 특성 분석)

  • Sim, Youngjong;Jin, Kyu-Nam;Song, Ki-Il
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.15 no.5
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    • pp.455-468
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    • 2013
  • In recent, various types of steel pipe-roof methods, which is reinforced by mortar after propulsion of steel pipe into the ground, have been used for the construction of trenchless underpass. Integrated steel pipe-roof has flexural stiffness and can resist against overburden load and reduce the stress acting on the concrete underpass structures. Due to arching effect, vertical and horizontal stress distribution around the steel pipe-roof is changing. In this study, therefore, the characteristic of stress distribution around the underpass induced by the construction of integrated steel pipe-roof is investigated by using numerical method. To examine the soil-structure interaction, interface element is introduced. Results show that vertical stress acting on the concrete structure placing inside the steel pipe-roof is significantly reduced due to arching effect and flexural stiffness of integrated steel pipe-roof. Design load can be reduced and effective design of underpass will be available if the earth pressure reduction due to arching effect is considered in the design stage.

Wind-sand coupling movement induced by strong typhoon and its influences on aerodynamic force distribution of the wind turbine

  • Ke, Shitang;Dong, Yifan;Zhu, Rongkuan;Wang, Tongguang
    • Wind and Structures
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    • v.30 no.4
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    • pp.433-450
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    • 2020
  • The strong turbulence characteristic of typhoon not only will significantly change flow field characteristics surrounding the large-scale wind turbine and aerodynamic force distribution on surface, but also may cause morphological evolution of coast dune and thereby form sand storms. A 5MW horizontal-axis wind turbine in a wind power plant of southeastern coastal areas in China was chosen to investigate the distribution law of additional loads caused by wind-sand coupling movement of coast dune at landing of strong typhoons. Firstly, a mesoscale Weather Research and Forecasting (WRF) mode was introduced in for high spatial resolution simulation of typhoon "Megi". Wind speed profile on the boundary layer of typhoon was gained through fitting based on nonlinear least squares and then it was integrated into the user-defined function (UDF) as an entry condition of small-scaled CFD numerical simulation. On this basis, a synchronous iterative modeling of wind field and sand particle combination was carried out by using a continuous phase and discrete phase. Influencing laws of typhoon and normal wind on moving characteristics of sand particles, equivalent pressure distribution mode of structural surface and characteristics of lift resistance coefficient were compared. Results demonstrated that: Compared with normal wind, mesoscale typhoon intensifies the 3D aerodynamic distribution mode on structural surface of wind turbine significantly. Different from wind loads, sand loads mainly impact on 30° ranges at two sides of the lower windward region on the tower. The ratio between sand loads and wind load reaches 3.937% and the maximum sand pressure coefficient is 0.09. The coupling impact effect of strong typhoon and large sand particles is more significant, in which the resistance coefficient of tower is increased by 9.80% to the maximum extent. The maximum resistance coefficient in typhoon field is 13.79% higher than that in the normal wind field.

A New Shock Index for Predicting Survival of Rats with Hemorrhagic Shock Using Perfusion and Lactate Concentration Ratio (흰쥐의 출혈성 쇼크에서 관류와 젖산 농도 비를 이용한 새로운 생존 예측 지표 개발)

  • Choi, Jae-Lim;Nam, Ki-Chang;Kwon, Min-Kyung;Jang, Kyung-Hwan;Kim, Deok-Won
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.48 no.4
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    • pp.1-9
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    • 2011
  • Hemorrhagic shock is a clinically widespread syndrome characterized by inadequate oxygenation and supply. It is important to diagnose hemorrhagic shock in its early stage for improving treatment effects and survival rate. However, an accurate diagnosis and treatment could be delayed in the early stage of hemorrhagic shock by evaluating only vital signs such as heart rate and blood pressure. There have been many studies for the early diagnosis of hemorrhagic shock, reporting that lactate concentration and perfusion were useful variables for tissue hypoxia and metabolic acidosis. In this study, we measured both perfusion using a laser Doppler flowmeter and lactate concentration from the volume controlled hemorrhagic shock using rats. We also proposed a new shock index which was calculated by dividing lactate concentration by perfusion for early diagnosis. As a result of the survival prediction by the proposed index with the receiver operating characteristic curve method, the sensitivity, specificity, and accuracy of survival were 90.0, 96.7 and 94.0%, respectively. The proposed index showed the fastest significant difference among the other parameters such as blood pressure and heart rate. It could offer early diagnosis and effective treatment for human hemorrhagic shock if it is applicable to humans.