• 제목/요약/키워드: Characteristic Determination

검색결과 335건 처리시간 0.023초

분광학적 방법에 의한 계면활성제의 확인 (Qualitative Identification of Surfactants by Spectroscopic Method)

  • 안종일;조종희;박신자;김종길;전지혜;이정복;박홍수
    • 한국응용과학기술학회지
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    • 제18권4호
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    • pp.306-315
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    • 2001
  • Our study is aimed at proposal of systematic verification method of molecular structure using measuring method of selective ionic determination and spectrometry on 34 kinds of surfactants such as sodium dodecyl sulfate(SDS) which are most widely used today. In the IR spectrum, unsaturated fatty acids reveal themselves by HC= at $3000{\sim}3020cm^{-1}$, and intensity of $720cm^{-1}$ depends on carbon length of alkyl group. Also ethylene oxide(EO) adducts exhibit weak characteristic bands by $-CH_{2}-CH_{2}-O$ at 1350, 1100 and $950cm^{-1}$. Isethionate can be distinguished from diester succinate by intensity ratio of 1740 and $1200cm^{-1}$ spectrums, the ratio of latter is close to 1 due to 2 carboxylate radical in diester succinate. Quaternary ammonium salts exhibit characteristic band of $C_{4}N^{+}$ at $1000-900㎝^{-1}$. In the case of dialkyl dimethyl ammonium salts in quaternary ammonium surfactants, the spectrum of $3000cm^{-1}$ by $N-CH_{3}$ collapses to a very weak band at $3020cm^{-1}$. In ammonium heterocyclic derivatives, pyridinium salts show characteristic bands at 1640 and $1460cm^{-1}$, while imidazolinium salts exhibit characteristic band at $1620-1610cm^{-1}$. In the characteristic spectrum at $1080-1050cm^{-1}$ on OH radicals of the alkyl esters, primary alcohol appears as weak band and the 2 bands show in almost same intensity when primary and secondary alcohols exist together in one molecule. Also, alkyl ester of polyhydric alcohols appears as various broad band.

CAD를 이용한 텐세그리티 구조물의 평형응력모드 결정법 (Equilibrium Stress Mode Determination of Tensegrity Structure by CAD)

  • 김재열
    • 한국공간구조학회논문집
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    • 제12권2호
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    • pp.81-88
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    • 2012
  • 텐세그리티 구조시스템의 한 종류인 케이블 돔 시스템은 케이블과 마스트로 이루어져 있다. 이 케이블에 외부하중이 가해지지 않은 상태에서 안정된 구조물이 되기 위하여 일정의 프리텐션이 가해져야 하며 구조물은 가해진 프리텐션 하에서 자기평형응력상태에 있어야 한다. 본 연구에서는 부재의 내력 벡터의 합 원리를 기초하여 자기평형 응력모드를 구하는 새로운 방법을 제안하였으며, 자기평형응력을 유지하기 위해 필요한 응력모드를 시각화할 수 있다는 점이 기존의 논문과 비교하여 독특성을 갖는다. 본 연구에서 제안된 방법에서 사용된 기본 원리는 모든 절점에서 외부하중이 가해지지 않은 상태에서 내력벡터의 합은 0이 되어야 한다는 것이다. 제안된 방법은 CAD를 이용하여 간단히 자기 평형응력모드를 찾을 수 있으며, 예제 케이블 돔 구조물을 대상으로 각 절점에 연결된 부재들의 내력을 결정하였다. 결과 값은 역학적 계산 방법과 기존의 이론에 의해 검증하였으며 잘 일치하였다.

Characteristic X-ray Spectrum Analysis of Micro-Sized SiC

  • Miyoshi, Noriko;Mao, Weiji;Era, Hidenori;Shimozaki, Toshitada;Shinozaki, Nobuya
    • Applied Microscopy
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    • 제46권1호
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    • pp.27-31
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    • 2016
  • It has been investigated what kind of characteristic X-ray in electron probe micro-analyzer (EPMA) is effective for the determination of compounds of Si series materials. After comparing the characteristic X-rays among the primary and secondary lines in $K_{\alpha}$ and $K_{\beta}$ obtained from the Si series standard samples, it was found that the secondary line of $K_{\alpha}$ exhibited the most informative spectrum although the intensity was considerably weak. As a result of analyzing the spectrum shapes of the Si series standard samples, the spectrum shape of the secondary line of $K_{\alpha}$ for SiC was different from those for other Si compounds. To grasp the characteristics of the shape, a line was perpendicularly drawn from the peak top to base line in order to divide a spectrum into two areas. The area ratio of right to left was defined to call as the asymmetry index here. As a result, the asymmetry index value of the SiC was greater than one, while those of other Si compounds were less than one. It was found from the EPMA analysis that identification of SiC became successful to distinguish from other Si compounds and this method was applicable for micro-sized compounds in a practical composite material.

SWAT 모델을 이용한 강우특성 변화에 의한 퇴적물-유출량 간의 관계 평가 (Assessment of Relationship between Sediment-Discharge Based on Rainfall Characteristic using SWAT Model)

  • 김지수;김민석;조용찬
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제26권6호
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    • pp.118-129
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    • 2021
  • The sediment transportation caused by soil erosion due to rainfall-discharge in the large watershed scale plays critical role in human society. The relationship between rainfall-discharge-sediment transportation is depending on the start time of rainfall and end of rainfall but, the studies related with rainfall characteristics are insufficient. In this study, The Soil and Water Assession Tool (SWAT) model was used to study the relationship between rainfall-discharge-sediment transportation at the Sook river watershed which is monitored by the Ministry of Environment. To do this, first of all, the sensitivity analysis about model attributes was performed using monitored data. The accuracy analysis of SWAT model was conducted using the model's efficiency index (Nash and Sutcliffe model efficiency; NSE) and the coefficient of determination (R2). After that, it was studied what results could be obtained according to changes in rainfall timing and end points. In the result of discharge simulation, the modified rainfall values (sum of total rainfall starting time and end time) showed more high accuracy values (R2:0.90, NSE: 0.8) than original rainfall values (R2:0.76, NSE: 0.72). In the result of sediment transportation simulation, during calibration had more resonable results(R2:0.87, NSE: 0.86) than compared with original rainfall values (R2:0.44, NSE: 0.41). However, validation results of sediment transportation simulation showed low accuracy values compared with calibration results. This results maybe cause monitoring periods of sediment flow compared with discharge monitoring periods. Nevertheless, since rainfall characteristic plays critical rule in model results, continuous research on rainfall characteristic is needed.

발전량 비교를 통한 창조식 조력발전의 기동낙차 결정에 관한 연구 (A Study on the Determination of Starting Head by Comparing The Generating Power in Single Action Tidal Power Plant)

  • 김현한;김광호
    • 전기학회논문지
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    • 제67권5호
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    • pp.680-687
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    • 2018
  • Because of its predictability of the energy cycle and huge scale power output, the ocean energy from tidal power utilization has always received attention as a great energy source, even though its development cost, including the embankment construction, is so much higher than that of any other energy source. Nevertheless, nowadays many projects are being planned on account of institutional support from the government and the recent advance of construction technology. In Korea, the new industry field operating and managing the tidal power plant has already opened. But we are facing a number of problems for optimal operation of tidal power plant that are a lack of operation experience and a skill of professional management and others. This paper suggests a novel way to determine the starting head of power generation by generating power comparison method For this new method, the paper discusses many factors including changing the volume of the basin, the number of operating turbines and gates and forecasting the tidal amplitude and the characteristic curve of turbine and gate. Finally we verified that it can increase about 2% an annual power generation compared with the conventional method using the original operational function made in the plant design process.

불규칙파(不規則波)의 특성(特性)에 관한(關) 연구(硏究) (A Study on the Characteristic of Sea Wave)

  • 최한규;윤강훈
    • 산업기술연구
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    • 제5권
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    • pp.59-64
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    • 1985
  • The remarkable economic growth achived during 1960-1980 in Korea inevitablely demanded the expansion and maintenance of the harbors and their auxiliary seashore facilities. One of the most important elements in the basic besign for the expasion of a harbor and its auxiliary facilities is, of course, the proper determination of the design wave which reflects the major characteristics of the seashore under consideration. In this study, the parameters of significant waves for the industrial harbors on East Coast, Muck-Ho and Po-Hang, are first computed by means of computer programming using S.M.B and P.N.J methods, respectively. Then the design waves with the return periods of 5-200 years were estimated by frequency analysis of the significant waves. A comparison of the design waves with the observed wave data during the past 10 years made it possible to determine the optimum value of design wave at the two harbors. The important results of this study can be summarized as follows; 1) It seems appropriate to take the design wave hieghts with the return period of 50 years at Muck-Ho and Po-Hang as 6.9 and 5.8 meters respectively. 2) It was found that for the determination of design waves on East Coast of Korean Peninsula P.N.J method works better than S.M.B method in predicting the significant wave, and the Log-Normal distribution fits best to the wave data which were put to frequency analysis.

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Indirect Determination of Cetirizine Hydrochloride by ICP-AES

  • Wang, Li-Sheng;Wei, Xiao-Ling;Gong, Qi;Jiang, Zhi-Liang;Li, Dong-Mei;Liang, Qing
    • Bulletin of the Korean Chemical Society
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    • 제32권2호
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    • pp.595-598
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    • 2011
  • Cetirizine hydrochloride reacted with $BiI_4^-$ in an acidic aqueous solution to form precipitate. After centrifugation, the atomic emission intensity of $Bi^{3+}$ contained in the supernatant solution was measured at the characteristic wavelength of 206.170 nm. The difference between the spectral signal intensity of the blank solution and that of the supernatant, ${\Delta}I$, was linearly related to the concentration of cetirizine hydrochloride. As a result, a new inductively coupled plasmaatomic emission spectrometric (ICP-AES) method was developed for the analysis of cetirizine hydrochloride. The linear range was from 27.7 to 184.8 $mg{\cdot}L^{-1}$, with a correlation coefficient (r) of 0.9961 and a detection limit of 9.6 $mg{\cdot}L^{-1}$. This method is simple and accurate, Without using toxic organic solvents, and is feasible for the quality control of cetirizine hydrochloride tablets and capsules.

농촌계획지원용 지역자원평가시스템 구축(II) - AHP기법에 의한 자원요소의 중요도 펑가 - (Resources Evaluation System for Rural Planning Purposes(II) - Significance Determination of Resources Items by AHP Method -)

  • 최수명;황한철
    • 농촌계획
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    • 제3권2호
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    • pp.50-61
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    • 1997
  • As one of methodological approaches for objective and systematic evaluation for rural resources, a sequential system for significance determination of resources items was formulated using AHP (Analytic Hierarchy Process) as the base technique. By the system constructed in this study, the significance values were calculated for all items of standard goal system which had been presented in the first phase- paper of research works for rural resources evaluation. The results analysed and obtained in the study are summarized as follows; 1. In case that the number of resources items for evaluation are relatively large, stepwise matrix method is considered as the better one for pair-comparison works in view of evaluator's convenience and consistency. 2. The significance valuing results for most resources items showed a considerable difference between characteristic areas, especially in aspects of land and human resources, so being considered as wet reflecting the specific areal varieties, 3. On land resources, the items for industrial development and land use showed higher significance value, while natural environment resources the items for ecological varieties and on human resources the items for artificial facilities. However, lower-valued ones were the items for mineral stocks in land resources, for control and protection in natural environment resources and for lower-level culture heritage respectively.

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A Study on Correlations for Void Ratio, Coefficient of Uniformity and Coefficient of Curvature for Determination of Relative Density for Sands

  • Im, Soyeong;Jin, Yongguo;Chun, Byungsik
    • 한국지반환경공학회 논문집
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    • 제14권3호
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    • pp.13-17
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    • 2013
  • Determination of geotechnical characteristics of soil is either to use the field samples to measure the characteristics of soil through laboratory test or measuring the characteristics directly in the field. Field test can be derived similar value by considering characteristics of site and laboratory test can be confirmed the characteristic of soil by testing with field samples. This article describes relative density as the measure of compaction for cohesionless soils and presents several simple and mathematical relationships to help engineers estimate needed parameters for relative density calculations. The main purpose of this research is to investigate possible correlations between coefficient of uniformity, coefficient of curvature, maximum and minimum void ratio, mean grain size. Results show a linear relationship between the minimum and maximum void ratios and a power function relationship between coefficient of uniformity and the limiting void ratios. Void ratio range, which is the difference between the maximum and minimum void ratios, appeared to be log normally distributed but showed no simple mathematical fit to the data. these results were shown to help engineers estimate needed parameters for relative density calculations.

소프트웨어 기반 Loran-C 신호 처리 (Software-Based Loran-C Signal Processing)

  • 임준혁;임성혁;김우현;지규인
    • 제어로봇시스템학회논문지
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    • 제16권2호
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    • pp.188-193
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    • 2010
  • With GPS being the primary navigation system, Loran use is in steep decline. However, according to the final report of vulnerability assessment of the transportation infrastructure relying on the global positioning system prepared by the John A. Volpe National Transportation Systems Center, there are current attempts to enhance and re-popularize Loran as a GPS backup system through the characteristic of the ground based low frequency navigation system. To advance the Loran system such as Loran-C modernization and eLoran development, research is definitely needed in the field of Loran-C receiver signal processing as well as Loran-C signal design and the technology of a receiver. We have developed a set of Matlab tools, which implement a software Loran-C receiver that performs the receiver's position determination through the following procedure. The procedure consists of receiving the Loran-C signal, cycle selection, calculation of the TDOA and range, and receiver's position determination through the Least Square Method. We experiences the effect of an incorrect cycle selection and various error factors (ECD, ASF, sky wave, CRI, etc.) from the result of the Loran-C signal processing. It is apparent that researches which focus on the elimination and mitigation of various error factors need to be investigated on a software Loran-C receiver. These aspects will be explored in further work through the method such as PLL and Kalman filtering.