• 제목/요약/키워드: Characteristic Determination

검색결과 335건 처리시간 0.027초

Structural Determination of cis- and trans-5-Hydroxymethyl-5-methyl-2-thiono-r-2-ethoxy-1,3,2-dioxaphosphorinane by NMR and X-ray Crystallography: Model Compounds for the Reaction Mechanism Study of Organophosphorus Pesticides

  • Kim, Jeong Han;Toia, Robert F.;Craig, Donald C.
    • Journal of Applied Biological Chemistry
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    • 제43권1호
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    • pp.37-43
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    • 2000
  • 1,3,2-Dioxaphosphorinanes are suitable compounds for studying the stereochemistry of substitution at phosphorus. Cis- and trans-5-hydroxymethl-5-methyl-2-thiono-2ethoxy-1,3,2-dioxaphosphorinane were prepared, and their structures and stereochemistry unambiguously assigned by NMR and X-ray crystallography with acetoxy and 3,5-dinitrobenzoyloxy derivatives, respectively. Trans isomer gave $^{31}P$ NMR signal at higher field than cis isomer, and the ring proton Spectrum of cis isomer showed characteristic pattern for identifying its geometry. In X-ray crystallography they adopted a chair conformation with the ethoxy groups in the axial positions, and the sulfide groups in the equatorial positions. A flattening of the ring around the phosphorus center was noted, the POC bond angles were about $120^{\circ}$, and the C-O bonds in the ring were significantly longer than the C-O bond for the ethoxy group or the C-O bond for hydroxyl group.

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위상시간법에 의한 초음파전파시간의 결정에 관한 연구 (A study on the determination of Ultrasonic Travel Time by Norm Phase-Time Method)

  • 이은방
    • 한국항해학회지
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    • 제18권4호
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    • pp.137-146
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    • 1994
  • In this paper, a new algorithm to measure the ultrasonic travel time is proposed, which is fundamental to estimate distance depth and volume in several media. Pulse wave has been used to measure travel time of transmitted signal. However, due to the characteristic of transducer and propagation, the received signal is so distorted that it is difficult to measure travel time, which is propagation, the received signal is so distorted that it is difficult to measure travel time, which is to be time difference between transmitted and received signals. In this proposed method, transmitted and received signal are transformed respectively into norm phase newly designed by this paper and displayed on phase-time curve. And travel time is simply determined by the arithmetic numerical mean of time difference at the identical norm phase on the phase-time curves of transmitted and received signals. This method has several features; firstly, travel time is calculated analytically with high accuracy by least square error method, secondly, it is useful to compare the difference of signal magnitude for time information, thirdly, noise and discrete errors are relatively small, finally, the measurement accuracy is not influenced by D.C. bias. In particular, this method is useful and applicable to measuring very short distance and sound speed with high accuracy.

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시료 조건 및 측정방법에 따른 셀룰로오스의 결정화도 평가 (Determination of crystallinity index of cellulose depending on sample preparation and analysis instruments)

  • 안정언;윤혜정;정양진;김태영
    • 펄프종이기술
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    • 제44권4호
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    • pp.43-50
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    • 2012
  • The crystallinity index is an important characteristic of cellulose. The crystallinity value is different depending on the adopted instrument. In this study, we determined a crystallinity index of cotton and wood celluloses using wide-angle X-ray scattering (WAXS), powder X-ray diffractometer (PXRD), and cross polarization/magic angle spinning solid-state $^{13}C$ nuclear magnetic resonance spectroscopy (CP/MAS solid-state $^{13}C$ NMR). The specimen was prepared in forms of powder, sheet and pallet. With the comparison of the obtained crystallinity indices of the cellulose, the effects of the analysis instrument, the sample preparation and analysis method were investigated. Among three instruments, the crystallinity indices by PXRD and NMR had a good relationship and reproducibility, and WAXS gave the crystallinity index with poor reproducibility. In the case of analysis methods of crystallinity indices, the Segal method showed higher value than that of the Ruland-Vonk method. We expect that this study would be applicable to evaluate the crystallinity index of various cellulose materials with accuracy and reproducibility.

Structure Determination of Heishuixiecaoline A from Valeriana fauriei and Its Content from Different Cultivated Regions by HPLC/PDA Analysis

  • Hyejin Cho;Ki Hyun Kim;Sin Hee Han;Hak-Jae Kim;Ik-Hyun Cho;Sanghyun Lee
    • Natural Product Sciences
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    • 제28권4호
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    • pp.181-186
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    • 2022
  • A germacrane-type sesquiterpenoid was isolated and purified from a methanol extract of the roots of Valeriana fauriei (RVF) through open column chromatography using silica gel. This compound was verified to be heishuixiecaoline A by spectroscopic analysis. This compound was isolated for the first time from RVF. Quantitative analysis of heishuixiecaoline A from RVF cultivated from three different regions (Eumseong, Jinbu, and Jinan regions) was performed by combining high-performance liquid chromatography with a photodiode array detector. The extract of RVF cultivated in the Jinbu region showed the highest content (9.23 mg/g). In addition, a significant amount of the compound was detected in all RVF samples, which could be expected since it is a characteristic compound of RVF. The sesquiterpenoid group heishuixiecaoline A was isolated from RVF, a resource for various pharmacological substances, and quantitative analysis of RVF cultivated from three different regions was performed. As a result of these experiments, basic data on RVF that can be used in the development and application of pharmaceuticals and health functional foods in the future were obtained.

Analysis of the electrical properties of pork to discriminate between fresh and frozen/ thawed pork

  • Jun-Hwi, So;Seon Ho, Hwang;Sung Yong, Joe;Seung Hyun, Lee
    • 농업과학연구
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    • 제48권4호
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    • pp.739-751
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    • 2021
  • The thawing process is usually essential for imported pork because this product is typically distributed frozen. Consumers prefer fresh pork because discoloration, nutrient spills, and microbial contamination are high during the thawing process. The illegal act of selling frozen pork by disguising it as fresh pork through various methods can occur for the benefit of the difference in the sales price. However, there is some difficulty in securing systematic and objective data, as sensory tests are generally performed on imported pork. In the experiment conducted here, the electrical conductivity and dielectric properties of pork neck and pork belly products were measured. The amounts of change before and after freezing were compared through a statistical analysis, and a new method for determining frozen meat was proposed based on the analysis results. The weight was reduced compared to that before freezing due to the outflow of drips from the thawing process, but there was no difference in the drip loss level due to the thawing method. Vacuum packaging was found to lead to more drip loss than regular packaging, but the difference was not statistically significant. Frozen pork neck meat can be determined by measuring the electrical conductivity in the lean parts and the dielectric characteristic in the fatty parts. Frozen pork belly is determined by measuring the dielectric constant of the part closest to the outer fat layer.

도시고속도로의 진입연결로 접속부내 선형의 밀도예측모형 구축에 관한 연구 (The Linear Density Predictive Models on the On-Ramp Junction in the Urban Freeway)

  • 김태곤;신광식;김승길;김정서
    • 대한토목학회논문집
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    • 제26권1D호
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    • pp.59-66
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    • 2006
  • 이 연구는 도시고속도로의 진입연결로 접속부내 선형의 밀도예측모형 구축에 관한 연구로서 실시간 교통특성분석과 선형의 밀도예측모형 구축 및 검증을 통해 밀도예측모형 구축에 있어서 결정계수($R^2$)값이 대체적으로 0.7이상으로 나타나 선형회귀모형구축에 상당히 높은 설명력을 보이는 것으로 나타났고, 선형모형검증에 있어서 상관계수(r)값도 대체적으로 0.8 이상으로 상당히 높은 상관성을 보이는 것으로 나타났다. 따라서 향후 선형의 밀도예측모형을 이용하여 도시고속도로의 진입연결로 접속부내 차량의 밀도추정 및 지체분석에 상당히 유효할 것으로 판단된다.

TDR 측정시스템이 도입된 압력판 추출 시험기를 이용한 흙-함수특성곡선 연구 (Soil Water Characteristic Curve Using Volumetric Pressure Plate Extractor Incorporated with TDR System)

  • 정영석;사희동;강성훈;오세붕;이종섭
    • 한국지반공학회논문집
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    • 제31권8호
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    • pp.17-28
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    • 2015
  • 흙-함수특성곡선에 대한 선행 연구결과들의 경우, 정량적으로 간극수 유출입량을 측정하여 모관흡수력에 따른 체적함수비를 산정하였다. 본 연구에서는, 압력판 추출시험기(VPPE)에 Time Domain Reflectimoetry(TDR) 측정 시스템을 도입하여 불포화토의 건조과정 및 습윤과정 진행에 따른 유전상수를 측정하여 체적함수비를 산정하고자 하였다. 압력판 추출 시험기는 압력셀, 압력조절장치, 뷰렛 시스템, TDR 프로브로 구성된다. 압력셀에 초기 간극비가 다른 두 시료를 조성한 후, 압력조절장치를 이용하여 압력셀 내부에 0.1kPa - 50kPa 범위의 공기압을 가하여 모관흡수력을 조절하였다. 그리고 뷰렛시스템을 이용하여 모관흡수력 변화에 따른 시료의 체적함수비 변화를 측정하였다. 또한, 압력셀 내부에 설치된 TDR 프로브를 이용하여 프로브 양단에서 발생되는 전자기파의 반사 신호로부터 유전상수를 산정하였다. 주문진 표준사의 체적함수비 변화에 따른 유전상수 측정에 대한 보정으로 도출한 체적함수비와 유전상수관계를 이용하여 시료의 체적함수비를 산정하였다. 실험 결과, 시료의 초기 간극비와 상관없이 TDR 프로브에 의해 산정된 체적함수비는 뷰렛 시스템을 통해 정량적으로 산정된 체적함수비와 매우 유사한 것으로 나타났다. 또한, 건조과정 및 습윤과정 진행에 따라 동일한 모관흡수력에 대한 함수비의 차이가 존재하는 이력현상(Hysteresis)이 발생하였고, 건조과정 및 습윤과정의 반복에 따라 이력현상은 줄어들었다. 본 연구에서 적용된 전자기파의 시간영역반사법(TDR)을 통해 불포화토의 흙-함수특성곡선을 효과적으로 파악할 수 있을 것으로 판단된다.

Equivalent Transmission-Line Sections for Very High Impedances and Their Application to Branch-Line Hybrids with Very Weak Coupling Power

  • Ahn, Hee-Ran;Kim, Bum-Man
    • Journal of electromagnetic engineering and science
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    • 제9권2호
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    • pp.85-97
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    • 2009
  • As operating frequency is raised and as more integration with active and passive elements is required, it becomes difficult to fabricate more than 120 ${\Omega}$ characteristic impedance of a mierostrip line. To solve this problem, an equivalent high impedance transmission-line section is suggested, which consists mainly of a pair of coupled-line sections with two shorts. However, it becomes a transmission-line section only when its electrical length is fixed and its coupling power is more than half. To have transmission-line characteristics(perfect matching), independently of coupling power and electrical length, two identical open stubs are added and conventional design equations of evenand odd-mode impedances are modified, based on the fact that the modified design equations have the linear combinations of conventional ones. The high impedance transmission-line section is a passive component and therefore should be perfectly matched, at least at a design center frequency. For this, two different solutions are derived for the added open stub and two types of high impedance transmission-line sections with 160 ${\Omega}$ characteristic impedance are simulated as the electrical lengths of the coupled-line sections are varied. The simulation results show that the determination of the available bandwidth location depends on which solution is chosen. As an application, branch-line hybrids with very weak coupling power are investigated, depending on where an isolated port is located, and two types of branch-line hybrids are derived for each case. To verify the derived branch-line hybrids, a microstrip branch-line hybrid with -15 dB coupling power, composed of two 90$^{\circ}$ and two 270$^{\circ}$ transmission-line sections, is fabricated on a substrate of ${\varepsilon}_r$= 3.4 and h=0.76 mm and measured. In this case, 276.7 ${\Omega}$ characteristic impedance is fabricated using the suggested high impedance transmission-line sections. The measured coupling power is -14.5 dB, isolation and matching is almost perfect at a design center frequency of 2 GHz, showing good agreement with the prediction.

'경험-학습' 이론에 비추어 본 『삼국유사』 설화의 수양론적 특징 - 낙산사·분황사·금산사에 얽힌 세 설화를 중심으로 - (Characteristic of cultivating theory in fables of Sam Guk Yu Sa(三國遺事; The Heritage of the Three States) reflected to "Experience-Learning" theory - In the central figure of Three Fables with Naksan temple, Bunhwang temple, and Geumsan temple)

  • 최승현;김영훈;신창호
    • 한국철학논집
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    • 제32호
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    • pp.371-394
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    • 2011
  • 한국의 전통교육에서 불교는 큰 영향력을 차지하고 있다. "삼국유사"는 불교적 세계관을 바탕으로 민중성을 담보하고 있는 저작이다. 넓은 범위에서 민중성은 민중들의 수양교육으로 이어진다. 본고는 "삼국유사"에 나타난 불교적 민중성을 존 듀이의 '경험-학습' 모델에 근거하여 수양교육의 모습으로 검토한 것이다. "삼국유사"에 나타난 '성인-되기'라는 '의미-경험'은 불교적 세계관인 생성의 지평에서 볼 때, 강력한 수양교육의 성격을 띠고 있다. 듀이의 이론을 현대화한 듀이-들뢰즈적인 수양교육은 불교적 세계관을 바탕으로 한 "삼국유사"의 세 설화와 민중성이라는 지점에서 만난다. 이는 서구의 교육론과 한국의 전통사상의 수양론이 상호 교차하면서 독해될 수 있는 가능성을 열어준다. 승려에서 서민에 이르기까지 민중의 성장과 성숙을 다루고 있는 "삼국유사"의 설화에는, '충동-관찰-지식-판단'에 이르는 수양 교육의 과정을 통해, 불국토(佛國土)의 성취를 염원한다. 이러한 일련의 '성인-되기'의 과정은, 그 삶 자체가 수양론적 특성을 갖추고 있다. 이런 점에서 "삼국유사"의 설화는 한국의 전통 수양론의 모습을 보여주고 있으며, 서구의 교육이론과 접목할 수도 있는 수양교육의 담론서 역할을 할 수 있다.

진학소양평가 게임 시스템 개발에 관한 연구 (A Study on Game Development for Enter Literacy Evaluation)

  • 전중양;권두순
    • 경영정보학연구
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    • 제16권2호
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    • pp.61-76
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    • 2014
  • 최근 사회적으로 문제가 되고 있는 것이 내신등급 및 수능의 불합리한 난이도 때문에 학생들이 시험에 대한 부정이 높아지고 심지어는 진학 실패로 인해 자살에까지 이르고 있다. 그만큼 수능 난이도 조정 실패와 교육 제도 불안으로 인한 사회적 문제로 인해 진학에 대한 관심이 높아지고 있다. 이러한 사회적 환경을 고려해, 본 교육용 게임을 착안하게 되었다. 즉, 진학소양평가 게임 서비스를 통해 온라인 모바일 게임을 하면서 대학에 진학을 할 수 있다. 진학소양평가 게임 서비스는 실제 대학에서 원하는 시험 즉, 수학, 영어, 과학, 논술 등의 다양한 시험을 온라인 게임, 모바일 게임을 통해 미리 접할 수 있다. 이를 위해 진학소양평가 게임 서비스에 대한 전반적인 개념과 특성 확립과 기존 연구의 한계점을 이해하고, 인간 본연의 심리욕구를 다룬 대표적인 이론인 자기결정성 이론과 진학소양평가 게임 서비스에 대한 관계를 알아보고자 한다. 따라서 진학소양평가 기능성 게임의 개발은 대학의 경쟁력 확보와 우수 인재 확보라는 두 마리 우위를 잡을 수 있는 새로운 기회요인으로 볼 수 있으며, 기능성 게임의 발전을 위한 한 분야의 도전이라고 할 수 있다.