• Title/Summary/Keyword: Char Combustion

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A Experimental Study of Oxidation Kinetics for a Sub-Bituminous Coal Char (아 역청탄 촤 산화 반응속도론에 관한 실험적 연구)

  • Kang, Ki-Tae;Song, Ju-Hun;Lee, Chuen-Sueng;Chang, Young-June;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.18 no.4
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    • pp.239-246
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    • 2009
  • A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.

Characteristics of Various Ranks of Coal Gasification with $CO_2$ by Gas Analysis (가스분석을 이용한 석탄 종류별 $CO_2$ 가스화 반응특성 연구)

  • Kim, Yong-Tack;Seo, Dong-Kyun;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
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    • v.15 no.2
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    • pp.41-49
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    • 2010
  • Various coals from many countries around the world have been used for pulverized coal boiler in power plants in Korea. In this study, the gasification reactivities of various coal chars with $CO_2$ were investigated. Carbon conversion was measured using a real time gas analyzer with NDIR CO/$CO_2$ sensor. In a lab scale furnace, each coal sample was devolatilized at $950^{\circ}C$ in nitrogen atmosphere and became coal char and then further heated up to reach to a desired temperature. Each char was then gasified with $CO_2$ under isothermal conditions. The reactivities of coal chars were investigated at different temperatures. The shrinking core model (SCM) and volume reaction model(VRM) were used to interpret the experiment data. It was found that the SCM and VRM could describe well the experimental results within the carbon conversion of 0-0.98. The gasification rates for various coals were very different. The gasification rate for any coal increased as the volatile matter content increased.

Modeling of a Pulverized Coal Combustion With Applying WSGGM (희체가스 가중합산모델을 적용한 미분탄 연소의 해석)

  • Yu, Myoung-Jong;Baek, Seung-Wook
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.155-163
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    • 1999
  • A numerical study for simulating a swirling pulverized coal combustion in axisymmetric geometry is done here by applying the weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard ${\kappa}-{\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase for soot. The eddydissipation model is employed for the reaction rate for gaseous mixture, and the single-step first-order reaction model for the devolatilization process for coal. By comparing the numerical results with experimental ones, the models used here are confirmed and found to be one of good alternatives for simulating the combustion as well as radiative characteristics.

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Preparation & Properties of the Flame Retarded NBR Foams with Phosphorus/Nitrogen-Containing Flame Retardants (인/질소계 난연제를 포함한 난연 NBR 발포체의 제조 및 특성)

  • Jo, Byung-Wook;Moon, Sung-Chul;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.39 no.2
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    • pp.105-120
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    • 2004
  • The flame retarded NBR foams were prepared with metal hydroxides and various phosphorus/nitrogen-contain ing flame retardants. The dependency of the phosphorus content on thermal properties, flame retardancy, smoke density, and foaming properties were investigated in the foams. Foaming properties and morphology of the flame retarded NBR foams with P/N flame retardants( ${\le}10 phr$) were similar to those of the foams without P/N ones but containing metal hydroxides The flame retardancy of the foams was improved with increasing the phosphorus content and char formation under combustion atmosphere. The cone-calorimeter test and LOI index were also coincided with the TGA analysis quite well. The heat release rate (HRR), total heat release (THR), and effective heat of combustion (EHC) were decreased, whereas the carbon monoxide yield was increased with increase of the phosphorus content of P/N flame retardant. The smoke density values were closely related with CO yield values obtained by the cone-calorimeter test due to the high and hard char formation.

An Experimental Study on the Combustion Behavior of Single Coal-Water Slurry Droplet (석탄-물 혼합물 단일액적의 연소 특성에 관한 실험적 연구)

  • 채재우;조용철;전영남;한영수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.11
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    • pp.2159-2168
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    • 1992
  • Coal-water slurry is considered to have the potential for displacing petroleum used in the existing oil-fired industrial and utility boilers. The combustion of coal-water slurry(CWS) is a complex process and little is known about the detailed mechanism. In this paper the combustion behavior of a single suspended droplet of CWS in hot gas stream was investigated. The effect of coal particle size, water content in droplet, initial droplet size, ambient temperature and oxygen fraction in ambient gas were studied. The results are as follows; (1) Increasing the oxygen fraction in ambient gas considerably reduced the char combustion time. (2) The variation of water content and coal particle size in droplet showed little effect on the combustion behavior. (3) In the relatively high temperature ambient gas, the water evaporation time became shorter and the combustion process was stable.

The characteristics of pyrolysis and combustion for a hollow cylindrical solid fuel (중공 원통형 고체연료의 열분해 및 연소특성)

  • 민성기;김호영
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.3
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    • pp.517-527
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    • 1989
  • A theoretical analysis for the characteristics of pyrolysis and combustion of solid fuel was carried out in the present study. The hollow cylindrical combustion model including gas phase and solid fuel at inside and outside respectively was developed for the numerical analysis and parametric studies. The effects of volatile contents in the porous solid fuel and Reynolds number at inlet of gas phase on the characteristics of pyrolysis and combustion such as the radial, axial and time variations of volatile mass flux through porous solid fuel, temperature, mass fractions of gaseous fuel and oxidizer, and flame shape were investigated in the parametric studies. The results of the present study show that the flame produced by the volatiles moves to the downstream of fuel with accelerating velocity with time until extinction is occurred resulting from the completion of pyrolysis. When flame is employed with smaller amount of volatiles content in the solid fuel, the flame sheet exists closer to the inner wall of solid fuel. As Reynolds number at inlet increases, the flame sheet moves to the inner wall due to effect of convection even though the volatiles by pyrolysis increases.

Fuel Characteristics of Sewage Sludge in a Fluidized Bed Incinerator (유동상 소각로에서 하수 슬러지 연료 특성)

  • Choi, Jin-Hwan;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.81-91
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    • 1999
  • Fuel characteristics of sewage sludge as required for the fluidized bed incinerators have been evaluated. Sewage sludge is basically a solid fuel with high percentage of moisture. Moisture content of the fuel directly affects the heating value of the fuel and the exhaust gas composition. When the sludge of transported into the incinerator, sludge cake is subject to the mixing, break-up and heat-up. Fluidization process would enhance these physical processes. The sludge fuel could then undergo the moisture evaporation and devolatilization process. Subsequent oxidation of volatiles as well as the remaining char would then follow. Sludge samples are characterized with high percentage of volatiles out of total combustibles. Quantitative understanding of above listed subprocesses would certainly help in the utilization of fluidized bed incinerators. A limited set of fuel characterization tests including calorimetric analysis, proximate analysis, elemental analysis and thermogravimetric analysis were conducted for the selected sludge samples. The measurement reasults of sludge samples were reported along with some published data. Limited experience in the actual incinerator plant is also presented.

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Scale-up of Melting Chamber for a Pyrolysis Melting Incinemtion System (폐기물 열분해/용융 소각 시스템의 용융로 Scale-up 연구)

  • Yang, Won;Kim, Bong-Keun;Yu, Tae-U;Jeun, Keum-Ha
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.168-175
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    • 2007
  • Ash melting chamber is one of the key facility of the pyrolysis-melting incineration system, and it should be designed and operated very carefully for avoiding solidification of slag. In this study, an example of numerical and experimental scale-up process of the melting chamber, in which high speed air is injected to the molten slag and generates bubbles, which enhances agitation of the slag and char combustion, is presented. Cold flow test, combustion and melting test in a lab-scale (30 kg/hr) chamber and a pilot scale (200 kg/hr) chamber. Minimum energy for maintaining molten slag is derived, and it was found that the molten slag can be maintained efficiently by concentrating heat into the bubbling slag.

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A Study on the Combustion Characteristics and Stratification for Lean Burn of Methanol (The Combust ion Character istics in a IDI Type Constant Volume Combustion Chamber) (메타놀의 희박연소를 위한 혼합기의 성층화와 연소특성에 관한 연구(제 I장 : IDI형 정적연소기에서의 혼합기 연소특성))

  • 박춘근;윤수한
    • Journal of Advanced Marine Engineering and Technology
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    • v.21 no.3
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    • pp.302-310
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    • 1997
  • In this paper, we find a method to improve ignitability using methanol which is prospective as an alternative fuel. The constant volume combuster is divided into main chamber and sub-cham¬ber. These two chambers are linked by an adapter which is shaped like a cup. We also compare CDI to HIS that is revised in our laboratory for making a scrutiny into the effects of ignition char¬acteristics. Besides, we analyze a flame propagation process in the main and sub-chamber through taking pictures 10, 000 frames per second by high speed camera at the state being fabricated quartz glass aside main and sub-chamber.

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Comparison of Combustion Properties of the Pinus rigida, Castanea sativa, and Zelkova serrata (리기다 소나무, 밤나무, 느티나무의 연소성질 비교)

  • Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.23 no.4
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    • pp.73-78
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    • 2009
  • This paper investigated the combustion properties of the Pinus rigida, Castanea sativa, and Zelkova serrata which are grown in Korea using the cone calorimeter. The heat release rate and smoke production for these species were measured. With respect to an increase of retardant properties attributed to char formation, Zelkova serrata showed good properties compared with that of Pinus rigida and Castanea sativa. The Castanea sativa has high $CO_{peak}$ Yield and high $CO/CO_2$ Yield compared with that of Pinus rigida and Zelkova serrata.