• 제목/요약/키워드: Chamotte

검색결과 16건 처리시간 0.017초

Chamotte질 내화물의 강도에 미치는 유이 Silica의 영향 (The Effect of Free Silica on the Strength of Chamotte Refractory)

  • 박금철;최영섭
    • 한국세라믹학회지
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    • 제13권1호
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    • pp.35-44
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    • 1976
  • The effect of quartz which exists in clays, especially in kaolin used for the production of chamotte sagger, on the strength of refractory was examined. In this study, a mixture of chamotte 50%, kaolin 25%, plastic clay 25% in ternary component system was selected as a batch composition. To this mixture 1%, 3% and 5% of feldspar and sericite were added respectively. The plastic clay used here was separated under 170 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. Feldspar and sericite were separated under 325 mesh by dry process. In order to change the particle size and the content of quartz, the kaolin was separated under 60, 115, 170 and 325 mesh by wet process, substituted quartz for coarse parts of it. Chamotte was classified into three grades, coarse (5-10mesh): medium (10-20mesh): fine(20-115mesh) and the ratio was 1:1:1. Samples were formed in 0.8xIx10cm size with 12.5% water at 160kg/$\textrm{cm}^2$ pressure, and fired at 130$0^{\circ}C$ for 1 hr. The fired samples were ivnestigated by means of x-ray diffraction analysis and microscopic observation, and the physical properties of them were also examined, such as firing shrinkage, apparent specific gravity and bulk specific gravity, apparent porosity, water absorption and modulus of rupture. The obtained results are as follows: 1. When screened kaolin with low content of quartz was added to fixed chamotte-plastic clay system, the sample lowered modulus of rupture and increased apparent porosity as the size of kaolin became finer. 2. When kaolin under 325 mesh with 7.2-15.81% quartz between 60-325 mesh was added to fixed chamotte-plastic clay system, the sample had higher apparent porosity and lower modulus of ruputure as the size and the amount of quartz became larger. 3. The addition of feldspar and sericite to chamotte-plastic clay system improved apparent porosity and modulus of rupture. The effect of feldspar was better when quartz content was low, although that of sericite was better than quartz content was high.

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용융 알루미늄에 의한 점토결합 카올린 샤모트의 침식에 관한 연구 (A Study on Corrosion Behavior of the Clay-Bonded Kaolin Chamotte by Molten Aluminum)

  • 박정현;이승주
    • 한국세라믹학회지
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    • 제17권4호
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    • pp.188-196
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    • 1980
  • To investigate the corrosion behavior of the clay-bonded kaolin chamotte by molten aluminum, the mixture of 20 wt% fire clay and 80 wt% kaolin chamotte was prepared and fired in the temperature range 900~120$0^{\circ}C$. The specimens fired at each temperature were reacted with molten aluminum at 90$0^{\circ}C$. The results obtained in this experiment are as followed. 1) It was confirmed through X-ray diffraction analysis that the clay-bonded kaolin chamotte exposed to molten aluminum suffered penetration by the reaction of aluminum with silica forming alumina and metallic silicon. 2) Penetration was independent whether the silica existed as free or one component of mullite. 3) Penetration of the specimen fired at 90$0^{\circ}C$ was negligible while the others fired above 100$0^{\circ}C$ showed remarkable penetration. 4) Penetration rate at 90$0^{\circ}C$ was parabolically increased with the holding time as in the case of metal oxidation.

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Chamotte-점토-골석계 및 랍석 첨가계 소결체의 특성에 관한 연구 (Study on Characteristics of the Bodies composed of Chamotte-Plastic Clay-Talc and added Agalmatolite System)

  • 박금철;최영섭
    • 한국세라믹학회지
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    • 제14권4호
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    • pp.215-225
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    • 1977
  • In this study, we are observe to the sagger which is composed of cordierite-mullite system. And especialy, we investigated the characteristics of the body which composed of Chamotte-Kaolin-Plastic clay-Talc (or Clinochlore) system and Chamotte-Kaolin-Plastic clay-Agalmatolite-Talc (or Clinochlore) system. The obtained results are as follows. 1. Modulus of rupture and apparent porosity were improved by particle size of talc and clinochlore in order that -16 mesh, -6 mesh, 6-16 mesh. 2. When the body composed of talc, the modulus of rupture was increased as firing temperature was rising up but composed of clnochlore, it was reversed. 3. When added to the agalmatolite, firing shrinkage, modulus of rupture and apparent porosity were improved. 4. Mineral phases of samples fired at 125$0^{\circ}C$ above consist of cordierite, mullite and $\alpha$-cristobalite.

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탄화규소-점토-Kaolin Chamotte 계의 소결에 미치는 첨가제 $Al_2O_3$의 영향 (Effect of $Al_2O_3$ as Additives on the Sintering of Sic-Clay-Kaolin Chomotte System)

  • 백용혁;박종훈
    • 한국세라믹학회지
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    • 제18권1호
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    • pp.41-47
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    • 1981
  • The sintering characteristics of the SiC-Clay-Kaolin chamotte system were studied by addition of $Al_2O_3$ for the manufacture of silicate-bonded silicon carbide refractories at $1350^{\circ}C$. The sinterbilit of SiC-Binder mixture was measured by apparent porosity and compressive strength. And its mineral compositions were identified with X-ray diffractometer. The following results were obtained; 1) Optimum amount of mixed clay ($\textrm{Al}_2\textrm{O}_3$ 40 wt% mixed) as a binder was about 25wt% 2) Appropriate mixing ratio of mixed Kaolin chamotte ($\textrm{Al}_2\textrm{O}_3$ 40wt% mixed) was about 30wt% in the clay Kaolin chamotte binder. 3) Variation of apparent porosity and compressive strength of sintered SiC-binder mixture fired at $1350^{\circ}C$ were due to the sinterbility of clay.

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점토질소지의 공정제어에 따른 저수축 치밀화효과 (Effect of Processing Parameters on the Densification-Behaviors by Low Shrinkage in Clay Materials)

  • 임희진;최성철;이응상;이진성
    • 한국세라믹학회지
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    • 제33권7호
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    • pp.725-734
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    • 1996
  • 점토질 소지에 있어서 수축 특성은 성형, 건조 및 소성 공정에 수반되어 치말화거등에 기여할 수 있는 구동력이 될 수 있다. 점토질 소지에서 저수축 치말화거동은 입자크기효과와 상전이 특성에 기인하는 열간 반응전이 거동을 포함하는 공정변수에 따라 크게 변화됨을 보였다. 90$0^{\circ}C$ 및 120$0^{\circ}C$에서 열처리된 Chamotte의 첨가를 통해서 점토질 소지의 열간 치밀화 과정에 기인하는 공정수축은 크게 억제될 수 있었다. 120$0^{\circ}C$에서 열처리된 조대한 Chamotte 입자는 점토 소지의 치밀화 거동을 억제하여 치밀한 소결미세구조를 얻을 수는 없었지만, 조대한 Chamotte 입자의 첨가는 neat-net-shape 제어를 촉진할 수 있었다. 점토질 소지에 있어서 미세구조/물성간의 연관관계는 저수축과 치밀화 거동사이의 상반된 특성을 제어함으로써 얻어진 최적조건에 따라 직접적인 영향을 받을 것으로 판단되었다.

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Chamotte-Kaolin 납석계 소결체의 특성에 미치는 $ZrO_2$의 첨가효과 (The Effect of Additive Zirconia on Properties in Sintered Body of Chamotte-Kaolin-Agalmatolite System)

  • 박금철;이석로
    • 한국세라믹학회지
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    • 제21권4호
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    • pp.366-372
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    • 1984
  • Unstabilized Zirconia was added to basic composition under 44$mu extrm{m}$ of 57.80wt% Clay-22.20wt% Chamotte-20.00wt% Agalmatolite system. Here the amount and the particle size of Zirconia were 5-25wt% and -20${\mu}{\textrm}{m}$ respectively and the body of these composition was first at 135$0^{\circ}C$. The results obtained from examining the properties of sintered body were as follows. 1. Firing linear shrinkage apparent density and bulk density apparent porosity and water absorption of the samples had the tend to increase according as the particle size of zirconia became larger and the amount of zirconia increased. 2. Modulus of rupture was inversely proportional to the particle size and the additive amount of zirconia, . Especially in case that the particle size of zirconia over 5${\mu}{\textrm}{m}$ and the additive amount of zirconia was 25wt% the modulus of rupture had shrunk drastically. 3. The maximum value of KIC was obtained at 20wt% additive amount of zirconia according to the each particle size of zirconia. Especially the highest value of KIC is 2, 173 M. Pa. M1/2 when the particle size of zirconia is 5~10${\mu}{\textrm}{m}$ and the additive amount is 20wt%.

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Al2O3-SiO2 계 폐내화물을 이용한 재생캐스타블에 있어서 잔존수축의 제어 (Control of Permanent Shrinking of Recycled Castable Refractories from Waste Refractories of Al2O3-SiO2)

  • 이상완;김효준;김의훈
    • 한국세라믹학회지
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    • 제29권1호
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    • pp.15-22
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    • 1992
  • The reason for permanent shrinking of recycled castable refractories from alumino-silicate waste refractories was investigated and the method to control shrinking is suggested in order to increase maximum service termperature. The porosity of castable refractories with waste material as large aggregate decreases after heat treatment because the porosity of waste refractories is greater than the of green material, in which CaO around large aggregate penetrates into aggregate and promotes liquid phase sintering. The shrinking of recycled castable refractories resulted in the decrease in porosity can be controled by addition of green kaolin chamotte as large aggregate. The shrinking of recycled castable refractories caused by the differences in densities of mineral phases before and after heat treatment can be controled by addition of kyanite. The use of green kaolin chamotte and kyanite increases the service temperature of recycled castable refractories up to 1500$^{\circ}C$.

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안창리 기와의 제작기법 (Manufacturing Techniques of Tile in Anchang-ri Historical Site of Wonju-city, Korea)

  • 양동윤;김주용;신숙정;박준범
    • 한국제4기학회지
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    • 제23권2호
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    • pp.13-33
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    • 2009
  • 안창리 유적지에서 출토된 기와를 대상으로 제작기법을 추정하기 위해, 기와 9점과 벅체 5점을 대상으로 하여, 실제현미경관찰, 편광현미경관찰, X-선 회절분석을 실시하였다. 기와를 제작할 때, 성형을 위해 비짐을 첨가하는 대신 기존의 기와편 등을 잘게 부셔 넣은 것으로 보인다. 철분이 많은 미세한 덩어리나, 폐기된 벽체 등에서 얻은 재료를 재활용하여 비짐으로 사용(chamotte)한 흔적이 기와 및 벽체에서 흔히 관찰된다. 또한 어떤 것은 chamotte 내에 다른 chamotte가 들어 있어 수차에 걸친 재활용도 이뤄졌을 것으로 보인다. 구성광물 조합에서 추정한 기와와 벽체의 소성온도에 따라 저온형($800^{\circ}C$ 이하), 중간형($800-930^{\circ}C$), 고온형($930^{\circ}C-1470^{\circ}C$)으로 분류하였다. 그 중에서 가장 고온에서 소성된 것은 조선시대의 것인 A8과 AW5로 판단된다.

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De-soda Process Using Silica for Fabrication of Low Soda Alumina Powder

  • Park, Sang-Chun;Kim, Dae-Woong;Heo, In-Woong;Lee, Sang-Jin
    • 한국세라믹학회지
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    • 제52권3호
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    • pp.192-196
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    • 2015
  • Low soda alumina powder was fabricated using silica (${\alpha}$-quartz) as an agent for removing soda components in the alumina. Quartz powder 2 mm in size was added to aluminum hydroxide obtained through the Bayer process, and then the mixture was heated at various temperatures. Finally, the heat-treated powders were sieved for classification. In this study, the effects of the quartz amount and heating temperature on the mechanism of removing soda were examined. A minimum soda content of 0.005 wt% was observed at the conditions of 15 wt% quartz (based on $Al(OH)_3$ amount) heat-treated at $1600^{\circ}C$ for 8 h. The soda components, such as $Na_2O$, NaOH, and $Na_2CO_3$, in alumina were ionized and activated at high temperature, and this facilitated the reaction with quartz silica and alumina producing nepheline. The advantages of using quartz include low iron content and low cost in comparison with the conventional de-soda process using chamotte, another silicate mineral.

고주파용 절연재료로서의 Forsterite 자기에 관한 연구 (I) (Forsterite의 결정질과 유리상) (A Study on the Forsterite Porcelain as a High Frequency Insulator (I) (Crystalline and Glassy Phases of Forsterite))

  • 이웅상;황성연
    • 한국세라믹학회지
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    • 제18권1호
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    • pp.13-22
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    • 1981
  • This study is to investigate the effective mineralizer in the manufacture of forsterite porcelain as a high frequency insulator. A mixture of $Mg(OH)_2$. and $SiO_2$.($\alpha$-Quartz) corresponding to the molar ratio of 2.0 MgO: 1.0 $SiO_2$ was prepared from the materials of high purity. It was heated to 140$0^{\circ}C$ at the rate of 20$0^{\circ}C$/hr, which was kept constantly for 1 hour, and one has made chamotte after cooling. Six kinds of glasses were prepared by an 0.1 atomic equivalent of K ions substitution-Ba, Bi, Zn, Cd, Zr-to the basic K-glass (0.333 $K_2O$.1.14 $SiO_2$) and were melted approximately at 150$0^{\circ}C$. The forsterite bodies were provided by adding each glass (10, 15, 20, 25, 30%) to the forsterite chamotte, which was fired at 1320, 1360, 1400, 144$0^{\circ}C$. (1 hr). One has examined the physical and dielectric properties for the specimens. The results of the experiments are as follows; 1. As for water absorption: Bodies were better vitrified with an addition and temperature change of Ba, Bi, Zn-glasses. The specimen containing Cd-glass showed deviation of slow decreasing, where as K-glass was completely not vitrified. 2. Bodies containing Ba, Zn, Bi-glasses appeared comparatively high Modulus of Rupture at 136$0^{\circ}C$, while containing Zr-glass had the highest Modulus of Rupture as the addition changes remarkably at 140$0^{\circ}C$. 3. It was estimated that 20-25% glass present in a forsterite bodies were in good conditions as for physical properties. 4. Specimens of Ba, Bi, Zr-glasses were superior as for dielectric properties, where among Ba-glass was most excellent. 5. Dielectric constant commonly increases in a slight gradient as firing temperature rises. 6. The petrographic examination showed that the bodies containing Ba, Bi-glasses had fine crystals, and were observed distinctly large mosaic crystals in the Zn-glass.

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