• Title/Summary/Keyword: Chain transfer

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Development of an Electronically Controlled Transfer Case for Automobile (자동차용 전자제어식 부변속기 개발)

  • 김광열;김태훈
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.6
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    • pp.155-163
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    • 2000
  • A technology of full time four wheel drive(4WD) vehicle has been improved greatly, and the market share of full time 4WD has been extended steadily in recent days. The transfer case is an essential element in the 4WD automobile. In this paper, the details of electronically controlled transfer case is described. In order to achieve easy shifting, the shifting, the developed system automate the conversion of "$4\times2\longleftrightarrow4\times4(H)\longleftrightarrow4\times4(L)$". Furthmore, this system employs an chain drive type instead of gear drive type for drive type and synchromesh type instead of constant-mesh type for gear mesh type. Therefore, the developed transfer case is accomplished light-weight, low noise, and compact.d compact.

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Characteristics and Ring-Opening Isomerization Polymerization of 2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) (2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline(TAO)의 개환이성화중합과 특성평가)

  • Lee, Chan-Woo;Chung, Jin-Do
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.262-267
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    • 2012
  • 2-(1,3,3-Trimethyl-6-azabicyclo [3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) was polymerized at several conditions to clarify the influence of initiators, alkyl halide ($PhCH_2Br$, $PhCH_2Cl$, MeI) and sulfonate (MeOTf). The reactions were conducted at $100^{\circ}C$ for 24 h. The resultant polymer forms several kinds of structures with different combination of initiators. The sole MeOTf initiator caused chain transfer reaction to form the one-order structure for which the resultant polymer exclusively formed pendant structure, while alkyl halide and MeOTf formed two kinds of structures, pendant and main chain, which is caused by partly-proceeded double isomerization polymerization by highly reactive nucleophilic counter anion of halogen. Merrifield polymer was also utilized as an intiator and copolymerized with TAO, which produced a graft structure.

The Optimum pH of Oxidoreductases: A Comparison Between Experimental and Calculated pH Optimum (산화환원 효소의 최적 pH 예측)

  • Kim, Jin Ryeon;Yang, Ji Hye;Yu, Yeong Je
    • Journal of the Korean Chemical Society
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    • v.46 no.5
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    • pp.432-449
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    • 2002
  • For various oxidoreductases, the optimum pHs of the enzymes can be calculated using the rule based on proton transfer. Relative probability of a certain amino acid side chain to be in the water, or the relative affinity to the water was calculated using Boltzman distribution. Also, the protonated and deprotonated portions of a certain amino acid side chain were calculated using p$K_R$ of that and the effective protonated and deprotonated protions were the product of relative probability and the protonated and deproteonated protions. Where the total effective protonated portion was equal to the effective deprotonated portion of amino acid side chains, it was expected that oxidoreductases have max-imum activities. The optimum pHs calculated by our rule were compared with the experimental results.

Improvement in Enzyme Immobilization of Polypyrrole Enzyme Electrode using Radical Transfer (Radical Transfer 반응을 이용한 Polypyrrole 효소전극의 효소고정화 향상)

  • Kim, Hyun-Cheol;Cho, Young-Jai;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.100-103
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    • 2000
  • In the case of immobilizing of glucose oxidase into polypyrrole (PPy) using electrosynthesis, the glucose oxidase (GOx) forms a coordinate bond with the polymers backbone. However, because of intrinsic insulation and net-chain of the enzyme, the charge transfer and mass transport are obstructed during the film growth. Therefore, the film growth is dull. We synthesized the enzyme electrode by electropolymerization added some organic solvent. A formative seeds of film growth is delayed by adding ethanol. The delay is induced by radical transfer between ethanol and pyrrole monomer. The radical transfer shares the contribution of dopant between electrolyte anion and GOx polyanion. This may lead to increase amount of immobilized the enzyme in PPy. For the UV absorption spectra of synthetic solution before synthesis and after, in the case of ethanol added, the optical density was slightly decreased for the GOx peaks. It suggests amount of GOx in the solution was decreased and amount of GOx in the film was increased. We established qualitatively that amount of immobilization can be improved by adding a little ethanol in the synthetic solution. It is due to radical transfer reaction. The radical transfer shares the contribution of dopant between small and fast electrolyte anion and big and slow GOx polyanion.

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Comparison between Water and N-Tetradecane as Insulation Materials through Modeling and Simulation of Heat Transfer in Packaging Box for Vaccine Shipping

  • Dao, Van-Duong;Jin, Ik-Kyu;Hur, Ho;Choi, Ho-Suk
    • Clean Technology
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    • v.22 no.1
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    • pp.45-52
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    • 2016
  • This study reports on the modeling and simulation of heat transfer in packaging boxes used for vaccine shipping. Both water and n-tetradecane are used as primary insulation materials inside a multi-slab system. The one-dimensional model, which is a spherical model using a radius equivalent to the rectangular geometry of container, is applied in this study. N-tetradecane with low thermal diffusivity and proper phase transition temperature exhibits higher heat transfer resistance during both heating and cooling processes compared to water. Thus, n-tetradecane is a better candidate as an insulating material for packaging containers for vaccine shipping. Furthermore, the developed method can also become a rapid and economic tool for screening appropriate phase change materials used as insulation materials with suitable properties in logistics applications.

Experimental Study on the Heat Transfer under the Effects of Wake In a Turbine Cascade (후류의 영향을 고려한 터빈 캐스케이드내 열전달 현상에 대한 실험적 연구)

  • Min, H.K.;Chung, J.T.
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.36-41
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    • 2001
  • In order to simulate wake of stator and a gas turbine engine's balde row, acryl cylinder and a linear turbine cascade were used respectively in this study. Experimental of heat transfer distributions was done on the passage endwall and blade suction surface. Temperature distributions on the experimental regions were obtained through image processing system by using the cholesteric type liquid crystal which has chain structure of metyl$(CH_3)$. To represent the degree of heat transfer, dimensionless St number was used. The results show that heat transfer on the blade suction surface was increased due to the wake from the cylinder and was decreased as the distance between cylinder row and blade row increases. Because of groth of passage vortex, heat transfer distributions on the trailing edge area showed triangular shape which was little changed with wake. On the other hand, heat transfer on the passage endwall was decreased due to the wake from cylinder. As the distance between cylinder row and blade row increases, heat transfer was more decreased.

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Molecular Dynamics Simulation Study of the Ionic Mobility of OH- Using the OSS2 Model

  • Lee, Song-Hi
    • Bulletin of the Korean Chemical Society
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    • v.27 no.8
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    • pp.1154-1158
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    • 2006
  • Anomalously high ionic mobilities of H+ and $OH^-$ are owing to the transfer of $H^+$ by the Grotthus chain mechanism. Molecular dynamics simulations for the system of 215 water including $OH^-$ ion at 298.15 K using the OSS2 model [J. Chem. Phys. 109, 5547 (1998)] as a dissociable water model with the use of Ewald summation were carried out in order to study the dynamics of $OH^-$ in water. The calculated ionic mobility of $OH^-$ is in good agreement with the experimental result and the Grotthus chain mechanism is fully understood.

An Experimental Suggestion on the Transformation of Korean Energy Policies (한국 에너지 정책체계의 전환방안 연구)

  • Park, Jung-Gu
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.1-7
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    • 2010
  • This experimental study suggests some alternatives for stable growth and environmental conservation, responding to the unstability of global energy market and the regulations to greenhouse gas reduction. It introduces the energy-chain approach optimizing the whole processes extending energy production, transfer, and exploitation. And the alternatives are covered from low-carbon & environment-friendly energy-specific innovation system, transformation of major industries to low-carbon & environment-friendly industries, upgrading of energy efficiency, procurement of energy sources to policy cluster.

Parameter Uncertainty and Sensitivity Analysis on a Dose Calculation Model for Terrestrial Food-Chain Pathway (육상식품 섭취경로에 의한 선량계산 모델에서 파라메터의 불확실성 및 민감도 분석)

  • Lee, Chang-Woo;Choi, Yong-Ho;Chun, Ki-Jung;Lee, Jeong-Ho
    • Journal of Radiation Protection and Research
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    • v.16 no.2
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    • pp.67-74
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    • 1991
  • Parameter uncertainty and sensitivity of KFOOD model for calculating the ingestion dose via terrestrial food-chain pathway was analyzed with using Monte-Carlo approach. For the rice ingestion pathway, estimated values from KFOOD code were very conservative. Most sensitive input parameters in model were deposition velocities and soil-to-plant transfer coefficient of radionuclides.

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