• Title/Summary/Keyword: Ceramic-polymer composite

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Fracture Mechanism of Ceramic/Glass-fiber-reinforced-composites Laminate by High Velocity Impact (세라믹/유리섬유강화복합재 적층판의 고속충돌에 의한 파괴거동)

  • Jung Woo-Kyun;Lee Woo-Il;Kim Hee-Jae;Kwon Jeong-Won;Ahn Sung-Hoon
    • Journal of the Korean Society for Precision Engineering
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    • v.23 no.5 s.182
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    • pp.170-176
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    • 2006
  • Multi-layered laminate made of ceramic/composite have been developed to prevent penetration by high velocity impact. In this study, three-layered plates consisted of 1) cover layer (glass fiber reinforced polymer), 2) $Al_{2}O_{3}$, ceramic plate, and 3) backing plate (glass fiber reinforced polymer) were fabricated with various conditions and tested for their ballistic protection characteristic. The ceramic composite laminates, with thin backing plate, were completely penetrated by armor piercing projectile. The plate with inserted rubber between ceramic and backing plate showed excellent ballistic protection, though completely penetrated by the second shoot.

Evaluation of Piezoelectric Properties in Pb(Zr1Ti)O3-PVDF Composites for Thick Film Speaker Application (후막 스피커 응용을 위한 Pb(Zr1Ti)O3-PVDF 복합체의 압전 특성 평가)

  • Son Yong-Ho;Kim Sung-Jin;Kim Young-Min;Jeong Joon-Seok;Ryu Sung-Lim;Kweon Soon-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.10
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    • pp.966-970
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    • 2006
  • We reported on characteristics of the piezoelectric ceramic-polymer composite for the application of the thick-film speaker. The PVDF-PZT composites were fabricated to incorporate the advantages of both ceramic and polymer with various mixing ratios by 3-roll mill mixer. The composite solutions were coated by the conventional screen-printing method on ITO electrode coated PET (Polyethylene terephthalate) polymer film. After depositing the top-electrode of silver-paste, 4 kV/mm of DC field was applied at $120^{\circ}C$ for 30 min to poling the composite films. The value of $d_{33}$ (piezoelectric charge constant) was increased when the PZT weight percent was increased. The maximum value of the $d_{33}$ was 24 pC/N at 70 wt% PZT. But the $g{33}$ (piezoelectric voltage constant) showed the maximum value of $32mV{\cdot}m/N$ at 65 wt% of PZT powder. The SPL (sound pressure level) of the speaker fabricated with the 65:35 composite film was about 68 dB at 1 kHz.

Effects of Absorbent Polymer on the Moisture Resistance and Hydration Characteristics of Cement Pastes (시멘트 페이스트의 특성에 미치는 흡수성폴리머의 영향)

  • 나종균;김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.539-546
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    • 1999
  • Absorbent polymer-cement composites were fabricated by the semi-powder mixing OPC(ordinary Portland cement) with an absorbent polymer. The effects of absorbent polymer on the mechanical properties and the hydration characteristics were observed and the polymer-cement interaction also discussed. Absorbent polymer-cement composites showed the value of total porosity of 8vol% the value of 28 days flexural strength was up to 280 Kgf/cm2 in the case of absorbent polymer-cement composite at 1 wt% absorbent polymer content and microstructure of absorbent polymer-cement composite has been observed more dense than that of OPC paste. Accordingly the permeability of compositewas improved and so the moisture resistance was also increased. Adding polymer did not retard the hydration of OPC. It was considered from the results of IR(infrared) analysis that the functional group of absorbent polymer would be changed from unidentate to bidentate during by the hydration of cement minerals.

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Ceramic - Polymer Nanocomposite: Alternate Choice of Bone

  • Sarkar, Debasish;Chu, Min-Cheol;Cho, Seong-Jai
    • Journal of the Korean Ceramic Society
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    • v.45 no.6
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    • pp.309-319
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    • 2008
  • This study evaluates a range of materials that may be used to design prostheses for bone. It is found that nanocrystalline ceramic-polymer composite could be the best material for prosthetic bone with respect to biocompatibility, morphology, chemistry, and compatibility with the piezoelectric and mechanical behavior of long human bones, such as the femur.

Dielectric and Mechanical Properties of BNT-LCP Composites

  • Park, Myoung-Sung;Cho, Jeong-Ho;Kim, Byung-Ik;Chun, Myoung-Pyo;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.7
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    • pp.547-553
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    • 2011
  • We investigated the dielectric and mechanical properties of ceramic polymer composite xBNT - (1-x)LCP (x= 0, 10, 20, 30, 40 vol.%). The disk shaped BNT ($BaNd_2Ti_4O_{12}$) - LCP (liquid crystal polymer) composite samples were prepared by compression molding method. With increasing the BNT content in composites from 10 to 40 vol.%, the dielectric constant increased but the dielectric loss as well as bending strength of composites reduced. These composites were well described with modified Lichtenecker's model having k = 0.392 and 0.303 for the first and second ball milled BNT filled composites, which means that the BNT filler in composites are well dispersed. The dielectric constant of the composite comprised of the second milled BNT ($D_{50}$ = 1.39 um) was higher that of the composite of the first milled BNT ($D_{50}$= 2.45 um), which seems to be related with the different particle size and dispersion of BNT fillers in LCP matrix. The bending strength of the composite containing the second milled BNT was superior to that of the composite of the first milled BNT.

Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • v.10 no.5
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

Preparation and Characterization of BCB Resin-BNT Composite Substrate Materials (BCB Resin-BNT 복합 기판 소재의 제조 및 특성 평가)

  • Kim, Un-Yong;Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik;Lee, Yong-Hyun;Myoung, Sung-Jae;Han, Ik-Hyun;Shin, Dong-Uk
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.179-183
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    • 2007
  • BCB $Resin-BaNd_2Ti_4O_{12}$(BNT) composites with BNT contents were prepared by tape casting method and epoxy resin-BNT composites were prepared by using heating press. Their dielectric properties and microstructures were investigated. The dielectric properties such as dielectric constant and dielectric loss at 1 MHz for epoxy resin-BNT composites and BCB resin-BNT composites are improved with an increase of BNT volume fraction. The dielectric constant of the Epoxy-BNT composite increased from 5.9 to 7.8 as the volume fraction of BNT increased from 15 to 25. The dielectric constant of the BCB-BNT composite increased from 9.1 to 15.5 as the volume fraction of BNT increased from 30 to 50. The dielectric behavior of BCB-BNT system can be explained by Lichtenecker's equation. The dielectric constant of epoxy resin-BNT composite is smaller than that of BCB resin-BNT composite. These results are considered to be related with the dispersion of BNT filler in polymer matrix from the result of SEM photograph.

Effect of ceramic powder addition on the insulating properties of polymer layer prepared by dip coating method

  • Kim, S.Y.;Lee, J.B.;Kwon, B.G.;Hong, G.W.
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.14-18
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    • 2014
  • The mechanical, electrical and thermal characteristics of insulating materials may significantly affect the performance and reliability of electrical devices using superconductors. General method to provide insulating layer between coated conductors is wrapping coated conductor with Kapton tape. But uniform and compact wrapping without failure or delamination in whole coverage for long length conductor is not a simple task and need careful control. Coating of insulating layer directly on coated conductor is desirable for providing compact insulating layer rather than wrapping insulating layers around conductor. Ceramic added polymer has been widely used as an insulating material for electric machine because of its good electrical insulating properties as well as excellent heat resistance and fairy good mechanical properties. The insulating layer of coated conductor should have high breakdown voltage and possesses suitable mechanical strength and maintain adhesiveness at the cryogenic temperature where it is used and withstand stress from thermal cycling. The insulating and mechanical properties of polymer can be improved by adding functional filler. In this study, insulating layer has been made by adding ceramic particles such as $SiO_2$ to a polymer resin. The size, amount and morphology of added ceramic powder was controlled and their effect on dielectric property of the final composite was measured and discussed for optimum composite fabrication.

Fabrication of Polymer Composite with Enhanced Insulation and Mechanical Properties using Aluminum Borate Nanowhiskers (알루미늄 보레이트 나노휘스커를 이용한 향상된 절연성 및 기계적 특성을 가지는 고분자 복합체 제작)

  • Junhyeok Choi;Sangin Lee;Kiho Song;Taekyung Kim;Changui Ahn
    • Journal of Powder Materials
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    • v.30 no.4
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    • pp.356-362
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    • 2023
  • Inorganic-organic composites find extensive application in various fields, including electronic devices and light-emitting diodes. Notably, encapsulation technologies are employed to shield electronic devices (such as printed circuit boards and batteries) from stress and moisture exposure while maintaining electrical insulation. Polymer composites can be used as encapsulation materials because of their controllable mechanical and electrical properties. In this study, we propose a polymer composite that provides good electrical insulation and enhanced mechanical properties. This is achieved by using aluminum borate nanowhiskers (ABOw), which are fabricated using a facile synthesis method. The ABOw fillers are created via a hydrothermal method using aluminum chloride and boric acid. We confirm that the synthesis occurs in various morphologies based on the molar ratio. Specifically, nanowhiskers are synthesized at a molar ratio of 1:3 and used as fillers in the composite. The fabricated ABOw/epoxy composites exhibit a 48.5% enhancement in mechanical properties, similar to those of pure epoxy, while maintaining good electrical insulation.

Bio-Inspired Synthesis of a Silicate/PMMA Composite

  • Nam, Kyung Mok;Lee, Yoon Joo;Kwon, Woo Teck;Kim, Soo Ryong;Shin, Dong-Geun;Lim, Hyung Mi;Kim, Hyungsun;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.51 no.1
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    • pp.7-10
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    • 2014
  • Abalone shell is composed of 95 wt% $CaCO_3$ platelets and 5 wt% of a protein-rich organic matrix which acts as an adhesive layer, connecting aragonite tablets, thus maintaining the structural integrity of the composite. By mimicking abalone shell, we prepared a silicate plate/polymer nanocomposite by infiltrating PMMA between silicate layers and warm-pressing them at $200^{\circ}C$ for 1 h under 15 tons to make organic-inorganic composite materials. To examine the organic-inorganic composite materials after the warm-pressing procedure, the composite sample was analyzed with FE-SEM and TG. The bending strengths and densities of the composites prepared by a silicate plate and PMMA after the warm-pressing process were ~140 MPa and 1.5, respectively.