• Journal of the Korean Ceramic Society
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• v.50 no.3
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• pp.195-200
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• 2013

Here, we report preparation of cyan ceramic nano-pigment for inkjet printing and the Ni substitutional effects on the cyan color. $MgAl_2O_4$ was selected as the crystalline host network for the synthesis of nickel-based cyan ceramic nano-pigments. Various compositions of $Ni_xMg_{1-x}Al_2O_4$ ($0{\leq}x{\leq}1$) powders were prepared using the polymerized complex method. The powder was then preheated at $400^{\circ}C$ for 5 h and finally calcined at $1000^{\circ}C$ for 5 h. XRD patterns of $Ni_xMg_{1-x}Al_2O_4$ showed a single phase of the spinel structure in all the compositions. The particle sizes ranged from 20 to 50 nm in TEM observations. The characteristics of the color tones of $Ni_xMg_{1-x}Al_2O_4$ were analyzed by UV-Visible spectroscopy and CIE $L^*a^*b^*$ measurement. CIE $L^*a^*b^*$ measurement results indicate that the pigment color changes from light cyan to deep cyan due to the decrease of the $a^*$ and $b^*$ values with an increase of an Ni substitutional amount. In addition, the thermal stability and the binding nature of $Ni_xMg_{1-x}Al_2O_4$ are also discussed using TG-DSC and FT-IR results respectively.

• Journal of Technologic Dentistry
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• v.30 no.2
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• pp.87-92
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• 2008

Purpose: In this study, we tried to compare marginal accuracy when produce ceramic crown using all ceramic materials and existent metal-ceramic system. Material and methods: All-ceramic systems were E-max (Ivoclar/Vivadent, Lichtenstein), Lava(3M, U.S.A.) and Wol-ceram(Teamziereis, Germany). Metal-ceramic system(PFG) was composed of Au-Pt alloy (Metalor, Switzerlandand) and overlying ceramic(D-sign, Ivoclar/Vivadent, Lichtenstein). We fabricated metal master die with upper diameter of 7.95mm, bottom diameter of 9.00mm, height of 5.00mm, and taper of $6^{\circ}$. All ceramic system used 0.5mm thickness ceramic coping, while metalceramic system used 0.3 thickness metal coping. By adding dentin and enamel ceramics on each coping, a crown with a proximal thickness of 1.0 mm and occlusal thickness of 2.0mm was fabricated. Pressure of 2kg was applied for 10 seconds on each crown with static load compressor. Before and after cementation, we measured the marginal gap at 4 points of each crown using optical microscope. The data was analyzed using a Student's t test and repeated-measures of analyses of variance(ANOVA) followed by a Bonferroni test. A p value<0.05 was considered significant. Results: As experiment results, marginal accuracy of wol-ceram and Lava is no good when compared with marginal accuracy of PFG. But marginal accuracy of E.max is good when compared with PFG. This result showed not significant. The marginal accuracy of E.max is good when compared with marginal accuracy of wol-ceram and Lava. Conclusion: The marginal accuracy of E.max is very good when compared with marginal accuracy of another group.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.2
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• pp.101-105
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• 2016

The basic characteristics of glass are highly fragile and brittle consequences the ultimate purpose of glass manufacturing is to make a transparent glass with complex shape. In order to solve this problem, mechanical properties of glass can be increased by crystallization of its amorphous glass. However, glass-ceramics has become opaque through crystallization process due to the distracted interface of glass by precipitated particles. This study has been investigated thermal processing conditions of LAS transparent glass-ceramic by using DTA (differential thermal analysis), in order to control size of precipitated particle and then fabricate transparent glass-ceramic. DTA indicated that crystallization peak area was declined with increased nucleation temperature. Subsequently, we have been established optimum temperature for crystallization depending on the nucleation temperature. The transmission and thermal expansion were measured after crystallization, and the size of precipitated particle was identified in range of 20~100 nm by FE-SEM. In addition, by setting the optimized crystallization condition, with high transmission and low thermal expansion glass was synthesized through this experiment.

• Journal of Powder Materials
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• v.26 no.4
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• pp.327-333
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• 2019

In this study, a process is developed for 3D printing with alumina ($Al_2O_3$). First, a photocurable slurry made from nanoparticle $Al_2O_3$ powder is mixed with hexanediol diacrylate binder and phenylbis(2,4,6-trimethylbenzoyl) phosphine oxide photoinitiator. The optimum solid content of $Al_2O_3$ is determined by measuring the rheological properties of the slurry. Then, green bodies of $Al_2O_3$ with different photoinitiator contents and UV exposure times are fabricated with a digital light processing (DLP) 3D printer. The dimensional accuracy of the printed $Al_2O_3$ green bodies and the number of defects are evaluated by carefully measuring the samples and imaging them with a scanning electron microscope. The optimum photoinitiator content and exposure time are 0.5 wt% and 0.8 s, respectively. These results show that $Al_2O_3$ products of various sizes and shapes can be fabricated by DLP 3D printing.

• Journal of the Semiconductor & Display Technology
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• v.20 no.2
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• pp.61-66
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• 2021

In this study, we studied the alternative of plasma resistant ceramic parts that constitute plasma chambers in the semiconductor dry etching process. MgO-Al₂O₃-SiO₂(MAS) glass was made of 13 types of glass using the Design Of Experiments(DOE) and the effect on thermal properties such as glass transition temperature and crystallization temperature depending on the content of each composition and etching resistance to CF₄/O₂/Ar plasma gas. MAS glass showed excellent plasma resistance and surface roughness up to 20 times higher than quartz glass. As the content of Al₂O₃ and MgO increases, the plasma resistance is improved, and it has been confirmed that it has an inverse relationship with SiO₂.

• Korean Journal of Materials Research
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• v.14 no.1
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• pp.59-66
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• 2004

In the present study, ceramic brake pads without fiber phases were manufactured by the low temperature heat treatment below$ 700 ^{\circ}C$. The manufacturing parameters of ceramic brake pads and those levels were investigated by the analysis results of signal-to-noise ratios, ANOVA based upon the Taguchi method. The ceramic brake pads prepared in the Mg experiment had a friction coefficient of 0.30～0.55 very close to the target coefficient (0.35～0.45) of commercial brake pads utilized in the automobiles. The frictional properties of ceramic brake pads could be stabilized with the adjustment of amounts of lubricating additives. The optimum preparation conditions as well as batch formulations for the fabrication of non-fibrous ceramic brake pads were finally determined using Taguchi method in this study.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.429-430
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• 2002

In this study, three kinds of brake: discs including two coated brake discs and one steel disc were tested under the same experimental conditions on a reduced scale braking test bench. Plasma spray coating technique was used to coat ceramic powder on the discs. In the test, four commercial sintered brake pads were coupled with discs. Ceramic coated discs have shown good stability in friction coefficient at high speed and high energy braking conditions. However, ceramic coated discs caused more wear loss of pad mass than the steel disc. It was shown that thermal barrier effect in ceramic coated discs adjusted the thermal partition between pad and disc. Steel disc showed fluctuating friction coefficient at high speed but less wear loss of pad mass than ceramic coated discs.

• Journal of the Microelectronics and Packaging Society
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• v.18 no.3
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• pp.1-7
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• 2011

Active brazing of ceramic to metal is reviewed in this paper. As one of the key aspect in joint techniques, active brazing has been developed to simplify the manufacturing procedure of brazed joints between ceramic and metal. The active filler metal includes Ag-Cu-Ti series, Cu-Ti series, Co-Ti series and so on. The active filler metal which supplies the chemical bonds between ceramic and metal, enhances the wetting of filler metal on ceramic surface and eliminates the need for metallization treatments. The residual stress caused by difference of coefficient of thermal expansion between ceramic and metal, holds a direct influence on the bonding strength and even results in a fracture. Good joints of ceramic to metal promote the miniaturization and simplicity of electronic components with multifunction.

• Journal of the Korean Ceramic Society
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• v.56 no.6
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• pp.601-605
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• 2019

This work reports the preparation of ceramic hybrid films with illite-polyethylene composites analyzed as a function of concentration of added illite in polyethylene. The enhancement of oxygen and water-vapor transmission rate of illite-polyethylene film was evaluated to determine its influence on the freshness in fruit packaging. Particle size of illite materials was controlled in the range of 1~10 ㎛ and then mixed with LDPE to form the masterbatch. Ceramic hybrid films were prepared through a blown film making process. To determine the dispersity and abundancy of illite materials in the polyethylene matrix, various characterizations of illite-PE hybrid masterbatch and films were performed using SEM, TGA, and FT-IR. The oxygen and water-vapor transmission rate of illite-polyethylene film was found to be two times higher than that of LDPE film.

• Journal of the Korean Ceramic Society
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• v.56 no.6
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• pp.596-600
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• 2019

Artificial intelligence with a sufficient amount of realistic big data in certain applications has been demonstrated to play an important role in designing new materials or in manufacturing high-quality products. To reduce cracks in ceramic products using machine learning, it is desirable to utilize big data in recently developed data-driven optimization schemes. However, there is insufficient big data for ceramic processes. Therefore, we developed a numerical algorithm to make "virtual" manufacturing data sets using indirect methods such as computer simulations and image processing. In this study, a numerical algorithm based on the random walk was demonstrated to generate images of cracks by adjusting the conditions of the random walk process such as the number of steps, changes in direction, and the number of cracks.