• Title/Summary/Keyword: Ceramic matrix

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Electrical Discharge Machining of Alumina Ceramic Matrix Composites Containing Electro-conductive Titanium Carbide as a Second Phase (도전성 탄화티타늄 이차상을 포함하는 산화알루니늄기 세라믹 복합체의 방전가공)

  • 윤존도;왕덕현;안영철;고철호
    • Journal of the Korean Ceramic Society
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    • v.34 no.10
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    • pp.1092-1098
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    • 1997
  • Electrical discharge machining (EDM) was attempted on a ceramic matrix composite containing non-conductive alumina as a matrix and conductive titania as a second phase, and was found successful. As the current or duty factor increased, the material removal rate (MRR) increased and the surface roughness also increased. The EDMed surface was covered with a number of craters of a circular shape having 100-200 microns of diameter. The melting and evaporation was suggested for the EDM mechanism. The bending strength decreased 44% after EDM, but the Weibull modulus increased more than twice. Combination of EDM and barre이 polishing resulted in the maintenance of the bending strength level. Temperature distribution near a spark in the sample was computer-simulated by use of finite element method, and was found to have similar shape to the one which the observed craters have.

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Influence of Fiber Breaks on the Frictional Work in a Continuous Fiber-Reinforced Ceramic Matrix Composite (장섬유로 보강된 세라믹 복합재료에서 섬유파단이 마찰일에 미치는 영향)

  • 조종두
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.7
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    • pp.1730-1737
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    • 1994
  • Theoretical equations for an influence of fiber breaks on the frictional heating phenomenon in a uniaxially fiber-reinforced ceramic matrix composite are formulated. The microslip and gross slip phases are considered for deriving the equations. During a complete loading/unloading cycle, the work done against friction is derived. In order to estimate interfacial shear in a unidirectionally reinforced ceramic matrix composite which has fiber fractures as well as matrix cracks, parametric studies using the derived equations are done. In a case of less than 10% fiber fractures, additional frictional work due to fiber breaks can be neglected compared to the rest.

Recent Research Activities for Continuous SiC Fiber Reinforced Ceramic Matrix Composites in Japan (일본에서의 탄화규소장섬유세라믹스강화 복합재료 연구개발)

  • Ogasawara, Toshio
    • Ceramist
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    • v.9 no.6
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    • pp.18-23
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    • 2006
  • In this article, the present activities regarding research and development of continuous SiC fiber reinforced ceramic matrix composites (CFCC) in Japan are reviewed. The key technologies in SiC fiber composites are interphase between fiber and matrix and its oxidation resistance. To improve oxidation resistance of interphase, various kinds of technologies such as environment barrier coating, high dense matrix, unti-oxidation matrix, multi-layered intephase have been developed. It is suggested that high performance, affordable processing cost, and excellent reliability will be important factors to be in practical use of CMCs in future.

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PROMISE: A QR Code PROjection Matrix Based Framework for Information Hiding Using Image SEgmentation

  • Yixiang Fang;Kai Tu;Kai Wu;Yi Peng;Yunqing Shi
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.17 no.2
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    • pp.471-485
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    • 2023
  • As data sharing increases explosively, such information encoded in QR code is completely public as private messages are not securely protected. This paper proposes a new 'PROMISE' framework for hiding information based on the QR code projection matrix by using image segmentation without modifying the essential QR code characteristics. Projection matrix mapping, matrix scrambling, fusion image segmentation and steganography with SEL(secret embedding logic) are part of the PROMISE framework. The QR code could be mapped to determine the segmentation site of the fusion image as a binary information matrix. To further protect the site information, matrix scrambling could be adopted after the mapping phase. Image segmentation is then performed on the fusion image and the SEL module is applied to embed the secret message into the fusion image. Matrix transformation and SEL parameters should be uploaded to the server as the secret key for authorized users to decode the private message. And it was possible to further obtain the private message hidden by the framework we proposed. Experimental findings show that when compared to some traditional information hiding methods, better anti-detection performance, greater secret key space and lower complexity could be obtained in our work.

Microstructure and Processing of Bioactive Ceramic Composites as Dental Implants (치과 임플란트용 bioactive 세라믹 복합재료의 제조와 미세조직)

  • Kim, Bu-Sob
    • Journal of Technologic Dentistry
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    • v.25 no.1
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    • pp.21-28
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    • 2003
  • The purpose of this study was to process bio-active glass ceramic composite, reinforced with sapphire fibers, by hot press. Also to study the interface of the matrix and the sapphire fiber, and the mechanical properties. Glass raw materials melted in Pt crucible at 1300$^{\circ}C$ during 3.5 hours. The melt was crushed in ball mill and then crushed material, ground and sieved to $<40{\beta}{\mu}m$. Sapphire fibers cut (30mm) and aligned. Powder and fibers hot pressed. The micrographs show good bonding between the matrix and the fiber and no porosity in the glass matrix. This means ideal fracture phenomena. Glass is fractured before the fiber. This is indication of good fracture strength. EDXS showing aluminum rich phase and crystalline phase. Bright field image of the matrix showing crystalline phase. Also diffraction pattern of TEM showing the crystalline phase and more than one phase. Strength of the samples was determined by 3 point bend testing. Strength of the 10vol% sample was approximately 69MPa, while strength of the control sample is 35MPa. Conclusions through this study as follow: 1. Micrographs show no porosity in the glass matrix and the interface. 2. The interface between the fiber and the glass matrix show no gaps. 3. Fracture of the glass indicates characteristic fiber-matrix separation. 4. Presence of crystalline phase at high processing temperature. 5. Sapphire is compatible with bioactive glass.

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Electrical Properties of PVdF/PVP Composite Filled with Carbon Nanotubes Prepared by Floating Catalyst Method

  • Kim, Woon-Soo;Song, Hee-Suk;Lee, Bang-One;Kwon, Kyung-Hee;Lim, Yun-Soo;Kim, Myung-Soo
    • Macromolecular Research
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    • v.10 no.5
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    • pp.253-258
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    • 2002
  • The multi-wall carbon nanotubes (MWNTs) with graphite crystal structure were synthesized by the catalytic decomposition of a ferrocene-xylene mixture in a quartz tube reactor to use as the conductive filler in the binary polymer matrix composed of poly(vinylidene fluoride) (PVdF) and poly(vinyl pyrrolidone) (PVP) for the EMI (electromagnetic interference) shielding applications. The yield of MWNTS was significantly dependent on the reaction temperature and the mole ratio of ferrocene to xylene, approaching to the maximum at 800 $^{\circ}C$ and 0.065 mole ratio. The electrical conductivity of the MWNTs-filled PVdF/PVP composite proportionally depended on the mass ratio of MWNTs to the binary polymer matrix, enhancing significantly from 0.56 to 26.7 S/cm with the raise of the mass ratio of MWNTs from 0.1 to 0.4. Based on the higher electrical conductivity and better EMI shielding effectiveness than the carbon nanofibers (CNFs)-filled coating materials, the MWNTs-filled binary polymer matrix showed a prospective possibility to apply to the EMI shielding materials. Moreover, the good adhesive strength confirmed that the binary polymer matrix could be used for improving the plastic properties of the EMI shielding materials.

Thermo-mechanical Properties and Microstructures of $ZTA-Al_2O_3$ Whisker Composites ($ZTA-Al_2O_3$ Whisker계 복합재료의 미세구조 변화에 따른 열적, 기계적 특성에 관한 연구)

  • 이문환;최성철;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.6
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    • pp.457-468
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    • 1993
  • In oxide matrix-SiC(W) composites, instability and glassy phase formation due to oxidation at the high temperature and the diffusion of Si, respectively, cause brittle fracture and low reliability for ceramic materials. The mode of contribution in each mechanisms induced by matrix-whisker debonding, varies with the morphology of matrix-whisker interfaces. This work has described the dispersion behaviours and stabilization mechanisms in slip systems, and multiple toughening mechanisms by dint of two second phase different from each other when spherical ZrO2 and chemically stable Al2O3(W) is respectively added in Al2O3 matrix. To obtain complexshaped components, slip casted bodies were sintered at 1$600^{\circ}C$, 2hrs up to 98~99% R.D.. Multiple toughening mechanisms in comparison with theories reported until now will be discussed as a result of the phase analysis of ZrO2 by athermal behaviours and microstructural characterizations as well as measured mechanical properties.

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Development of Stretchable PZT/PDMS Nanocomposite Film with CNT Electrode

  • Yun, Ji Sun;Jeong, Young Hun;Nam, Joong-Hee;Cho, Jeong-Ho;Paik, Jong-Hoo
    • Journal of Sensor Science and Technology
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    • v.22 no.6
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    • pp.400-403
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    • 2013
  • The piezoelectric composite film of ferroelectric PZT ceramic ($PbZr_xTi_{1-x}O_3$) and polymer (PDMS, Polydimethylsiloxane) was prepared to improve the flexibility of piezoelectric material. The bar coating method was applied to fabricate flexible nanocomposite film with large surface area by low cost process. In the case of using metal electrode on the composite film, although there is no problem by bending process, the electrode is usually broken away from the film by stretching process. However, the well-attached, flexible CNT electrode on PZT/PDMS film improved flexibility, especially stretchability. PZT particles was usually settled down into polymer matrix due to gravity of the weighty particle, so to improve the dispersion of PZT powder in polymer matrix, small amount of additives (CNT powder, Carbon nanotube powder) was physically mixed with the matrix. By stretching the film, an output voltage of PZT(70 wt%)/PDMS with CNT (0.5 wt%) was measured.

The Role of Inorganic Compounds Additions on the Matrix Microtexture Control of C/C Composite (무기화합물 첨가에 의한 C/C복합재료의 매트릭스 조직제어)

  • ;安田榮
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1151-1158
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    • 1997
  • Fracture of uni-directional carbon fiber reinforced carbon matrix composite is strongly dependent on the orientation of basal plane in graphite matrix when it is limited within matrix. The orientation of basal planes are vertically stacked to carbon fiber which results in the weakness for applied tensile or shear force in thermosetting resin derived-carbon matrix composite. Microtextural control of the matrix was tried through chemical interaction between metal carbides and furan resin derived-carbon matrix. SiC and TiO2 addition made the orientation disordered. However, porosity increased due to decomposition of SiC. Interfacial bonding could be controlled by TiO2 addition, but carbon fiber was considerably reacted with TiC during thermal treatment higher than 2$600^{\circ}C$. Therefore, it is desirable to control the thermal treatment temperature at which decomposition of SiC was not serious and TiC/C was not formed eutectoid.

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