• Title/Summary/Keyword: Cement-paste

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Optimum Abrasing Condition for Recycled Fine Aggregate Produced by Low Speed Wet Abraser Using Sulfur (황산수를 사용한 저속 습식 마쇄법에 의한 순환잔골재의 최적 마쇄조건)

  • Kim, Jin-Man;Kim, Ha-Seog;Park, Sun-Gyu;Kim, Bong-Ju;Kwak, Eun-Gu
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.557-563
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    • 2008
  • Recently, the amount of disposed construction materials like demolished concrete is growing fast and the shortage of natural concrete aggregate is becoming serious. Therefore, recycling of aggregate extracted from the demolished concrete is getting important and use of the recycled aggregate for concrete has been seriously considered. However, the use of the recycled aggregate even for low performance concrete is very limited because recycled aggregate which contains large amount of old mortar has very low quality. Therefore, removing the paste sticked to the recycled aggregate is very important in the manufacturing of high quality recycled aggregate. We have studied a series of research according to complex crushing method, which is removed the ingredient of cement paste from recycled fine aggregate using both the low speed wet abrasion crusher as mechanical process and the acid treatment as chemical processes. This paper is to analyze the quality of the recycled fine aggregate produced by those complex method and investigate optimum manufacturing condition for recycled fine aggregate by the design of experiments. The experimental parameters considered are water ratio, coase aggregate ratio, and abrasion time. As a result, data concerning the properties of recycled sand were obtained. It was found that high quality recycled fine aggregate could be to obtain at the condition of the fifteen minute of abrasion-crusher time and the over 1.0 of recycled coarse aggregate ratio.

Basic Research of Self Compacting Concrete Using Alkali-Activated Slag Binder (알칼리 활성 슬래그 결합재를 이용한 자기충전 콘크리트의 기초 연구)

  • Song, Keum-Il;Shin, Gyeong-Sik;Gong, Min-Ho;Song, Jin-Kyu
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.657-665
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    • 2013
  • The purpose of this study is the basic research of self-compacting concrete using Alkali-Activated Slag (AAS) binder in order to emphasize the durability of structures and facilitate casting the fresh concrete in field. The AAS binder emitted low carbon dioxide ($CO_2$) is eco friendly material of new concept because AAS products not only emit little $CO_2$ during production but also reuse the industrial by-products such as ground granulated blast-furnace slag (GGBS) of the steel mill. Until now, almost of domestic and foreign research are using Ordinary Portland Cement (OPC) for self-compacting concrete, and also, nonexistent research about AAS. The self-compacting concrete must get the performance of flowability, segregation resistance, filling and passing ability. Nine concrete mixes were prepared with the main parameter of unit amount of binder (400, 500, 600 $kg/m^3$) and 3 types of water-binder (W/B) ratio. The results of test were that fresh concretes were satisfied with flowability, segregation resistance, and filling ability of JSCE. But the passing ability was not meet the criteria of EFNARC because of higher viscosity of AAS paste than OPC. This high viscosity of AAS paste enables the manufacturing of self compacting concrete, segregation of which does not occur without the using of viscosity agent. It is necessary that the development of high fluidity AAS binders of higher strength and the study of better passing ability of AAS concrete mixes in order to use self compacting AAS concrete in field.

Assessment of Formwork-Seepage Minimization in High Fluidity, Normal Strength Concrete Utilizing Thixotropic Properties (고유동 일반강도 콘크리트의 요변성 부여에 따른 거푸집 누출 저감 성능 분석)

  • Kim, Young-Ki;Lee, Yu-Jeong;Kim, In-Tae;Han, Dong-Yeop
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.4
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    • pp.337-348
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    • 2023
  • The central objective of this study is to curtail the leakage of mortar or cement paste, often resultant of ill-constructed formwork, by implementing thixotropy in the formulation of high-fluidity, standard-strength concrete. When such concrete is utilized in smaller scale construction projects, instances of formwork gaps due to suboptimal construction precision may lead to significant leakage of mortar and paste, a problem not typically encountered with traditional slump-flow concrete. In this investigation, Polyvinyl Alcohol(PVA) and borax are incorporated into the concrete mixture to induce thixotropy. The experimental design includes varying methodologies for integrating PVA and borax, while assessing alterations in diverse concrete performances, including thixotropy and leakage reduction potential that simulates formwork gap conditions. Under the experimental conditions defined within this study, it was found that replacing, rather than merely adding PVA and borax, aids in averting water addition via suspensions. This approach yielded promising results in terms of concrete properties and proved efficacious in stemming leakage in concrete possessing sufficient thixotropy. Notably, when a 6% PVA suspension was substituted, a significant reduction in leakage was observed. Consequently, it is projected that construction quality can be ensured, even with lower precision formwork, by applying thixotropy to concrete through the use of PVA and borax.

Physical Properties of Photosynthetic Cyanobacteria Applied Porous Concrete by CO2 Sequestration (광합성 남세균을 도포한 투수 콘크리트의 이산화탄소 고정에 의한 물성 변화)

  • Indong Jang;Namkon Lee;Jung-Jun Park;Jong-Won Kwark;Hoon Moon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.416-424
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    • 2023
  • Concrete emits a large amount of carbon dioxide throughout its life cycle, and due to the societal demand for carbon dioxide reduction, research on storing carbon dioxide in concrete in the form of minerals is ongoing. In this study, cyanobacteria, which absorb carbon dioxide through photosynthesis and fix it as calcium carbonate, were applied to a porous concrete substrate, and the changes in the properties of the concrete substrate due to their special environmental curing condition were analyzed. The results showed that the calcium carbonate precipitation by the microorganisms was concentrated in the light-exposed surface area, and most of the precipitation occurred in the cement paste part, not in the aggregate. This microbially induced calcium carbonate precipitation enhanced the mechanical performance of the paste and improved the overall compressive strength as the curing age progressed. In addition, the increase in microbial biofilm and calcium carbonate improved the pore structure, which influenced the reduction in water permeability.

Arsenic removal from artificial arsenic water using CaAl-monosulfate and CaAl-ettringite (CaAl-monosulfate와 CaAl-ettringite를 이용한 인공비소폐수의 비소 제거 연구)

  • Shim, Jae-Ho;Kim, Ki-Baek;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.141-148
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    • 2012
  • The objective of this study is to remove arsenate from artificially contaminated wastewater using CaAl-ettringite and CaAl-monosulfate which were synthesized in laboratory. The study was carried on the basis of solidification/stabilization of waste using cement. Monosulfate and ettringite are constituents of cement paste. The CaAl-ettringite has a chemical formula of $Ca_6Al_2O_6(SO_4)_3{\cdot}32H_2O$ and has a needle like morphology. Whereas CaAl-monosulfate $Ca_4Al_2O_6(SO_4){\cdot}12H_2O$ has layered double hydroxide structure (LDH) in which the mainlayer consists of Ca and Al and S as interlayer. Ettringite and monosulfate were synthesized by reaction of tricalcium aluminate and gypsum and hydrating this mixture at elevated temperature. The synthesized mineral were characterized by PXRD and FESEM to ensure purity. It was found that concentrations of As(V) in contaminated water were reduced from initial concentration of 1.335 mmol/L to 0.054 mmol/L and 0.300 mmol/L by CaAl-monosulfate and CaAl-ettringite respectively. The post experimental results of PXRD and FESEM analysis indicate that arsenate removal was by ion exchange.

The Analysis of Early Age Properties of Hydration Heat and Autogenous Shrinkage according to Specimen Size and Retardation of Hydration (시험체 크기 및 수화지연 효과에 따른 초기재령 수화발열 및 자기수축 특성 분석)

  • Kim, Gyu-Yong;Koo, Kyung-Mo;Lee, Hyoung-Jun;Lee, Eui-Bae
    • Journal of the Korea Concrete Institute
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    • v.21 no.4
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    • pp.481-488
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    • 2009
  • It has been reported that the magnitude and the development rate of autogenous shrinkage of cement paste, mortar and concrete were affected by history and magnitude of inner temperature at an early age. But it was not enough to explain the relation between hydration heat and autogenous shrinkage at an early age, because there was no certain analysis on histories of hydration heat and autogenous shrinkage in previous studies. In our prior study, to understand the relationship between hydration heat and autogenous shrinkage of concrete at an early age, the analysis method for histories of hydration heat and autogenous shrinkage was suggested. Based on this method, early age properties of hydration heat and autogenous shrinkage of high strength concrete with different sizes and hydration retardation were investigated in this study. As a result of the study, properties of hydration temperature and autogenous shrinkage were different according to specimen size and hydration retardation. However, there was a close relationship between hydration temperature and autogenous shrinkage at an early age, especially between HHV and ASV as linear slopes of the sections where hydration temperature and autogenous shrinkage increase rapidly; the higher HHV, the higher ASV and the greater ultimate autogenous shrinkage. And it was found that, among the setting time, bend point and temperature increasing point, they were close relationship each other on cement hydration process.

Structure and physical properties of the earth crustal material in the middle of Korean Peninsula : A study on the prescription of standard test by mortar-bar method (한반도 중부권 지각물질의 구조와 물성연구 : 콘크리트 공시체에 의한 표준시험 규정에 대하여)

  • 정진곤;유신애
    • The Journal of Engineering Geology
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    • v.5 no.2
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    • pp.193-200
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    • 1995
  • It has been well known that the alkali-aggregate reaction between the aggregates and cement paste is one of the reasons of a concrete siructre expansion. Because of a serious demage on the concrete stnicture from the expansion, in many countries, the safety of the materials is checked in laboratory by mortar-bar test and the upper limit of expansion in length is 0.1%. The prescriptions are presented in the ASTM C227 and 490 of U.S. which has been international currency and in the KS Handbook F2503, F2546 and L5107 of Korea published by Korean Standards Association. Both of the prescriptions are almost same in their contents. Actually, in the process of preparing and measuring the mortar-bar according to the prescription mentioned above, it seems that there are no problems for its own purpose but a few points are found to be improved upon the methods to increase the accuracy for laboratory work as follows. 1. The prescription of blending ratio(aggregate, cement and water) should be noted by volume not by weight. 2. It is unreasonable to measure the initial length of mortar bars after 24$\pm$2 hours at once regardless the kind of aggregates. 3. It may bring about errors in calculating the expansion ratio under the condition of the denominator value fixed as 254mm. 4. The measuring methods of specific gravity are selected according to the purposes but the pure specific gravity displays the highest accuracy among them.

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Characterization of Concrete Composites with Mixed Plastic Waste Aggregates (복합 폐플라스틱 골재 치환 콘크리트의 기초 물성 평가)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Uk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.317-324
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    • 2020
  • Plastic wastes generated from domestic waste are separated by mixed discharge with foreign substances, and the cost of the separation and screening process increases, so recycling is relatively low. In this study, as a fundamental study for recycling mixed plastic wastes generated from domestic waste into concrete aggregates, changes in concrete properties according to the plastic waste types and the substitution rate were evaluated experimentally. The mixed plastic waste aggregate(MPWA) was found to have a lower density and a higher absorption rate compared to the coarse aggregate with good particle size distribution. On the other hand, the single plastic waste aggregate(SPWA) was composed of particles of uniform size, and both the density and the absorption rate were lower than that of the fin e aggregate. It was found that the MPWA substitution concrete did not cause a material separation phenomenon due to a relatively good particle size distribution even with the largest amount of plastic waste substitution, and the amount of air flow increased little. The compressive strength and flexural strength of the PWA substitution concrete decreased as the amount of substitution of the PWA increased due to the low strength of the PWA, the suppression of the cement hydration reaction due to hydrophobicity, and the low adhesion between the PWA and the cement paste. It was found that the degree of deterioration in compressive strength and flexural strength of concrete substituted with MPWA having good particle size distribution was relatively small.

Properties of Cement Paste Containing High Volume γ-C2S and MgO Subjected to CO2 Curing (γ-C2S 및 MgO를 다량 혼입한 시멘트 페이스트의 CO2 양생유무에 따른 특성변화)

  • Sung, Myung-Jin;Cho, Hyeong-Kyu;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.281-289
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    • 2015
  • Carbonation of concrete causes reduction of pH and subsequently causes steel corrosion for reinforced concrete structure. However, for plain concrete structure or PC product, it can lead to a decrease in porosity, high density, improvement of concrete, shrinkage-compensation. Recently, based on this theory, research of $CO_2$ curing effect has been performed, but it was mainly focused on its effects on compressive strength using only ordinary portland cement. Researches on $CO_2$ curing effect for concrete containing $CO_2$ reactive materials such as ${\gamma}-C_2S$, MgO haven't been investigated. Therefore, this study has performed experiments under water-binder ratio 40%, and the replacement ratios of ${\gamma}-C_2S$ and MgO were 90%. Micro-chemical analysis, measurement of compressive strength according to admixtures and $CO_2$ curing were investigated. Results from this study revealed that higher strength was measured in case of $CO_2$ curing compared with none $CO_2$ curing for plain specimen indicating difference between 1.08 and 1.26 times, in case of ${\gamma}-C_2S$ 90, MgO 90 specimen, incorporating high volume replaced as much as 90%, it was proven that when applying $CO_2$ curing, higher strength which has difference between 14.56 and 45.7 times, and between 6.5 and 10.37 times was measured for each specimen compared to none $CO_2$ curing. Through micro-chemical analysis, massive amount of $CaCO_3$, $MgCO_3$ and decrease of porosity were appeared.

Evaluation of Hydration Heat of Mass Concrete with Capsulated Slurry PCM and FEM Study for Analyzing Thermal Crack (캡슐형 슬러리 PCM을 혼입한 매스콘크리트의 수화열 평가 및 온도균열 FEM 해석에 관한 연구)

  • Park, ChangGun;Kim, Bo-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.379-388
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    • 2014
  • The purpose of this study is to investigate the effect of capsulated slurry phase change material (PCM) on the thermal crack in mass concrete by experimental work and FEM analysis. In this study, three conditions of samples were prepared for evaluating the level of hydration heat, i.e., a material condition, a cement paste condition and a concrete condition. Also, a compressive strength test was conducted for FEM inverse analysis. Based on the results of the experiment, exothermic function coefficients of concrete with encapsulated slurry PCM were deducted by the inverse analysis. After that, they applied to FEM analysis of the mass scale concrete structures. From the results of this experiment, $31^{\circ}C$ capsulated slurry PCM had no super cooling phenomenon in the material condition. In the cement condition, hydration heat decreased by 34.61J when PCM of 1g was mixed. In the concrete condition, PCM of 6% was deducted as the best level in hydration heat absorption. In FEM inverse analysis, rate coefficient of reaction gradually decreased when PCM mixing ratio increased. But, temperature-rise coefficient increased when PCM mixing ratio exceeded 6%. For the inversed exothermic function coefficients applying to large scale concrete structures, a thermal cracking index increased by 0.05 when PCM of 1% was mixed.