• Title/Summary/Keyword: Cement-paste

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Rheological Evaluation of Blast Furnace Slag Cement Paster over Setting Time (고로슬래그 혼합 시멘트 페이스트의 응결시간 경과에 따른 레올로지 특성)

  • Cho, Bong-Suk;Ahn, Jae-Cheol;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.6
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    • pp.505-512
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    • 2016
  • Even though high performance concrete was developed according to the trend of bigger and higher of reinforced concrete building, the rheological evaluations such as viscosity, yield stress are not enough to use as input data to accomplish the numerical analysis for the construction design. So there are many problems in the harden concrete such as poor compaction, rock pocket and crack, etc. in the field. In this study, consistency curves were measured by the viscometer as hydration reaction time passed. At the same time the slump flow test and Vicat setting test were carried out for comparing with the results of rheological properties. The fluidity of the W/B 30% decreased as the increase of replacement ratio of blast furnace slag. But in case of W/B 40%, the replacement ration did not significantly influenced to the slump flow value with the passage of hydration time. By the replacement of blast furnace slag to cement, initial setting was delayed and the time gap between initial and final setting became shorten. Through the regression analysis using Bingham model, there are a sudden changes of viscosity and yield stress around initial setting in case of low W/B 30%. The increase of workability by the change of free water in cement paste was offset by the coating effect of impermeable layer in case of W/B 40%.

A Study on the Pozzolan Reactivity and Mechanical Characteristic of Blended Portland Cements using CFBC Fly Ash (순환유동층 플라이 애시를 사용한 혼합시멘트의 포졸란 반응성과 역학적 성질에 관한 연구)

  • Park, JongTak;Oh, Hongseob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.207-213
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    • 2018
  • Nowadays, circulating fluidized bed combustor(CFBC) boilers system that can reduce environmental pollution particles are widely used in electric power plants. But the fly ash generated from CFBC boilers has lower $SiO_2$ and higher MgO and $SO_3$ contents and also has free CaO inducing expansion and abrupt initial setting of concrete. Therefore, revised KSL5405 for CFBC fly-ash as well as pulverized coal combustion(PCC) is introduced in the concrete field. In this study, the chemical properties and mechanical properties of blended cements with PCC and CFBC fly-ash produced in Korea are analyzed. The blended cement with only CFBC fly ash shows a lower length change than OPC but a higher flow change ratio. The compressive strength of blended cement paste with PCC and CFBC fly ash is slightly greater than that of cement paste with only PCC fly-ash. Based on the results, CFBC flyash blended cement products should be used with PCC flyash to ensure the material stability and material properties.

Experimental Study on the Material Characteristics of Slag Cement with Various Phosphogypsum Materials (인산부산석고의 각 형태조건에 따른 슬래그 시멘트의 품질특성에 관한 실험적 연구)

  • Park, Jong-Tak;Oh, Hong-Seob
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.729-735
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    • 2009
  • In this study, it is experimentally verified a feasibility of the wasted phosphogypsum ($CaSO_4/H_2O$) that is a byproduct from the phosphoric acid process of manufacturing fertilizers can be applied as an admixture in slag cement. For the test, phosphogypsum is modified as dihydrate, hemihydrate, type III anhydrite, and type II anhydrite, and then chemical characteristics and mechanical properties of various slag cements containing above mentioned gypsum materials were analyzed. The test results show that the gypsum made at high temperature has better quality with decrease of water-soluble phosphoric acid ($S-P_2O_5$) which has an effect on the quality of cement. And type II anhydrite shows superior quality in terms of drying shrinkage and the compressive strength of cement paste with hemihydrate at 56 days is higher than other gypsum material.

Effects of Mineral Admixture on the Paste Fluidity and Mortar Strength Development of High Chloride Cement (염소 고함유시멘트의 페이스트 유동성과 모르타르 강도발현성에 미치는 무기질 혼화재의 영향)

  • Jeong, Chan-Il;Park, Soo-Kyung;Lee, Eui-Hak;Lee, Kyung-Hee
    • Journal of the Korean Ceramic Society
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    • v.44 no.1 s.296
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    • pp.43-51
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    • 2007
  • Fluidity, setting time, hydration heat, bond water ratio, compressive strength, SEM and BET of OPC were measured by adding 1.0 wt% KCl and replacing 20 wt% mineral admixture in order to examine effects of blast furnace slag (BFS), limestone powder (LSP), and fly ash (FA) on fluidity and strength development of the cement contained much chloride. In general, the cement contained much chloride was high in heat of hydration, short in its setting time, low in its fluidity and low in its strength at 28 days due to the rapid hydration in its initial stage. As a result of the experiment, it has been demonstrated that fluidity became improved but the compressive strength at 28 days was decreased as replaced LSP to the cement contained much chloride. the fluidity and compressive strength at 28 days was improved as replaced BFS, the initial compressive strength development was improved due to the activation of initial reaction by KCl. Fluidity, initial compressive strength and late compressive strength at 28 days of cement contained much chloride replaced 5 wt% LSP and 15 wt% BFS concurrently was better than OPC, but the hydration heat was lower.

A Study on the Basic Properties of Concrete and Low Heat-Blended Cement with Bottom Ash (바텀애시를 이용한 저발열 혼합시멘트 및 콘크리트의 기초물성에 관한 연구)

  • Kim, Won-Ki;Kim, Hoon-Sang;Kim, Hong-Joo;Lee, Won-Jun;Shin, Jin-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.685-688
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    • 2008
  • This study has examined the effect of bottom ash(BA) on the properties of low heat-blended cement(LHC) and concrete. A number of binders were prepared by the replacement of LHC with BA in range of 5$^{\sim}$20wt%. The results showed that the final setting time of cement paste were delayed when the BA replaced part of the cement. However, The heat of hydration increased narrowly with adding BA in a early hydration period. The results also showed the inclusion of BA at replacement levels of 5$^{\sim}$10wt% resulted in an increase in compressive strength of the specimens compared with that of the control concrete and improved a resistance of concrete against the sulfate and chlorine ion.

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Experimental Study on the Setting Time and Compressive Strength of Nano-Micro Pozzolanic Binders as Cement Composites (포졸란 혼화재의 입자 크기 및 비표면적에 따른 응결시간 발현 및 압축강도 특성 평가)

  • Kim, Won-Woo;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.269-275
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    • 2022
  • In this study, the setting time and compressive strength of cement paste composites applied with nano-micro pozzolanic binders were experimental analyzed. The pozzolanic binder was reduced initial and final setting time and the compressive strength was increased. Micro silica was effective in decrease the initial setting and final setting time and impressing the compressive strength. When two or more cement binders were used, the using of silica fume and a small amount of nano silica at reduced the setting time to 62-64 % to OPC cement and the compressive strength was increased to 117 %. A small amount of mixing the nano silica was effect to pore filling and pozzolanic activation. However, the addition of a chemical admixture should be considered when mixing table design because pozzolanic binders high specific surface area causes a decrease in cement composites flow.

Effect of limestone calcined clay cement (LC3) on the fire safety of concrete structures

  • Gupta, Sanchit;Singh, Dheerendra;Gupta, Trilok;Chaudhary, Sandeep
    • Computers and Concrete
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    • v.29 no.4
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    • pp.263-278
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    • 2022
  • Limestone calcined clay cement (LC3) is a low carbon alternative to conventional cement. Literature shows that using limestone and calcined clay in LC3 increases the thermal degradation of LC3 pastes and can increase the magnitude of fire risk in LC3 concrete structures. Higher thermal degradation of LC3 paste prompts this study toward understanding the fire performance of LC3 concrete and the associated magnitude of fire risk. For fire performance, concrete prepared using ordinary Portland cement (OPC), pozzolanic Portland cement (PPC) and LC3 were exposed to 16 scenarios of different elevated temperatures (400℃, 600℃, 800℃, and 1000℃) for different durations (0.5 h, 1 h, 2 h, and 4 h). After exposure to elevated temperatures, mass loss, residual ultrasonic pulse velocity (rUPV) and residual compressive strength (rCS) were measured as the residual properties of concrete. XRD (X-ray diffraction), TGA (thermogravimetric analysis) and three-factor ANOVA (analysis of variance) are also used to compare the fire performance of LC3 with OPC and PPC. Monte Carlo simulation has been used to assess the magnitude of fire risk in LC3 structures and devise recommendations for the robust application of LC3. Results show that LC3 concrete has weaker fire performance, with average rCS being 11.06% and 1.73% lower than OPC and PPC concrete. Analysis of 106 fire scenarios, in Indian context, shows lower rCS and higher failure probability for LC3 (95.05%, 2.22%) than OPC (98.16%, 0.22%) and PPC (96.48%, 1.14%). For robust application, either LC3 can be restricted to residential and educational structures (failure probability <0.5%), or LC3 can have reserve strength (factor of safety >1.08).

A Study on Properties of High Blaine Cement for Shotcrete (숏크리트용 고분말도 시멘트의 특성)

  • Kim, Jae-Young;Kim, Teuk-Jun;Lee, Min-Suk;Ryoo, Dong-Woo
    • Journal of the Korea Concrete Institute
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    • v.22 no.5
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    • pp.633-640
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    • 2010
  • This study was performed to get basic information about properties of high blaine cement for shotcrete use. Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of high blaine cement. Setting time of high blaine cement was shorter and compressive strength was higher than those of ordinary portland cement (OPC). Results of analysis showed early hydration products of high blaine cement is smaller and spread widely due to increased specific surface. From the SEM observation and analysis of DSC and XRD results, it was seen that the aluminates accelerators promoted calcium aluminium hydrates while the alkali free accelerators increased ettringite and monosulfates formation. Strength and setting time measurement of cement paste with aluminate accelerator is more effective than the alkali free accelerator in reducing the setting time and increasing early strength while alkali free accelerator is more effective in increasing the strength after 7 days.

The Properties of Flexural Strength and Density of Extrusion Molding Concrete Panel Using Sepiolite (세피올라이트를 이용한 압출성형 콘크리트 패널의 휨강도 및 밀도 특성)

  • Jung, Eun-Hye;Kang, Cheol;Kim, Jae-Won;Lee, Jung-Koo;Choi, Hun-Gug;Kim, Jin-Man
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.49-52
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    • 2006
  • Extrusion concrete panel is made by extrusion of high viscosity paste. The high viscosity paste is made by mix of cement, silica, reinforced fiber and thickening agent in the dry mixer and wet mixer subsequently, extrusion in the extruder, and curing in the normal steam curer and high pressure steam curer subsequently. To increase a flexural strength of the panel, it is used inorganic fiber as like asbestos. But it was known that the asbestos was harmful to human being lately, in the domestic area it is restricted usage in the construction materials. So, it is demanded the alternative material for asbestos in the extrusion concrete panel. This study is to investigate that the sepiolite is possible to be the alternative of asbestos. The 3 types of sepiolite is applied to the extrusion concrete panel. To investigate the properties of the panel with sepiolite, it is compared the control with asbestos in the flexural strength, the specific density and the spot compressive strength. From the test results, it was found that the panel with sepiolite B is higher than the control with asbestos in the flexural strength and in the density.

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Numerical modeling of drying shrinkage behavior of self-compacting concrete

  • Chen, How-Ji;Liu, Te-Hung;Tang, Chao-Wei
    • Computers and Concrete
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    • v.5 no.5
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    • pp.435-448
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    • 2008
  • Self-compacting concrete (SCC), characterized by the high flowability and resistance to segregation, is due to the high amount of paste (including cement and mineral admixtures) in contrast with normal concrete (NC). However, the high amount of paste will limit the volume fractions of coarse aggregate,and reduce the tendency of coarse aggregate to suppress drying shrinkage deformations. For this reason, SCC tends to produce higher values of drying shrinkage than NC for the most part. In order to assess the drying shrinkage of SCC quantitatively for application to offshore caisson foundations, the formulas presented in the literatures (ACI 209 and CEB-FIP) are used to predict the values of drying shrinkage in SCC according to the corresponding mix proportions. Additionally, a finite element (FE) model, which assumes concrete to be a homogeneous and isotropic material and follows the actual size and environmental conditions of the caisson, is utilized to simulate stress distribution situations and deformations in the SCC caisson resulting from the drying shrinkage. The probability of cracking and the behavior of drying shrinkage of the SCC caisson are drawn from the analytic results calculated by the FE model proposed in this paper.