• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 춘계 학술논문 발표대회
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• pp.205-206
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• 2019

This study investigated the fluidity and compressive strength properties of blast furnace slag based non-cement paste containing ferronickel slag powder to evaluate the possibility of use in for cement replacement materials. As a result, the fluidity of non-cement paste showed a higher flow as the mixing ratio of ferronickel slag powder increased. The compressive strengths similar to those of the non-cement paste using only blast furnace slag powder were obtained when 5 and 10% of ferronickel slag powder were used.

• 한국세라믹학회지
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• 제47권5호
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• pp.426-429
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• 2010

The Influence of the character of fly ash on the fluidity of cement paste with a polycarboxylic acid type superplasticizer was investigated in connection with the particle size distribution, unburned carbon content, specific surface area and shape of the fly ash. The fluidity of the fly ash cement paste with an added 20 vol% fly ash increases with an increasing roundness of the fly ash and it decreases with an increasing n-value of the fly ash cement. There is a linear correlation between the roundness/n-value and the fluidity of fly ash cement paste.

• Computers and Concrete
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• 제11권4호
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• pp.317-336
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• 2013

In this study, the pore structure of Portland cement paste is experimentally characterized by MIP (mercury intrusion porosimetry) and nitrogen adsorption, and simulated by a newly developed status-oriented computer model. Cement pastes with w/c=0.3, 0.4 and 0.5 at ages from 1 day to 120 days are comprehensively investigated. It is found that MIP cannot generate valid pore size distribution curves for cement paste. Nevertheless, nitrogen adsorption can give much more realistic pore size distribution curves of small capillary pores, and these curves follow the same distribution mode. While, large capillary pores can be effectively characterized by the newly developed computer model, and the validity of this model has been proved by BSE imaging plus image analysis. Based on the experimental findings and numerical simulation, a hypothesis is proposed to explain the formation mechanism of the capillary pore system, and the realistic representation of the pore structure of hydrated cement paste is established.

• Advances in concrete construction
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• 제7권3호
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• pp.175-181
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• 2019

Low-calcium fly ash (LCFA) were used to prepare cement/LCFA specimens in this study. The basic physical properties including water demand, fluidity, setting time, soundness and drying shrinkage of cement/LCFA paste were investigated. The effects of curing time, immersion time and wet-dry cycles in 3% $Na_2SO_4$ solution on the compressive strength and the microstructures of specimens were also discussed. The results show that LCFA increases the water demand, setting time, soundness of cement paste samples. 50% and 60% LCFA replacement ratio decrease the drying shrinkage of hardened cement paste. The compressive strength of plain cement specimens decreases at the later immersion stage in 3% $Na_2SO_4$ solution. The addition of LCFA can decrease this strength reduction of cement specimens. For all specimens with LCFA, the compressive strength increases with increasing immersion time. During the wet-dry cycles, the compressive strength of plain cement specimens decreases with increasing wet-dry cycles. However, the pores in the specimens with 30% and 40% LCFA at early ages could be large enough for the crystal of sodium sulfate, which leads to the compressive strength increase with the increase of wet-dry cycles in 3% $Na_2SO_4$ solution. The microstructures of cement/LCFA specimens are in good agreement with the compressive strength.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.505-508
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• 2003

The rheological properties of cement paste system mixed with mineral admixture for the purpose of increasing the strength and improving durability and rheology of concrete were investigated. The results were as follows: The rheological properties of one-ingredient paste system were improved with increasing the dosage of superplasticizer. For two-ingredients paste system, increasing the replacement rate of BFS(blast furnace slag) and FA(fly ash), the yield value and plastic viscosity were decreased compared with non-replacement. In the OPC(ordinary portland cement)-SF(silica fume) system, increasing the replacement rate of SF, the plastic viscosity and yield value increased linearly. In three-ingredients paste system, both OPC-BFS-SF and OPC-FA-SF system, the rheological properties were improved compared with the only replacement of SF. Both two- and three- ingredients paste system, the rheological properties using BFS were improved more than FA.

• 콘크리트학회지
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• 제11권2호
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• pp.85-94
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• 1999

플라이애쉬 대체량에 따른 변화, 양생방법이 미치는 영향 그리고 조기강도를 높이기 위해 첨가된 화학 혼화제가 시멘트-플라이애쉬 페이스트의 특징 및 콘크리트 강도에 미치는 영향을 알아보았다. 시멘트-플라이애쉬 페이스트의 압축강도는 시멘트로만 만들어진 페이스트보다 낮았으며, 플라이애쉬의 대체량이 증가할수록 강도차이가 증가하였다. 그러나 증기양생시 시멘트-플라이애쉬 페이스트는 수중양생시보다 압축강도가 증가하였으며, 특히 조기강도가 크게 향상되었다. 조기강도 증진을 목적으로 혼입한 활성화제($Na_2SO_4$)의 첨가는 시멘트-플라이애쉬 페이스트 조기강도를 증진시켰으며, 또한 $Na_2SO_4$와 플라이애쉬를 30% 함유한 플라이애쉬 콘크리트의 강도도 월등히 향상되었다.

• 한국세라믹학회지
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• 제45권6호
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• pp.336-344
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• 2008

Rheological properties of cement pastes containing blast furnace slag (BFS: 3,900, $7,910\;cm^2/g$) or fly ash powder (FA: 4,120, $8,100\;cm^2/g$) according to the ratio of water/binder (W/B) and the dosage of polycarboxylate type superplasticizer (PC) were investigated by a mini slump and a coaxial cylinder viscometer. In this experiment, the ratio of replacing OPC with BFS or FA was 30 wt%, the W/B was from 30 to 70 wt%. As a result, the fluidity of cement paste containing BFS or FA was improved with increasing W/B and the dosage of PC. BFS or FA replaced cement paste with W/B 70% and PC 0.3% showed the highest fluidity. The segregation range of cement paste was occurred below $10\;d/cm^2$ of the yield stress and below 50 cPs of the plastic viscosity by the coaxial cylinder viscometer. And also it was formed that the plastic viscosity and the yield stress of FA replaced cement paste were higher than them of BFS replaced cement paste.

• 한국도로학회논문집
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• 제19권5호
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• pp.77-88
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• 2017

PURPOSES : It is necessary to clarify the rheological properties of cement paste as a basic research in the development of mechanistic concrete mix design. The rheological properties of cement paste with different binder types, mix propositions, and with/without high range water reducers have been analyzed. METHODS : In this study, ordinary Portland cement, fly-ash, blast furnace slag, silica fume, and limestone powder were used as binders. The range of water-binder ratio was 0.3-0.5, and a total of 30 different mixes have been tested. The slump flow test, V-funnel test, and Dynamic Shear Rheometer (DSR) test were performed to analyze the rheological properties of cement paste. RESULTS : As a result of the slump flow test, it was found that the composition ratio of the binder contents greatly affected the paste flow when the high range water reducers were added. The results of V-funnel test showed that when the water-binder ratio was decreased without high range water reducers, the binder composition ratio had a large effect on the passing time of the V-funnel tester, but with high range water reducers the impact of the binder composition ratio was decreased. The slump flow and V-funnel have a certain relationship with the rheological factors (yield stress and plastic viscosity), but the correlation was not significant. Finally, we proposed the M-value considering the density and specific surface area of the binder. The correlation between rheological factors and M-value were better demonstrated than experimental values, but there is still a limit to predict the rheological factor in general mix design. CONCLUSIONS :In this study, the rheological properties of cement paste were analyzed. The binder type, composition ratio of binder, and with/without high range water reducers have combined to provide the complex effects on the rheological properties of cement paste. The correlation between the proposed M-value and rheological factor was found to be better than experimental results, but needs to be improved in the future.

• 한국세라믹학회지
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• 제24권3호
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• pp.282-288
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• 1987

Diffusion of Cl- ion in hardened cement paste with slag and siliceous powder such as silica fume and white carbon was investigated. The addition of admixtures reduces the content of Ca(OH)2, which is the main cause of pore formation by corrosive action of sea-water. The addition of admixtures makes the hardened cement paste dense, thereby restricting the diffusion of Cl- ion and improving the resistance to sea-water. Apparence diffusion coefficient of Cl- ion in hardened ordinary portland cement paste was 3.7${\times}$10-8$\textrm{cm}^2$/sec, while that for the hardened cement paste with the admixture was 1.2∼3.2${\times}$10-8$\textrm{cm}^2$/sec.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.189-194
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• 2002

Many researches in the past have shown that a majority initial cracking in concrete are caused during early age period. Therefore, the close examination of early age concrete behavior under various stress conditions is necessary to fully understand the cracking mechanism of concrete. In this study early age cement paste specimen is axially strained up to 20% of its original length by laterally reinforcing it. This type of test is called "Tube Squash Test" and has been previously used to apply up to 50% axial strain on concrete. Microscopic analyses (XRD, FESEM, EDS and DSE/TG) are performed on 20% axially strained early age cement paste specimen. The analysis results show that the microscopic structures and material characteristics of 20% axially strained cement paste remained same as the unstrained cement paste.