• Journal of the Korean Ceramic Society
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• v.26 no.5
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• pp.609-616
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• 1989

For the development of high durable portland cement, it was tested that the some physical properties of ordinary portland cements (OPC) treated with 0.3-1.5wt.% asphalt and 0.5-1.0wt.% carbon black. From the results, the contact angles of water against cements treated with more than 0.6wt.% asphalt were increased over 80 degrees, the initial and the final setting times of cement paste were delayed about 20min. according to the every 0.3wt.% increase of asphalt. The first and the second pick heights of the hydration curve of the cement were considerabely decreased and the induction period of that was increased. And so, the cumulative hydration heat of the cement which was treated with 0.6wt.% asphalt and 0.5wt.% carbon black was lower about 10cal/g than that of ordinary portland cement during 42 hydration times.

• Journal of the Korean Ceramic Society
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• v.37 no.6
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• pp.576-582
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• 2000

Two type of expanding cement generally referred to as CSA with Hauyne(3CaO 3Al2O3 CaSO4) and Quick lime(CaO). Hauyne is formed to ettringite when there are presented with CaO and CaSO4, and CaO reacts wtih water to form Ca(OH)2. REcently, the mechanism of compensation and expand mortar or concrete tend to same and it has been used improving on its shrink property. The volume of cement paste varies with its water content shrink with drying and re-wetting. Concrete and mortar works are required shrinking compensation and expansion properties to reduce of potential crack. The use of expansion cement may improve on its shrinking volume changes. CSA dosages for shrinking compensation limited by cement weight, but obtained difference expansion rate with varied W/C or inorganic admixture. This paper studies expansion rate according to expansion cement dosages, water and inorganic admixtures as Silica fume. Therefor, the expansion factor has to considered before the application.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10b
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• pp.888-893
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• 1998

Calcium sulfoaluminate, $C_4$A$_3$$\bar{S}$, was prepared for reutilizing industrial by-products, such as II-CaSO$_4$, Al(OH), CaF$_2$ and cement sludge wastes. Mixed powder was fired at 1,15$0^{\circ}C$. $C_4$A$_3$$\bar{S}$ clinkers fired at 1,15$0^{\circ}C$ were analyzed by SEM and XRD. Also were added in cement paste and mortar and characterized as setting time, flow values and compressive strength. $C_4$A$_3$$\bar{S}$ could be found in the X-ray diffraction pattern. The setting time of cement pastes added clinkers fired at 1,15$0^{\circ}C$ was shorter than that of ordinary portland cement. Also the compressive strengths of the cement mortar added clinkers was higher than those of ordinary portland cement.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.191-192
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• 2023

This study, evaluated the effect of changes in the chemical composition of cement on the hydration reaction for carbon neutrality. For this purpose, changes in the chemical bound water and heat of hydration between current cement and past cement were compared. As a result, it was found that both the chemically bound water and heat of hydration of currently used cement decreased.

• Proceedings of the Korean Ceranic Society Conference
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• 2004.04b
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• pp.52.2-52.2
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• 2004

• Magazine of RCR
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• v.16 no.3
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• pp.34-38
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• 2021

• KSCE Journal of Civil and Environmental Engineering Research
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• v.8 no.1
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• pp.103-112
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• 1988

The reasons why the hardened cement paste substituted the domestic fly ash are better in resisting against sulfate or calcium chloride attack the one used portland cement are as follows. First, because the fly ash could restrict the gypsum creation in resisting against sulfate attack, the $C_3A$ hydrates were not inversed to ettringite. Second, in the case of the, hardened cement paste immersed in calcium chloride solution, the fly ash was effective in resisting the deteorioration resulting from microcrack in surface and inner composition by the ionization of calcium chloride solution.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.649-652
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• 2008

In this paper, the applicability of hwangtoh, as an alternative of cement paste, is investigated for the solution of internal heat and shrinkage caused by the hydration of cement paste. Several small-sized specimens of hwangtoh and ordinary portland concrete(OPC) were compared as to compressive strength, heat of hydration, and shrinkage strain. Moreover, the applicability of mass structure was reviewed through the test of large-size specimens. The 28-day compressive strength of hwangtoh concrete(HBC), ranged 18 to 33 Mpa, can reach that of ordinary portland concrete. Not only the maximin internal temperature of HBC was read about 1/4 of OPC as it is cured, but also its drying shrinkage decreased as lower as 50% of OPC starting from 60 days. Therefore, hwangtoh binder is more favorable than cement one in the view of hydration heat and shrinkage under the construction of mass structures.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.151-152
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• 2023

This study investigates the effect of nano-silica and nano-calcite on the hydration properties and mechanical performance of limestone calcined clay cement (LC³) paste. The pastes were synthesized by replacing limestone with nano-silica and nano-calcite in order to enhance the mechanical properties in both early and late stages of hydration. The nano-calcite enhanced the strength of LC³ pastes at 1 day of hydration, however, the strength decreased compared to the ordinary LC³ pastes afterwards due to excessive amount of carboaluminate produced in the pastes. On the other hand, nano-silica improved the mechanical properties of LC³ pastes at all ages of hydration. This is mainly due to the nucleation effect and pozzolanic reaction of nano-silica, affecting the early age and late ages of hydration, respectively. The nucleation effect of both nanomaterials were confirmed by the analysis of hydration heat, supporting the enhanced early age strength of nanomaterial incorporated LC³ pastes. Furthermore, the dense matrix was shown in the pore size distribution, and the increased C-S-H due to the pozzolanic reaction evidence the improved compressive and splitting tensile strength of nano-silica incorporated LC³ pastes.

• Journal of the Korean Ceramic Society
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• v.45 no.11
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• pp.744-749
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• 2008

The properties of the polymer-modified mortars are influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases. Also, this quality of polymer modified cement strongly depend on weather condition and polymer cement ratio. To overcome this problem, polymer-modified cement were prepared by varying polymer/cement mass ratio (P/C) with $0{\sim}20%$ and constant water/cement mass ratio of 0.5. The effect of polymer on the hydration of this polymer cement is studied on different polymer cement ratio. The results showed that the polymer cement paste have increased the viscosity in addition the amount of polymer dosage and the polymers is completed resulting in a reduced degree of hydration caused by different ion elution amount. Also we know that the reactants is calcium acetate as a results of chemical reaction between acetate group in EVA which is hydrolysis in water and $Ca^{2+}$ ion during hydration of cement.