• 제목/요약/키워드: Cement matrix

검색결과 317건 처리시간 0.023초

Effects of Fiber Volume Fraction and Water/Cement Ratio on Toughness Development of Steel Fiber Reinforced Concrete

  • Lee, Chang Joon;Lange, David A.;Lee, Jae Yong;Shin, Sung Woo
    • 한국건축시공학회지
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    • 제13권1호
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    • pp.20-28
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    • 2013
  • Flexure toughness of Steel Fiber Reinforced Concrete (SFRC) shows a time-dependent characteristic due to the hydration process of the cement matrix in the SFRC system. The effect of two important factors, water/cement (w/c) ratio and fiber volume fraction, on the flexure toughness development of SFRC were investigated. Three different SFRC mixtures with hooked-end steel fibers were tested using a four-point bending testing configuration. Each mixture was tested at five different ages. The results showed that the post-peak toughness of SFRC developed at an earlier age than the first-crack toughness.

변형속도에 따른 폴라아미드 섬유 및 후크형 강섬유 보강 시멘트 복합체의 인장특성 (Tensile Properties of Polyamide Fiber and Hooked Steel Fiber Reinforced Cementitious Composites by Strain Rate)

  • 이상규;김규용;황의철;손민재;백재욱;남정수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 추계 학술논문 발표대회
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    • pp.73-74
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    • 2018
  • In this study, it evaluate the tensile properties of polyamide fiber reinforced cementitious composite and hooked steel fiber reinforced cementitious Composites by strain rate. Polyamide fiber reinforced cement composites (PAFRCC) and Hooked Steel Fiber Reinforced Cement Composite(HSFRCC) were fabricated. Each specimen was reinforced with 1.0 and 2.0vol% fiber. The length of the reinforced fiber was 30 mm for both fibers, and the tensile test specimen was made in dumbbell shape. As a result, the tensile strength of fiber in polyamide fiber and the mechanical bonding between fiber and matrix in hooked steel fiber are considered to be the main factors affecting tensile behavior of fiber reinforced cement composite.

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AE기법에 의한 하이브리드 섬유보강 시멘트복합체의 압축파괴특성 평가 (Assessing Compressive Failure Characteristics of Hybrid Fiber Reinforced Cementitious Composites by Acoustic Emission)

  • 김선우;지상규;전수만;윤현도
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.229-232
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    • 2006
  • The HPFRCCs show that the multiple crack propagation, high tensile strength and ductility due to the interfacial bonding of the fibers to the cement matrix. Moreover, performance of cement composites varies according to type and weight contents of reinforcing fiber. and HPFRCCs with hybrid fiber have better performance than HPFRCCs with single fiber in damage tolerance. Total four cylindrical specimens were tested, and the main variables were the type and weight contents of fiber, which was polyvinylalchol (PVA), polyethylene (PE). In order to clarify effect of hybrid types on the characteristics of fracture and damage process in cement composites, AE method was performed to detect micro-cracking in HPFRCCs under cyclic compression. Loading conditions of the uniaxial compression test were monotonic and cyclic loading. And from AE parameter value, it is found that the second and third compressive load cycles resulted in successive decrease of the amplitude as compared with the first compressive load cvcle.

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고강도 비닐론 섬유로 보강된 빛 투과 콘크리트의 투명 봉 간격 변화에 따른 물리적 특성 연구 (A Study on the Physical Properties of Cement Composites with High-strength Vinylon Fibers)

  • 한윤정;김수연;김병일
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.100-101
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    • 2017
  • LEFC(Light Emotion Friendly Conceret) was developed in Korea with demands of esthentic requirements in line with the recent developmental trend of concrete technology. The LEFC is made by inserting transparent transparent rods, and this forms a heterogeneous structure in the concrete matrix causing the LEFC substrate to crack due low adhesion between the rod and the cement. In this study, as a way to strengthen the bonding to the rod inserted in the LEFC, high strength vinylon fibers of varying mixture ratios were applied and physical properties were tested accordingly. To study the effect of different spacing of the bars on the LEFC, physical property testing was conducted on respective specimens with two different diameters (5mm, 10mm) inserted in different intervals of spacing (10mm, 15mm, and 20mm).

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Precipitation of Calcium Phosphate at pH 5.0 for the β Tri-calcium Phosphate Cement

  • Chang, Myung Chul
    • 한국세라믹학회지
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    • 제50권4호
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    • pp.275-279
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    • 2013
  • The purpose of this study was to prepare calcium phosphate cement [CPC] for use in artificial bone. Nano-crystalline calcium phosphate [CaP] was precipitated at $37^{\circ}C$ using highly active $Ca(OH)_2$ in DI water and an aqueous solution of $H_3PO_4$. From the XRD measurements, the nano-CaP powder was close to apatitic TCP phase and the powders fired at $800^{\circ}C$ showed a critical ${\beta}$-TCP phase. A mixture of one mole $CaCO_3$ and two moles di-calcium phosphate was calcined at $1100^{\circ}C$ to make a reference ${\beta}$-TCP material. The nano-CaP powders were added to the normal ${\beta}$-TCP matrix and fired at $900^{\circ}C$ to make a ${\beta}$-TCP block. The sintered block showed improved mechanical strength, which was caused by the solid state interaction between nano-CaP and normal ${\beta}$-TCP.

황산염침식 방지를 위한 포틀랜드시멘트의 선정-Part 1 황산나트륨 침식 (Selection of Portland Cement for Prevention of Sulfate Attack-Part 1 Sodium Sulfate Attack)

  • 김종필
    • 콘크리트학회논문집
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    • 제21권4호
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    • pp.441-447
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    • 2009
  • 황산염침식을 방지하기 위하여 포틀랜드시멘트 중의 황산염침식 저항성이 우수한 시멘트를 선정하기 위한 연구의 일환으로 황산나트륨 용액에 360일간 침지한 후 모르타르의 역학적 특성 및 기기분석을 통하여 침식 특성을 평 가한 결과, 외관조사, 강도감소 및 길이변화에 따른 성능저하 순서는 보통 포틀랜드시멘트 >내황산염 포틀랜드시멘트 > 저열 포틀랜드시멘트 순으로 나타났다. 포틀랜드시멘트의 주요 반응생성물은 Calcite 피크 이외에도 황산염과의 반응으 로 인한 Gypsum, 에트린자이트 및 Thaumasite로 확인되었다. 포틀랜드시멘트의 경우 시멘트의 조성광물 비에 따라 성 능저하 형태가 상이하게 나타났다. 특히, C3A량과 칼슘실리케이트비가 가장 적은 저열 포틀랜드시멘트가 황산염침식 저 항성에 매우 우수한 것으로 확인되었다.

Development of reference materials for cement paste

  • Lee, Dong Kyu;Choi, Myoung Sung
    • Advances in concrete construction
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    • 제9권6호
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    • pp.547-556
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    • 2020
  • This study aimed to develop reference materials (RMs) that are chemically stable and can simulate the flow characteristics of cement paste. To this end, the candidate components of RMs were selected considering the currently required properties of RMs. Limestone, slag, silica, and kaolin were selected as substitutes for cement, while glycerol and corn syrup were selected as matrix fluids. Moreover, distilled water was used for mixing. To select the combinations of materials that meet all the required properties of RMs, flow characteristics were first analyzed. The results revealed that silica and kaolin exhibited bilateral nonlinearity. When an analysis was conducted over time, slag exhibited chemical reactions, including strength development. Moreover, fungi were observed in all mixtures with corn syrup. On the other hand, the combination of limestone, glycerol, and water exhibited a performance that met all the required properties of RMs. Thus, limestone, glycerol, and water were selected as the components of the RMs. When the influence of each component of the RMs on flow characteristics was analyzed, it was found that limestone affects the yield value, while the ratio of water and glycerol affects the plastic viscosity. Based on this, it was possible to select the mixing ratios for the RMs that can simulate the flow characteristics of cement paste under each mixing ratio. This relationship was established as an equation, which was verified under various mixing ratios. Finally, when the flow characteristics were analyzed under various temperature conditions, cement paste and the RMs exhibited similar tendencies in terms of flow characteristics. This indicated that the combinations of the selected materials could be used as RMs that can simulate the flow characteristics of cement paste with constant quality under various mixing ratio conditions and construction environment conditions.

EVA, EVCL 분말수지와 플라이애시를 혼입한 시멘트 모르타르의 고온특성 (High Temperature Properties of Cement Mortar Using EVA, EVCL Redispersible Polymer Powder and Fly Ash)

  • 송훈;신현욱
    • 한국건설순환자원학회논문집
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    • 제6권4호
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    • pp.365-372
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    • 2018
  • 건축물에서의 3D 프린팅은 구조재 및 비구조재로의 적용으로 구분되며, 비구조재는 내 외장 패널이나 조형물로의 적용 등이 주를 이룬다. 연속적으로 적층하여 제조하는 3D 프린팅 방식은 시멘트 모르타르의 경화속도나 특성을 개질하며 이를 위한 재료의 혼입과 경화속도나 시공성, 접착성의 개선을 위한 시멘트 혼화용 폴리머의 사용이 필수적이다. 본 연구는 적층방식 3D 프린팅 적용을 위해 시멘트, 플라이애시, EVA 및 EVCL 분말수지의 혼입률을 달리하여 고온에서의 특성을 검토하였고 혼입에 따른 유효성 여부를 확인하였다. 실험결과, EVA 및 EVCL 분말수지에 혼입에 따라 시멘트 모르타르는 연행된 공기에 의해 특성이 개질되었고 EVA보다는 EVCL을 혼입한 시험체가 고온에서 유리하였다.

THE MICROSTRUCTURE OF Pb-DOPED SOLIDIFIED WASTE FORMS USING PORTLAND CEMENT AND CALCITE

  • Yoo, Hee-Chan;Lee, Dong-Jin
    • Environmental Engineering Research
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    • 제11권1호
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    • pp.54-61
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    • 2006
  • An electron probe microanalysis (EPMA) investigation can provide quantitative and qualitative insight into the nature of the surface and bulk chemistry on solidified waste forms(SWF). The proportion of Pb in grain areas is below 0.3 wt. %, and the proportion near the border of the grain slightly increases to 0.98 wt. % but in the inter-particle areas farther from the grain, the concentration of Pb markedly increases. It is apparent that very little Pb diffuses into the tricalcium silicate($C_3S$) particles and most of the Pb exists as precipitates of sulfate, hydroxide, and carbonate in the cavity areas between $C_3S$ grains. Calcite additions on Pb-doped SWF are also observed to induce deeper incorporation of lead into the cement grains with EPMA line-analysis of cross-sections of cement grains. The line-analysis reveals the presence of $0.2{\sim}5$ weight % Pb over $5\;{\mu}m$ from cement grain boundaries. In the inter-particle areas, the ratio of Ca, Si, Al and S to Pb is relatively similar even at some distance from the grain border and the Pb (wt. %) ratio is reasonably constant throughout the whole inter-particles area. It is apparent that the enhanced development of C-S-H on addition of calcite can increasingly absorbs lead species within the silica matrix.

Percolation threshold and piezoresistive response of multi-wall carbon nanotube/cement composites

  • Nam, I.W.;Souri, H.;Lee, H.K.
    • Smart Structures and Systems
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    • 제18권2호
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    • pp.217-231
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    • 2016
  • The present work aims to develop piezoresistive sensors of excellent piezoresistive response attributable to change in nanoscale structures of multi-wall carbon nanotube (MWNT) embedded in cement. MWNT was distributed in a cement matrix by means of polymer wrapping method in tandem with the ultrasonication process. DC conductivity of the prepared samples exhibited the electrical percolation behavior and therefore the dispersion method adopted in this study was deemed effective. The integrity of piezoresistive response of the sensors was assessed in terms of stability, the maximum electrical resistance change rate, and sensitivity. A composite sensor with MWNT 0.2 wt.% showed the lowest stability and sensitivity, while the maximum electrical resistance change rate exhibited by this sample was the highest (96 %) among others and even higher than those found in the literature. This observation was presumably attributed by the percolation threshold and the tunneling effect. As a result of the MWNT content (0.2 wt.%) of the sensor being near the percolation threshold (0.25 wt.%), MWNTs were close to each other to trigger tunneling in response of external loading. The sensor with MWNT 0.2 wt.% was able to maintain the repeatable sensing capability while sustaining a vehicular loading on road, demonstrating the feasibility in traffic flow sensing application.