• International Journal of Concrete Structures and Materials
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• v.9 no.3
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• pp.381-390
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• 2015

Investigating the microstructure of hardened cement mixtures with the aid of advanced technology will help the concrete industry to develop appropriate binders for durable building materials. In this paper, morphological, mineralogical and thermogravimetric analyses of autoclave-cured mixtures incorporating ground dune sand and ground granulated blast furnace slag as partial cementing materials were investigated. The microstructure analyses of hydrated products were conducted using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), differential thermal analysis (DTA), thermo-graphic analysis (TGA) and X-ray diffraction (XRD). The SEM and EDX results demonstrated the formation of thin plate-like calcium silicate hydrate plates and a compacted microstructure. The DTA and TGA analyses revealed that the calcium hydroxide generated from the hydration binder materials was consumed during the secondary pozzolanic reaction. Residual crystalline silica was observed from the XRD analysis of all of the blended mixtures, indicating the presence of excess silica. A good correlation was observed between the compressive strength of the blended mixtures and the CaO/$SiO_2$ ratio of the binder materials.

• Advances in materials Research
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• v.7 no.1
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• pp.45-72
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• 2018

In the present study, a special attention has been paid to the effects regarding the use of different superplasticizers in different dosages. To do so, 36 mixes of normal and self-compacting concrete with two water/binder ratios of 0.35 and 0.45, four different types of superplasticizer including melamine-formaldehyde, naphthalene-formaldehyde, carboxylic-ether and poly-carboxylate, four different superplasticizer/cement ratios of 0.4%, 0.8%, 1.2% and 1.6% and two silica fume/cement ratios of 0% and 10% have been cast. Moreover, the initial and final setting time of the pastes have been tested. For self-compacting mixes, flow time, slump flow, V-funnel, J-ring and L-box tests have been carried out as well as testing the compressive strength and rupture modulus. For normal concrete mixes,slump test has been conducted to assess the workability of the mix and then for each mix, the compressive strength and rupture modulus have been determined. The results indicate that in addition to the important role of superplasticizer type and dosage on fresh state properties of concrete, these parameters as well as the use of silica fume could affect the hardened state properties of the mixes. For instance, the mixes whose superplasticizer were poly-carboxylic-ether based showed better compressive and tensile strength than other mixes. Besides, the air contents showed robust dependency to the type of the superplasticizer. However, the use of silica fume decreased the air contents of the mixes.

• International Journal of Highway Engineering
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• v.16 no.6
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• pp.79-86
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• 2014

PURPOSES : In this study, wasted vinyl aggregate, which possesses better thermal properties than natural aggregate, was used in cement concrete mixture to develop more economical concrete with thermal insulation and freeze prevention effects. METHODS : Slump and air content of the fresh concrete, which substituted its 0%, 5%, and 10% of coarse aggregate with wasted vinyl aggregate, were measured. Compressive strength, Poisson's ratio, elastic modulus, and splitting tensile strength of hardened concrete were measured by laboratory tests. Thermal properties of concrete such as coefficient of thermal expansion, thermal conductivity, and specific heat were also measured according to replacement ratio of wasted vinyl aggregate. Finally, the thermal insulation and freeze prevention effectiveness of the concrete mixed with wasted vinyl aggregate was confirmed through finite element analysis of road pavement crossing above concrete box culvert made from wasted vinyl aggregate. RESULTS : Even though the physical properties of wasted-vinyl-aggregate concrete such as compressive strength, Poisson°Øs ratio, elastic modulus, and splitting tensile strength were inferior to those of ordinary concrete, they met requirements for structural concrete. The thermal properties of concrete were improved by wasted vinyl aggregate because it decreased thermal conductivity and increased specific heat of the concrete. According to the result of finite element analysis, temperature variation in pavement subgrade was mitigated by box culvert made from wasted-vinyl-aggregate concrete. CONCLUSIONS : Through the laboratory test and finite element analysis of this study, it was concluded that the concrete structures made from wasted vinyl aggregate showed thermal insulation and freeze prevention effects.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2006.05a
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• pp.35-38
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• 2006

This study investigated fundamental properties of lightweight foamed concrete using cement kiln dust (CKD) and both fly ash(FA) and stability agent. Test results showed that concrete incorporating more amounts of admixture decreased slump flow and it caused increase of superplasiticizer in order to secure the fluidity performance. In addition concrete adding stability agent showed stable flow state, resisting segregation of materials and decreasing bleeding capacity. Sinking depth of concrete incorporating 20% of CKD and adding 0.002% of stability agent was indicated at 0mm. For the properties of hardened concrete. compressive strength of concrete incorporating CKD declined due to a lower appearance density, compared with other specimens. The difference of that was not very significant and the value of ail specimen was higher than KS range. Moreover strength of concrete incorporating CKD was even higher at curing temperature $5^{\circ}C$. Tensile strength ratio of concrete incorporating CKD was indicated between 0.50 to 0.59, which is higher value than control concrete. Heat conductivity of concrete incorporating FA was under the KS range while concrete incorporating 20% of CKD was satisfied in KS. Concrete adding stability agent improved insulation performance due to the lower heat conductivity. In conclusion, it is possible that concrete incorporating 20% of CKD and adding 0.002% of stability agent can secure high quality of lightweight foamed concrete.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2003.10a
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• pp.134-138
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• 2003

The purpose of this paper is to recycle the fly ash to the valuable resources and settle environment problems which was caused by the fly ash produced from the thermal power plant. Making the fly ash-cement matrix reused fly ash in large quantities, we looked into minutely the physical properties - the elastic modulus, the compressive strength - to increase the usefulness as the building materials for the structure widely. In this paper, the variables are the water-binder(39, 42, 45%), the fine aggregate ratio(37, 41, 45%). Because the fracture energy is influenced by the strength, it is showed to decrease with the increase of W/B and S/a. Besides, we will be able to know that basic properties of the fly ash-cement matrix are similar to that of concrete. But, it is needed to carry out durability experiment on the drying shrinkage, creep, freezing and thawing test to use structural materials.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.1
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• pp.27-32
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• 2014

This study analyzed the fundamental characteristics of concrete according to a ternary system mixing in order to reduce hydration heat of mass concrete and to improve early age strength. The results are as follows. The fluidity of unconsolidated concrete satisfied the target scope regardless of the binder conditions. When the replacement ratio between FA and BS increased, the slump of low heat-A mix and low heat-B mix increased, and air content was not affected by the change of binders. As for setting time, low heat cement mix had the fastest regardless of W/B, and high early strength low heat mix achieved 6 hours' reduction compared with low heat-B mix at initial set, and 12 hours' reduction at the final set respectively. As for the simple hydration heat, the low mix peak temperature was the highest and low heat-B mix had the lowest temperature. And high early strength low heat mix was similar with that of low heat-B. The compressive strength of hardened concrete had similar strength scope in all mixes except for low heat-B mix at early ages, and had unexceptionally similar one without huge differences at long-term ages.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.441-444
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• 2008

Ultra high performance concrete (UHPC) in this study is composed of sand, cement, silica fume, siliceous powder, superplasticizer and steel fiber. UHPC is composed of fine mineral particles below 0.5mm in diameter. In general, siliceous powder improves the mechanical properties of concrete by physical and chemical effect. Physical effect is related with filling interior voids which weaken the mechanical properties and chemical effect with reaction of $SiO_2$ with cement hydrates in a condition of high temperature and pressure. We evaluated the effect of siliceous powder's particle size on the mechanical properties of ultra high performance concrete in air pressure and $90^{\circ}C$ steam curing condition. siliceous powder's particle size in this study is in the range of $2{\mu}m$ to $26{\mu}m$. Fluidity in a fresh concrete, compressive strength, ultimate strain, elastic modulus and flexural strength in a hardened concrete was evaluated. We could find out that the smaller siliceous powder's particle size is, the better the fluidity and strength properties.

• Journal of the Korea Institute of Building Construction
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• v.2 no.4
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• pp.89-98
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• 2002

Self-leveling material(SLM) is one of the floor finishing materials which make flat surface like as water level by itself in a short time. So it is possible to increase construction speed and enhance economical efficiency In this study, author intended to develop SLM for the industrial warehouse and factory loading heavy weight machinery and vehicles. The demanded properties for this type of SLM are above 200mm of flow value and above 300kgf/$cm^2$ of 28-days compressive strength. To possess demended strength and fluidity, SLM have to be composed of many types of binders and chemical additives. So it is difficult to decide suitable mixing proportion of composition materials. In this study, author investigated the weight percentage effect of main composition materials for high-strength self-leveling material, by experimental design such as tables of orthogonal arrays and simplex design, and by statistical analysis such as analysis of variance and analysis of response surface. Variables of experiments were ordinary Portland cement(OPC), alumina cement(AC), anhydrous gypsum(AG), lime stone(LS) and sand, and properties of tests were fluidity of fresh state and strength of hardened state. Results of this study are showed that suitable mix proportions of binders for the high strength self-leveling materials are two groups. One is 78~85.5% OPC, 7.5~9.5% AC, 9~12.5% AG and the other is 72.5~78% OPC, 9~12.5% AC, 13~15% AG.

• KIEAE Journal
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• v.10 no.5
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• pp.115-121
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• 2010

Lime was the solidifier mostly used at the fields of construction and civil works in the past. however, the development of Portland cement remarkably reduced the use of it. Recently as the concernment on circumstances gets higher, lime wined attention again as an eco-friendly material and was used at earth-using construction. This study examined the physical and chemical capacity of lime complexes with lime capacity improved, and performed fundamental study on the way to concretize by mixing it with earth. As a result, lime complex pressure strength was lower than cement pressure strength but it showed the possibility that its strength was improved by W/B control. The measurement of XRD after paste formation confirmed a compound generated by the reaction of Ca2+ion and Si, Al, and Fe from pozzolan reaction. A earth wall experiment by using lime complexes and earth showed that the higher, WB or the lower the quantity of unit combined materials, the lower the pressure strength was. The maximum pressure strength was maximum 11MPa when the quantity of unit combined materials was 450. It is because the composed earth particles had a high content of micro powder less than silt, so a lot of combination are demanded to secure fluidity. As a result of peptization experiment, after hardening, the material was not dissolved, which informed of the possibility of use as an outer subsidiary material. If the material is hardened by mold formation method, natural hardening crack appears. Cast expresses smart surface quality and enables to design for multiple purpose. The result shows the possibility of construction of low-story structures by using earth wall made of lime complexes and earth.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.10
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• pp.271-279
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• 2016

This study examines the properties of high-fluidity concrete after adding copper slag as a mineral admixture. For this purpose, the replacement ratio of cement to copper slag was varied to 0, 10, 20, 30, 40, and 50%. A slump flow test, reach time slump flow of 500 mm, and a U-Box and O-lot test were conducted on the fresh concrete. The compressive strength of the hardened concrete was determined at 3, 7, 14 and 28 days. According to the test results, the workability, compaction, and compressive strength of the high-fluidity concrete increased when replacing 30% of the cement with copper slag. These parameters decreased for all material ages with more than 30% copper slag, which was the optimal mixture ratio.