• 한국응용과학기술학회지
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• 제26권4호
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• pp.428-433
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• 2009

Cellulose triacetate (CTA) was prepared from cotton linter and pulps which contain various contents of $\alpha$-cellulose. CTA which contains 2.8 of degree of substitution (DS) and 222 of degree of polymerization (DP) was obtained from V-81 pulp under the heterogeneous system. The DS was measured by the titration method, and the DP was obtained by measurement of viscosity. FT-IR spectometer (FT-IR 6300, JASCO) was used to analyze the chemical structure of raw materials and cellulose triacetate, and X-ray diffractometer (X-pert MPD PW3040, Philips) was used to confirm the crystal structure and to calculate the relative crystallinity index (RCI). As $\alpha$-cellulose content in pulp increased, the acetylation yield increased. Besides with a kind of pulp, it contains insoluble residue which was mainly formed due to the formation of glucomannan triacetate and xylan diacetate during the esterification.

• 멤브레인
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• 제17권4호
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• pp.277-286
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• 2007

전 세계적으로 물 부족 문제를 해결하기 위한 한 가지 대안으로서 해수 담수화 기술이 높은 관심을 받고 있다. 본 연구에서는 해수 담수화를 위한 고효율 저에너지 소모 공정으로 떠오르고 있는 역삼투막의 제조를 위해 cellulose triacetate(CTA)의 적용 가능성을 살피고자 하였다. 염소에 대한 안정성과 유기물에 대한 저항성을 가지는 CTA를 사용하여 막을 제조할 시 아세틸화도, 용매, 첨가제와 같은 제막 조성의 변화가 막의 성능에 미치는 것으로 나타난다. 높은 아세틸화도와 CTA의 용매인 다이옥산과 아세톤의 비에서 다이옥산의 함량이 높을수록 높은 유량과 염 제거율을 가지는 막의 제조가 가능하다. 첨가제로는 acetic acid와 maleic acid가 선호된다. 실제 해수 담수화 플랜트에 상용화된 CTA 막($HOLLOSEP^{(R)}$)을 적용해 본 결과 다른 화학적 처리 없이 계속적인 염소 처리만으로 장기간 안정된 유량과 수질을 나타낸다.

• Fibers and Polymers
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• 제3권1호
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• pp.43-48
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• 2002

A series of monoazo disperse dyes based on 2-amino-4-phenylthiazole was prepared using various N,N-dialkvlaniline derivatives as the coupling component. The dyes were characterized by IR spectral studies, visible absorption spectroscopy and elemental analysis. The dyeing performance of these dyes was assessed on cellulose triacetate and nylon fibers. These dyes were found to give a wide range of colour shades varying from bright red to royal blue with very good depth, brightness and levelness on fibers. The dyed fibers showed good to very good light fastness and very good to excellent fastness to washing, perspiration, rubbing and sublimation. The dyebath exhaustion and fixation on the fibers were found to be very good.

• Bulletin of the Korean Chemical Society
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• 제31권8호
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• pp.2207-2210
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• 2010

This paper describes the preparation and study of thermally stimulated discharge conductivity (TSDC) study of cellulose triacetate (CTA) - multiwalled carbon nanotubes (MWNTs) film thermoelectrets. TSDC has been carried out in the temperature range 308 - 503 K and at four different polarizing fields. The conductivity of the polymer blends increased with increase in temperature showing a semi-conducting behavior. The apparent activation energy also showed a pronounced effect with the increase in the content of MWNTs.

• Bulletin of the Korean Chemical Society
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• 제34권5호
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• pp.1391-1396
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• 2013

The photocontrolled reduction of silver nitrate to silver (Ag) nanoparticles on honeycomb-patterned poly(N-vinylcarbazole) (PVK)-cellulose triacetate (CTA) composite thin films was studied. The composites were prepared via the oxidative polymerization of N-vinylcarbazole with ferric chloride using different CTA concentrations. A honeycomb-patterned film was fabricated by casting the composite solution under humid conditions. Ag particles with a homogeneous distribution were produced by the composite film in a moderate CTA concentration, whereas aggregated Ag was obtained from the pure PVK film.

• 대한화학회지
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• 제4권1호
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• pp.44-50
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• 1957

Fibrous cellulose triacetate prepared from purified cotton under various temperatures was dissolved in the solution of 70%, monochloroacetic acid and it was fractionated using water as a precipitant. Eight fractions were obtained through the stepwise precipitation. Degree of polymerization and molecular weight of each fraction were measured viscometrically. Integral and differential molecular weight distribution curve were drawn for each sample prepared under various temperatures and were carefully observed. On this experimental study, following conclusions were obtained: Fractional precipitation can be carried out for fibrous cellulose triacetate in the solution of 70% monochloroacetic acid using water as a precipitant. The differences on the shapes of molecular weight distribution curve were occured on account of the various acetylation temperatures. At the relatively higher acetylation temperatures, the cellulose was randomly degraded and the portion of low degree of polymerization was increased. Commercial acetate, therefore, may not be prepared at above 40$^{\circ}C$ according to the molecular weight distribution curve regardless of higher viscosity and average degree of polymerization. It was concluded that the optimum acetylation temperature for commercial acetate was approximately 30$^{\circ}C$.

• 한국염색가공학회지
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• 제4권1호
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• pp.26-29
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• 1992

Ternary solutions that cellulose triacetate (CTA) and polyethylene terephthate (PET) were mixed in a solvent trifiuoroacetic acid (TFA)/methylene chloride (MC) (6/4 : v/v) showed phase separation and mesophase formation. The ternary systems which were mesomorphic were spun into a methanol both and relatively strong cellulosic fillaments were successfully produced. Analysis showed that CTA/PET fibers have fibrillar structure and high orientation parallel to the fiber axis. These fibers proved to be molecular composite and have relatively high strength and modulus as spun.

• 한국염색가공학회지
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• 제3권4호
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• pp.17-21
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• 1991

A rigid polymer, cellulose triacetate (CTA) dissolved in a combination of trifluoroacetic acid (TFA) and methylene chloride (MC) solution are liguid crystalline above a certain concentration. A flexible polymer, polyethylene terephthalate (PET) also dissolves in TFA/MC, but does not form liguid crystal phase. Ternary solutions, CTA/PET/TFA-MC which CTA and PET were mixed in a same solvent TFA/MC (6/4 : v/v) showed phase separation and mesophase formation.

• 한국염색가공학회지
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• 제6권1호
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• pp.44-48
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• 1994

Cellulose triacetate(CTA) liquid crystal solutions obtained via dissolution of CTA in solvent mixture of triflucroacetic acid and methylene chloride were spun and saponified in various chemicals. Among chemicals, methanol/sodium hydroxide mixture endowed highest tenacity as well as modulus to regenerated cellulosic fiber and the fiber thereof showed Cell I or Cell IV morphology, or mixed morphology of Cell I and IV.

• 한국염색가공학회지
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• 제16권5호
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• pp.28-34
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• 2004

The polarizing film application exploits the unique physicochemical properties between PVA(Poly vinyl alcohol) film and CTA(Cellulose triacetate) film. However, hardly any research was aimed at improving the adhesion characteristics of the CTA film by radio frequency(RF) plasma treatment at argon(Ar) gaseous state. In this report, we deal with surface treatment technology for protective CTA film developed specifically for high adhesion applications. After Ar plasma, surface of the films is analyzed by atomic force microscopy(AFM), roughness parameter and peel strength. Furthermore, the wetting properties of the CTA film were studied by contact angle analysis. Results obtained for CTA films treated with a glow discharge showed that this technique is sensitive to newly created physical functions. The roughness and peel strength value increased with an increase in treatment time for initial treatment, but showed decreasing trend for continuous treatment time. The result of contact angle measurement refer that the hydrophilicity of surface was increased. AFM studies indicated that no considerable change of surface morphology occurred up to 3 minutes of treatment time, but a considerable uneven of surface structure resulted from treating time after 5 minutes.