• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2007년도 추계학술대회논문집
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• pp.73-76
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• 2007

Electro-Active paper (EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. It is made by cellulose that is abundant material in nature. EAPap is fascinating with its biodegradability, lightweight, large displacement, high mechanical strength and low actuation voltage. Actuating mechanism of EAPap is known to be the combined effects of ion migration and piezoelectricity. However, the electromechanical actuation mechanisms are not yet to be established. This paper presents the modeling of the actuation behavior of water infused cellulose samples and their composite dielectric constants calculated by Maxwell-Wagner theory. Electro-mechanical forces were calculated using Maxwell stress tensor method. Bending deflection was evaluated from simple beam model and compared with experimental observation, which result good correlation with each other.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2009년도 춘계학술대회 논문집
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• pp.462-465
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• 2009

Cellulose based electro-active paper (EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. Beside of the natural abundance, cellulose EAPap is fascinating with its biodegradability, lightweight, high mechanical strength and low actuation voltage. An actuating mechanism of EAPap is revealed to be the combination of ion migration effect and piezoelectricity. EAPap can generate the electrical current and voltage when the mechanical stress applied due to its electro-mechanical characteristics. In this paper, we investigated the feasibility of EAPap as a mechanical strain sensor.

• 한국소음진동공학회논문집
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• 제17권12호
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• pp.1179-1183
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• 2007

Electro-Active paper(EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. It is made by cellulose that is abundant material in nature. EAPap is fascinating with its biodegradability, lightweight, large displacement, high mechanical strength and low actuation voltage. Actuating mechanism of EAPap is known to be the combined effects of ion migration and piezoelectricity. However, the electromechanical actuation mechanisms are not yet to be established. This paper presents the modeling of the actuation behavior of water infused cellulose samples and their composite dielectric constants calculated by Maxwell-Wagner theory. Electro-mechanical forces were calculated using Maxwell stress tensor method. Bending deflection was evaluated from simple beam model and compared with experimental observation, and which result in good correlation with each other.

• 펄프종이기술
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• 제45권3호
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• pp.59-68
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• 2013

The cotton contains various impurities such as protein, wax, pectins, coloring matter, even though cotton has been a major source of pure cellulose. The purification processes have been commonly applied to obtain the pure cellulose. However the excessive purification treatments could lead to the damage in the cellulose structure which could result in the degradation of cellulose and the limited application of cotton cellulose. In this study, the changes in cellulose structural properties such as crystallinity and DP(degree of polymerization) by the various conditions of the purification processes were investigated. The less toxic agents such as hydrogen peroxide and sodium silicate were applied for the purification treatment in this study. The increase in the process times, the temperature and the applied amount of chemical agents resulted in the more purified cellulose. The DP of cotton cellulose was increased at the first weak conditions by the reduction of small molecules such as pectin, wax, and so on. Especially the 2 % addition amount of $H_2O_2$ with $Na_2SiO_3$ resulted in the higher value in the DP and the brightness compared to the 1.5 % addition amount of $H_2O_2$. However, the 4 % addition amount of $H_2O_2$ with $Na_2SiO_3$ showed the decreased value because of excessive treatment. In case of the changes in the crystallinity (Gjk), the highest value of the crystallinity was obtained by the 2% addition amount of $H_2O_2$ on the cotton cellulose, which showed similar with the change in the DP.

• 대한기계학회논문집B
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• 제36권5호
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• pp.539-543
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• 2012

셀룰로오스 EAPap 작동기는 생체 모방형 작동기의 하나로 생체적합하고 가볍고 비교적 낮은 전압에서도 큰 변위를 발생시킨다는 장점을 가지고 있다. 셀룰로오스를 재생하면서 셀룰로오스 파이버를 배열함으로써 압전 종이를 만들었다. 한편 셀룰로오스에 탄소나노튜브, 산화금속 나노분말, 전도성 고분자, 이온성 유체등을 물리적, 화학적으로 결합시켜 다양한 하이브리드 나노복합재를 만들었다. 본 논문에서는 셀룰로오스 EAPap 의 제조공정 및 이를 응용한 바이오센서, 화학센서, 유연트랜지스터, 그리고 작동기의 응용 디바이스에 대해 소개한다. 또한 셀룰로오스 EAPap 을 무선으로 구동하는 기술에 대해 소개한다. 이는 생체모방로봇, 정찰 등에 활용될 수 있다.

• 한국정밀공학회지
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• 제31권8호
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• pp.737-742
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• 2014

This paper reports a customized silver ink and its inkjet printing process on a cellulose electro-active paper (EAPap). To synthesize a silver ink, silver nanoparticle is synthesized from silver nitrate, polyvinylpyrrolidone and ethylene glycol, followed by adding a viscosifier, hydroxyethyl-cellulose solution, and a surfactant, diethylene glycol. The silver ink is used in an inkjet printer (Fujifilm Dimatix DMP-2800 series) to print silver electrodes on cellulose EAPap. After printing, the electrodes are heat treated at $200^{\circ}C$. The sintered electrodes show that the thickness of the electrodes linearly increases as the number of printing layers increases. The electrical resistivity of the printed electrodes is $23.5{\mu}{\Omega}-cm$. This customized ink can be used in inkjet printer to print complex electrode patterns on cellulose EAPap to fabricate flexible smart actuators, flexible electronics and sensors.

• 콘크리트학회논문집
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• 제12권2호
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• pp.89-98
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• 2000

The mechanical properties of specialty cellulose fiber reinforced concrete and the contribution of specialty cellulose fiber to drying shrinkage crack reduction potential of concrete and theirs evaluation are presented in this paper. The effects of differing fiber volume fraction(0.03%, 0.06%, 0.08%, 0.1%, 0.15%, 0.2%) were studied. The results of tests of the specialty cellulose fiber reinforced concrete were compared with plain and polypropylene fiber reinforced concrete. Flexural performance(flexural strength and flexural toughness) test results indicated that specialty cellulose fiber reinforcement showed an ability to increase the flexural performance of normal- and high- strength concrete(as compared to plain and polypropylene fiber reinforced concrete). Optimum specialty cellulose fiber reinforced concrete were obtianed using 0.08% fiber volume fraction. Drying shrinkage cracking test results confirmed specialty cellulose fibers are effective in reducing the drying shrinkage cracking of normal and high-strength concrete(as compared to popylene fiber reinforced concrete).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.349-354
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• 1999

Specialty cellulose fibers processed for the reinforcement of concrete offer relatively high levels of elastic modulus and bond strength. The hydrophilic surfaces of specialty cellulose fibers facilitate their dispersion and bonding in concrete. Specialty cellulose fibers have small effective diameters which are comparable to the cement particle size, and thus promote close packing and development of dense bulk and interface microstructure in the matrix. The relatively high surface area and the close spacing of specialty cellulose fibers when combined with their desirable mechanical characteristic make them quite effective in the suppression and stabilization of microcracks in the concrete matrix. The properties of fresh mixed specialty cellulose fiber reinforced concrete and the contribution of specialty cellulose fiber to the restrained shrinkage crack reduction potential of cement composites at early age and theirs evaluation are presented in this paper. Results indicated that specialty cellulose fiber reinforcement showed an ability to reduce the total area significantly (as compared to plain concrete and polypropylene fiber reinforced concrete.

• 펄프종이기술
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• 제45권2호
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• pp.56-65
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• 2013

Electron beam treatment was applied for improving dissolution of cellulose with ionic liquids. Two ionic liquids, 1-allyl-3-methylimidazolium chloride ([Amim]Cl]: AC) and 1,3-dimethylimidazolium methylphosphite ([Dmim][$(MeO)(H)PO_2$]: Me) were used for this experiment. Treatment with electron beams up to dose of 400 kGy resulted in the increase of hot water extract and alkali extract of cotton pulp and the great reduction in the molecular weight of cellulose. For the dissolution of cotton pulp with two ionic liquids, the electron beam treated samples showed faster dissolution. The dissolved cellulose with Me ionic liquid were regenerated with acetonitrile and the structure of regenerated cellulose showed distinct difference depending on the electron beam treatment. Those results provide the electron beam pre-treatment could be applied as an energy efficient and environmentally benign method to increase the dissolution of cellulose with ionic liquids.

• 펄프종이기술
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• 제29권3호
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• pp.26-33
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• 1997

The bacterial celluloses are very different in its physical, chemical and morphological structures compared to wood cellulose. These fibers have many unique properties that are potentially and commercially beneficial. This study was aimed to elucidate the production of bacterial celluloses and to improve their physical properties by chemical pretreatment. Bacterial celluloses produced by static culture had gel-like pellicle structure. The pellicle thickness was increased with the increasing time, and its layer was about 1.8cm after one-month incubation. The pellicles extruded from the cells of Acetobacter had a non-crystalline structure during initial growing stages, gradually getting crystaliyzed with the incubation time elapse, and eventually fumed to the cellulose I crystals. Young＇s modulus of bacterial cellulose sheet was increased with increasing NaOH concentration, and resulted in the highest at 5% NaOH concentration. Similar results with NaClO3 pretreatment can be observed. Too concentrated alkali solutions induced the destruction of cellulose fibrils and changed the mechanical properties of the sheets. These alkaline pretreatment have removed non-cellulosic components(NCC) from the bacterial cellulose, and enhanced inter-abrillar bonding by direct close contact among cellulosic fibrils.