• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 1999.11b
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• pp.50-55
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• 1999

Sizing development of AKD-sized paper by beta-ketoester formation has been debated until recent years because of absence of its obvious and direct spectroscopic evidence. In this study, reaction between AKD and cellulose was investigated to disclose the possibility of beta-ketoester formation between two components under no catalyzed neutral condition. In absence of water, AKD reacted with cellulose to form beta-ketoester linkage under no catalyzed neutral condition, while, in presence of water, most of AKD was hydrolyzed to a dialkyl ketone or beta-ketoacid. Therefore, the main mechanism of AKD sizing would not be the formation of beta-ketoester between AKD and cellulose in the papermaking process. It could be suggested that the sizing development of AKD-sized paper is obtained by next two mechanisms: 1) formation of a thin-layer of AKD on the fiber surface through melting and spreading of AKD emulsion particles by heat, and 2) the formation of ketone by the hydrolysis of AKD during drying and storage of AKD-sized papers.

• Journal of Convergence for Information Technology
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• v.10 no.6
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• pp.77-86
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• 2020

A thin and porous non-flammable wiper was prepared by phosphorus acid solution treatment and subsequent oven annealing. The H₃PO₃ treatment improved flame retardancy of wiper paper to nonflammable level. Thermogravimetric analyses showed that residues increased to 50% at 700℃, which means this treatment helps dehydration of the cellulose chain and promotes the formation of char-like structures during the burning. FT-IR and X-ray photoelectron spectroscopy showed that some of the added H₃PO₃ could react with the functional groups of the cellulose chain. The reacted H₃PO₃ components promote dehydration of the cellulose components and the formation of a char-like structure and improve the flame retardancy of the wiper paper.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.48 no.2
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• pp.46-55
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• 2016

The microcrystalline cellulose (MCC) was prepared from oil palm biomass, empty fruit bunch (EFB) for increasing the usability of EFB. The morphological, physical and chemical properties of MCC made from EFB were evaluated by comparing with those of the commercial MCC obtained from AVICEL. The EFB-MCC had the wider distribution in particle size and there were many small particles around $10{\mu}m$. There were no significant differences in the cellulose crytallinity and the chemical composition between EFB-MCC and AVICEL-MCC. The properties of tablet samples made by the common direct compression process were evaluated depending on the types of MCC and the compression pressure during tablet making process. The tablet made of EFB MCC showed the higher compressed structure, which resulted in the less disintegration by the water soaking treatment than those made of Avicel-MCC. The results of this study showed that the EFB-MCC could be utilized as one of the commercial MCC.

• Journal of Electrochemical Science and Technology
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• v.11 no.2
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• pp.155-164
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• 2020

Here we report our preliminary results about nickel phosphide (Ni-P) electroless coating on the surface of cellulose paper (CP) and its feasibility as the anode for lithium (Li) batteries. In particular, CP can act as a flexible skeleton to maintain the mechanical structure, and the Ni-P film can play the roles of both the anode substrate and the active material in Li batteries. Ni-P films with different P contents were plated uniformly and compactly on the microfiber strands of CP. When they were tested as the anode for Li battery, their theoretical capacity per physical area was comparable to or higher than hypothetical pure graphite and P film electrodes having the same thickness. After the large irreversible capacity loss in the first charge/discharge process, the samples showed relatively reversible charge/discharge characteristics. All samples showed no separation of the plating layer and no detectable micro-cracks after cycling. When the charge cut-off voltage was adjusted, their capacity retention could be improved significantly. The electrochemical result was just about the same before and after mechanical bending with respect to the overall shape of voltage curve and capacity.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.31 no.1
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• pp.61-71
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• 1999

The study aimed at the theoretical analysis of vapor sorption properties of, pp.rmaking fibers. Water vapor affinity and sorption thermodynamic properties of fiber constituents were evaluated based on Henry's law and Hildebrand's solubility theory. Theoretical equilibrium moisture content(ThEMC) on fiber surface was estimated using functional group contribution. Crystallinity of cellulose in fiber significantly controlled the water vapor solubility. Comparisons of the measured equilibrium moisture content data and the estimated ThEMC data coincidently suggested the fact that crystallinity of cellulose in fibers was around 60% to 70%. Carbohydrates constituents including amorphous cellulose and hemicellulose in fibers showed higher vapor solubility than lignin molecules. High correlation existed between ThEMC and vapor solubility as well as between ThEMC and solubility parameter. In the thermodynamic analysis on water-vapor sorption process in fibers, the sorption enthalpy increased as RH increased, whereas sorption entropy and free energy decreased with increasing RH.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 2006.06a
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• pp.137-140
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• 2006

This paper describes a technique combining chemometrics with UV spectroscopy for the determination of the concentra tions of two tissue additives (i.e., wet strength and softening agents) in a cellulose fiber containing solution. In single as ent solutions, the concentration of the additive can be measured by UV spectroscopy at the wavelength where the species having absorption. For a binary (i.e., containing two additives) solution system, the spectral characterization is very complicated. However, if aided by a chemometrical calibration technique, each additive in the binary solution can be quantified simultaneously. The present method is very rapid and simple, it can easily perform a continuous measurement in the changes in the additives' concentration after fiber addition, and therefore this becomes a valuable tool for the adsorption kinetics study of chemical additives onto the cellulose fibers. The time-dependent adsorption behaviors of the wet-strength, softening agent, and their both on fiber were also presented.

• Asian-Australasian Journal of Animal Sciences
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• v.19 no.8
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• pp.1164-1173
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• 2006

Cellulase from Aspergillus niger, (${\alpha}$-amylase from Bacillus sp. and protease from Bacillus globigii were used as enzyme sources in this study to examine how their respective substrates protect them in two kinds of simulated gastrointestinal tract digesting processes. Avian total digest tract simulation test showed that filter paper, Avicel and cellulose resulted in 7.7, 6.4 and 7.4 times more activity than of unprotected cellulose, respectively. Protease with addition of casein, gelatin or soybean protein showed no significant protection response. Starch protected amylase to be 2.5 times activity of the unprotected one. Monogastric animal total tract digestion simulation test showed that filter paper, Avicel and cellulose resulted in 5.9, 9.0 and 8.8 times activity of unprotected cellulase, respectively. Casein, gelatin and soybean protein resulted in 1.2, 1.3 and 2.0 times activity of unprotected protease, respectively. Starch did not protect amylase activity in monogastric animal total tract simulation. Protection of mixed enzymes by substrates in two animal total tract simulation tests showed that filter paper in combination with soybean protein resulted in 1.5 times activity of unprotected cellulose, but all substrates tested showed no significant protection effect to protease. Soybean protein and starch added at the same time protected the amylase activity to be two times of the unprotected one. Test of non-purified substrate protection in two animal total digest tract simulation showed that cellulase activity increased as BSA (bovine serum albumin) concentration increased, with the highest activity to be 1.3 times of unprotected enzyme. However, BSA showed no significant protection effect to protease. Amylase activity increased to 1.5 times as BSA added more than 1.5% (w/v). Cellulase activity increased to 1.5 times as soybean hull was added higher than 1.5%. Amylase had a significant protection response only when soybean hull added up to 2%. Protease activity was not protected by soybean hull to any significant extent.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2009.10a
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• pp.198-201
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• 2009

Due to piezoelectric property of regenerated cellulose paper, a green energy harvester using an electro-active paper (EAPap) was studied. In order to design the green energy harvester, we simulated cymbal type energy harvesting structures for single and multi-stacked layers of EAPap films. From the simulation, the optimized material orientation, thickness of harvesting structure was selected. By measuring of the induced output voltage by applying stress on energy harvester will be explained in detail. Therefore we propose the feasibility of the nature-friendly piezoelectric EAPap as a new green energy harvesting material.

• Journal of Electrical Engineering and Technology
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• v.7 no.6
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• pp.954-958
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• 2012

This paper reports a flexible patch rectenna for wireless actuation of cellulose electro-active paper actuator (EAPap). The patch rectenna consists of rectifying circuit layer and ground layer, which converts microwave to dc power so as to wirelessly supply the power to the actuator. Patch rectennas are designed with different slot length at the ground layer. The fabricated devices are characterized depending on different substrates and polarization angles. The EAPap integrated with the patch rectenna is actuated by the microwave power. Detailed fabrication, characterization and demonstration of the integrated rectenna-EAPap actuator are explained.

• Journal of the Korean Society for Precision Engineering
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• v.32 no.8
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• pp.743-748
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• 2015

This paper reports the enhanced fabrication and characterization of a $3{\times}3$ array tactile actuator composed of cellulose acetate. The array tactile actuator, with dimensions of $15{\times}15{\times}1mm^3$, consists of 9 pillar-supported cells made from a cellulose-acetate molding. The fabrication process and performance test along with the results for the suggested actuator are explained. To improve the cell-array fabrication, a laser cut was adopted after the molding process. The displacement of the unit cell increased the input voltage and frequency. Various top masses are added onto the actuator to mimic the touch force, and the acceleration of the actuator is measured under actuation. When 2 kV is applied to the actuator, the maximum acceleration is 0.64 g, which is above the vibrotactile threshold. The actuation mechanism is associated with the electrostatic force between the top and bottom electrodes.