• Title/Summary/Keyword: Cell-cell contact

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Textured Surface Epitaxial Base Silicon Solar Cell (Textured 표면을 갖는 에피텍셜 베이스 실리콘 태양전지)

  • 장지근;임용규;정진철
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.2
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    • pp.33-37
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    • 2003
  • The new textured surface epitaxial base(TSEB) cell as a high efficiency Si solar cell was fabricated and its eletro-optical characteristics were investigated. The fabricated device showed the open circuit voltage of 0.62 V, the short circuit current of 40 mA, the fill factor of 0.7, and the efficiency of 16% under the incident light of AM-1 100 mW/$cm^2$. The TSEB cell proposed in this paper has the structural superiority in the fabrication of high efficiency solar cell due to the carrier drift transport in the optical absorption region and the formation of back surface field by $P^-/P^+$ epitaxial base, and the low emitter series resistance by insertion of $n^+$ buried contact.

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Ion Release and Biocompatibility of Sintered Ni-Cr-Ti Alloy for Dental Prosthodontics (치과보철용 Ni-Cr-Ti소결체합금의 이온용출과 생체적합성)

  • Choe, Han-Cheol;Kim, Seung-Hui
    • Journal of Surface Science and Engineering
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    • v.50 no.5
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    • pp.360-365
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    • 2017
  • In this study, ion release and biocompatibility of sintered Ni-Cr-Ti alloy for dental prosthodontics have been researched by corrosion and cell culture test. The microstructures of the alloys were observed by optical microscope, and corrosion behavior was investigated using potentiostat (Model PARSTAT 2273, EG&G, USA). Cell culture was carried out using hGf cell in DMEM (Welgene Inc., South Korea) supplemented with 10% fetal bovine serum (FBS) (Welgene Inc., South Korea) and antibiotic antimycotic solution (Welgene Inc., South Korea). After corrosion and cell culture test, surface morphologies were observed by field-emission scanning electron microscopy. For wettability behaviors, contact angles were measured by wettability test. As the content of Ti increased, the number of pit decreased and the corrosion resistance was improved from anodic polarization test, also, polarization resistance of samples containing Ti remarkably improved as compared with the alloy not containing Ti. The sintered alloy showed a low contact angle due to the pores formed on the surface. The addition of Ti element showed that the cell survival rate was better than that of the control group.

Corrosion of rebar in carbon fiber reinforced polymer bonded reinforced concrete

  • Bahekar, Prasad V.;Gadve, Sangeeta S.
    • Advances in concrete construction
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    • v.8 no.4
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    • pp.247-255
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    • 2019
  • Several reinforced concrete structures that get deteriorated by rebar corrosion are retrofitted using Carbon Fiber Reinforced Polymer (CFRP). When rebar comes in direct contact with CFRP, rebar may corrode, as iron is more active than carbon. Progression of corrosion of rebar in strengthened RC structures has been carried out when rebar comes in direct contact with CFRP. The experimentation is carried out in two phases. In phase I, corrosion of bare steel bar is monitored by making its contact with CFRP. In phase II, concrete specimens with surface bonded CFRP were casted and subjected to the realistic exposure conditions keeping direct contact between rebar and CFRP. Progression of corrosion has been monitored by various parameters: Half-cell potential, Tafel extrapolation and Linear Polarisation Resistance. On termination of exposure, to find residual bond stress between rebar and concrete, pull-out test was performed. Rebar in contact with CFRP has shown substantially higher corrosion. The level of corrosion will be more with more area of contact.

Three Predictive Tests Using Mice for the Identification of Contact Sensitizer

  • Jung-Hyun Shin;Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.22 no.2
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    • pp.201-210
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    • 1996
  • Predictive tests for the identification of contact sensitizing chemicals have been developed. We measured the sensitization potential with three predictive tests, the in vitro and the in vivo Local Lymph Node Assay(LLNA), ELISA to detect interferon-gamma(IFN-${\gamma}$) from supernatant and flow cytometry to detect change of cell surface proteins, using draining lymph nodes of mice. BALB/c mice were exposed to various chemicals or vehicles on the ears daily for 3 consecutive days in all experiments. With some exceptions of propyl paraben, neomycin sulfate, the in vivo LLNA was able to detect the sensitizing capacity of test chemicals and was more sensitive than the in vitro LLNA for chemicals used in the present study. In another experiment, contact sensitivity was assessed by the ELISA to detect IFN-Υ from the supernatants of the cultured LNCs after sensitization with chemicals. There was a good correlation between the LLNA and the IFN-Υ production for test chemicals. We also examined the change of cell surface proteins on LNCs after sensitization by flow cytometry for some cell adhesion molecules(ICAM-1, E-cadherine, B7 molecule), T cell markers(CD3, CD4, CD8, T$\alpha$$\beta$,T${\gamma}$$\delta$) and B cell markers(LR1, CD45R, I-Ad). The number of ICAM-1 positive cells and B cells in LNCs were increased after sensitization with DNCB, TNCB, isoeugenol and 25%, 50% cinnamic aldehyde compared with that of vehicle as a control. In conclusion, the in vivo LLNA could provide more sensitive screening test for moderate to strong sensitizers and some weak sensitizers including cosmetic raw materials than the in vitro LLNA. The production of IFN-Υ by allergen-activated LNCs might be a values indicators without radioisotopes for the identification of contact allergens. Detection of allergens by testing the increase of ICAM-1 positive cells and B cells in LNCs by flow cytometry might be used as a test method to detect allergens.

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Front-side Texturing of Crystalline Silicon Solar Cell by Micro-contact Printing (마이크로 컨텍 프린팅 기법을 이용한 결정질 실리콘 태양전지의 전면 텍스쳐링)

  • Hong, Jihwa;Han, Yoon-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.11
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    • pp.841-845
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    • 2013
  • We give a textured front on silicon wafer for high-efficiency solar cells by using micro contact printing method which uses PDMS (polydimethylsiloxane) silicon rubber as a stamp and SAM (self assembled monolayer)s as an ink. A random pyramidal texturing have been widely used for a front-surface texturing in low cost manufacturing line although the cell with random pyramids on front surface shows relatively low efficiency than the cell with inverted pyramids patterned by normal optical lithography. In the past two decades, the micro contact printing has been intensively studied in nano technology field for high resolution patterns on silicon wafer. However, this promising printing technique has surprisingly never applied so far to silicon based solar cell industry despite their simplicity of process and attractive aspects in terms of cost competitiveness. We employ a MHA (16-mercaptohexadecanoic acid) as an ink for Au deposited $SiO_2/Si$ substrate. The $SiO_2$ pattern which is same as the pattern printed by SAM ink on Au surface and later acts as a hard resist for anisotropic silicon etching was made by HF solution, and then inverted pyramidal pattern is formed after anisotropic wet etching. We compare three textured surface with different morphology (random texture, random pyramids and inverted pyramids) and then different geometry of inverted pyramid arrays in terms of reflectivity.

Evaluation of Skin Sensitization Potential of Skin Whitening Agents by Local Lymph Node Assay (국소 림프절 시험법(Local lymph node assay)을 이용한 피부미백화장품 원료의 피부감작성 연구)

  • 이종권;박승희;박재현;김형수;엄준호;남기택;한범석;장동덕;최광식
    • Toxicological Research
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    • v.19 no.4
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    • pp.285-291
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    • 2003
  • The use of skin whitening agents has been recently increased in various kinds of cosmetic products, although there were some reports that whitening agents might cause allergic contact dermatitis. A murine local lymph node assay (LLNA) has been developed as an alternative to guinea pigs for contact sensitization potential. This study was carried out to investigate the skin sensitization potential of three whitening agents, arbutin, azelaic acid, and kojic acid, by LLNA using a non-radiois-topic endpoint. Female Balb/c mice were exposed topically to a weak allergen, $\alpha$-hexylcinnamalde-hyde (HCA), and three whitening agents following LLNA protocol. Lymph node (LN) weight and cell proliferation in ears and auricular lymph node using bromodeoxyuridine (BrdU) immunohistochemistry were evaluated. LN weights were significantly increased at the HCA group compared to the vehicle control. A weak allergen, HCA elicited 3-fold or greater increase in cell proliferation of lymph nodes as well as increase in cell proliferation of ear as measured by BrdU immunohistochemistry. However, in the case of skin whitening agent groups, there were no significant changes in LN weight and cell proliferation in the ear and lymph node of mice treated with 5, 10 and 20% of three whitening agents compared to the vehicle control. These results show that these three skin whitening agents may not have contact sensitization potentials at tested concentrations in Balb/c mice by LLNA.

Corrosion characteristics and interfacial contact resistances of TiN and CrN coatings deposited by PVD on 316L stainless steel for polymer electrolyte membrane fuel cell bipolar plates

  • Lee, Jae-Bong;Oh, In Hwan
    • Corrosion Science and Technology
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    • v.12 no.4
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    • pp.171-178
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    • 2013
  • In a polymer membrane fuel cell stack, the bipolar plate is a key element because it accounts for over 50% of total costs of the stack. In order to lower the cost of bipolar plates, 316L stainless steels coated with nitrides such as TiN and CrN by physical vapor deposition were investigated as alternative materials for the replacement of traditional brittle graphite bipolar-plates. For this purpose, interfacial contact resistances were measured and electrochemical corrosion tests were conducted. The results showed that although both TiN and CrN coatings decreased the interfacial contact resistances to less than $10m{\Omega}{\cdot}cm^2$, they did not significantly improve the corrosion resistance in simulated polymer electrolyte membrane fuel cell environments. A CrN coating on 316L stainless steel showed better corrosion resistance than a TiN coating did, indicating the possibility of using modified CrN coated metallic bipolar plates to replace graphite bipolar plates.

Development of Surface Coating Technology for Metallic Bipolar Hate in PEMFC : II. Study on the PEMEC Performance of Coated Metallic Bipolar Plate (PEMFC용 금속분리판 코팅 기술 개발 : II. 코팅 금속분리판 연료전지 성능 특성 연구)

  • Yun, Yong-Sik;Chung, Kyeong-Woo;Yang, Yoo-Chang;Ahn, Seung-Gyun;Jeon, Yoo-Taek;Na, Sang-Mook
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.352-355
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    • 2006
  • As the stainless steel has good corrosion resistance, mechanical property and ease of manufacture, it has been studied as the candidate material of metallic bipolar plate for automotive PIMFC. But, metal is dissolved under fuel cell operating conditions Dissolved ions contaminate a membrane electrode assembly (MEA) and, decrease the fuel cell performance. In addition, metal oxide formation on the surface of stainless steel increases the contact resistance in the fuel cell. These problems have been acted as an obstacle in the application of stainless steel to bipolar plate. Therefore, many kinds of coating technologies have been examined in order to solve these problems. In this study, stainless steel was coated in order to achieve high conductivity and corrosion resistance by several methods. Contact resistance was measured by using a tensile tester and impedance analyzer Corrosion characteristics of coated stainless steel were examined by Tafel-extrapolation method from the polarization curves in a solution simulating the anodic and cathodic environment of PEMFC. Fuel cell performance was also evaluated by single cell test. We tested various coated metal bipolar plate and conventional and graphite were also tested as comparative samples. In the result, coated stainless steel bipolar plate exhibited better cell performance than graphite to bipolar plate.

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A Study to Improve PEMFC Performance by Using Electro Polishing and CrN Coating on Metal Bipolar Plate (금속분리판의 Electro Polishing 및 CrN 코팅을 통한 PEMFC 성능 향상을 위한 연구)

  • Hwang, Sung Tack;Cheon, Seung Ho;Song, Jun Seok;Yun, Young-Hoon;Kim, Byeong Heon;Zhang, Xia;Kim, Dae-Ung;Hyun, Deoksu;Oh, Byeong Soo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.4
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    • pp.65-71
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    • 2014
  • As an important component of a fuel cell, the bipolar plate comprises a large proportion in the fuel cell's volume, weight and price. The bipolar plate is the most widely used; however, graphite bipolar plate is large in volume, brittle and therefore easily broken during assembling. In addition, due to its poor machinability, production costs a lot, unless mass production. Compared with the graphite bipolar plate, the metal bipolar plate has good machinability, high electric conductivity and strong mechanical strength; however, it corrodes easily and has a high contact resistance, so in order to prevent corrosion and reduce the contact resistance, the basic metal needs to be processed by use of electro polishing and coating. The water which is produced by electrochemical reactions in the fuel cell must be discharged smoothly. In this study, in order to prevent corrosion the processes of electro polishing and CrN coating were used. According to the presence or absence of these processes, the contact angles can be measured and different metal bipolar plates can be made, these plates can be used for comparing and analyzing the performance of the fuel cell.

Effects of Pahs and Pcbs and Their Toxic Metabolites on Inhibition of Gjic and Cell Proliferation in Rat Liver Epithelial Wb-F344 Cells

  • Miroslav, Machala;Jan, Vondracek;Katerina, Chramostova;Lenka, Sindlerova;Pavel, Krcmar;Martina, Pliskova;Katerina, Pencikova;Brad, Upham
    • Environmental Mutagens and Carcinogens
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    • v.23 no.2
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    • pp.56-62
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    • 2003
  • The liver progenitor cells could form a potential target cell population fore both tumor-initiating and -promoting chemicals. Induction of drug-metabolizing and antioxidant enzymes, including AhR-dependent CYP1A1, NQO-1 and AKR1C9, was detected in the rat liver epithelial WB-F344 "stem-like" cells. Additionally, WB-F344 cells express a functional, wild-type form of p53 protein, a biomarker of genotoxic events, and connexin 43, a basic structural unit of gap junctions forming an important type of intercellular communication. In this cellular model, two complementary assays have been established for detection of the modes of action associated with tumor promotion: inhibition of gap junctional intercellular communication (GJIC) and proliferative activity in confluent cells. We found that the PAHs and PCBs, which are AhR agonists, released WB-F344 cells from contact inhibition, increasing both DNA synthesis and cell numbers. Genotoxic effects of some PAHs that lead to apoptosis and cell cycle delay might interfere with the proliferative activity of PAHs. Contrary to that, the nongenotoxic low-molecular-weight PAHs and non-dioxin-like PCB congeners, abundant in the environment, did not significantly affect cell cycle and cell proliferation; however both groups of compounds inhibited GJIC in WB-F344 cells. The release from contact inhibiton by a mechanism that possibly involves the AhR activation, inhibition of GJIC and genotoxic events induced by environmental contaminants are three important modes of action that could play an important role in carcinogenic effects of toxic compounds. The relative potencies to inhibit GJIC, to induce AhR-mediated activity, and to release cells from contact inhibition were determined for a large series of PAHs and PCBs and their metabolites. In vitro bioassays based on detection of events on cellular level (deregulation of GJIC and/or proliferation) or determination of receptor-mediated activities in both ?$stem-like^{\circ}{\times}$ and hepatocyte-like liver cellular models are valuable tools for detection of modes of action of polyaromatic hydrocarbons. They may serve, together with concentration data, as a first step in their risk assessment.

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