• 제목/요약/키워드: Cell behavior

검색결과 1,385건 처리시간 0.032초

Analysis of Flow Rate Inducing Voltage Loss in a 100 cm2 Class Molten Carbonate Fuel Cell

  • Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • 제2권1호
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    • pp.20-25
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    • 2011
  • This work focuses on the behavior of the overpotential increase due to a utilization rise in a molten carbonate fuel cell. The behavior is generally explained by Nernst loss, which is a kind of voltage loss due to the thermodynamic potential gradients in a polarization state due to the concentration distribution of reactant species through the gas flow direction. The evaluation of Nernst loss is carried out with a traditional experimental method of constant gas utilization (CU). On the other hand, overpotential due to the gas-phase mass-transport resistance at the anode and cathode shows dependence on the utilization, which can be measured using the inert gas step addition (ISA) method. Since the Nernst loss is assumed to be due to the thermodynamic reasons, the voltage loss can be calculated by the Nernst equation, referred to as a simple calculation (SC) in this work. The three values of voltage loss due to CU, ISA, and SC are compared, showing that these values rise with increases in the utilization within acceptable deviations. When we consider that the anode and cathode reactions are significantly affected by the gas-phase mass transfer, the behavior strongly implies that the voltage loss is attributable not to thermodynamic reasons, namely Nernst loss, but to the kinetic reason of mass-transfer resistance in the gas phase.

일축 압축하중 하 다공성 폴리우레탄폼의 재료비선형 거동 및 미세구조 변화 (Material Nonlinear Behavior and Microstructural Transition of Porous Polyurethane Foam under Uniaxial Compressive Loads)

  • 이은선;고태식;이치승
    • 한국재료학회지
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    • 제27권12호
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    • pp.688-694
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    • 2017
  • Porous materials such as polymeric foam are widely adopted in engineering and biomedical fields. Porous materials often exhibit complex nonlinear behaviors and are sensitive to material and environmental factors including cell size and shape, amount of porosity, and temperature, which are influenced by the type of base materials, reinforcements, method of fabrication, etc. Hence, the material characteristics of porous materials such as compressive stress-strain behavior and void volume fraction according to aforementioned factors should be precisely identified. In this study, unconfined uniaxial compressive test for two types of closed-cell structure polyurethane foam, namely, 0.16 and $0.32g/cm^3$ of densities were carried out. In addition, the void volume fraction of three different domains, namely, center, surface and buckling regions under various compressive strains (10 %, 30 %, 50 % and 70 %) were quantitatively observed using Micro 3D Computed Tomography(micro-CT) scanning system. Based on the experimental results, the relationship between compressive strain and void volume fraction with respect to cell size, density and boundary condition were investigated.

공산품 소비제품의 경고표시가 소비자행동에 미치는 영향 (Effects of Warning Labels of Consumption Goods on Consumer Behavior)

  • 양덕순;송인숙
    • 대한가정학회지
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    • 제43권4호
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    • pp.141-159
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    • 2005
  • The purpose of this study is to examine the effects of warning labels of consumption goods on consumer behavior and the consumers' evaluation in order to suggest a policy of warning labels and the Product Liability Law. The following items which are somewhat risky but are used in everyday the were selected: cup noodles, one-touch can foods, washing machine, microwave range, dry cell, hydro-oxygen detergent, baby-walker, and block-toys. Data were collected from 345 respondents by internet survey with the following results. (1) The average score of the effects of warning labels on consumer behavior was so low that warning labels are not considered effective, especially in block-toys, dry cell, and baby-walker. (2) Consumers' evaluation scores on the character size, design and sticking place of warning labels were very low. Therefore an effort to make warning labels more effective is needed.

An Investigation for Meaningful Model of a Lithium-Ion Cell to Take into Account Electrochemical Behavior, Thermal Behavior and Degradation Using MapleSim

  • Abbas, Mazhar;Kim, Jonghoon
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2017년도 추계학술대회
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    • pp.167-168
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    • 2017
  • This paper investigates to identify an optimal for analysis of battery behavior in system-level applications such as Battery Energy Storage Systems in Smart Grid infrastructures and Electrical vehicles. At system level applications, it is mandatory to check model for meaningful equivalency and practical ability for extension from unit cell to Battery stack. The investigation of current battery models in relation to their suitability for study and analysis of system level applications of battery helpful for identification of optimal model and it also provides an intuition and direction to develop the most suitable model, if such models are not available already.

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Significance of nonlinear permeability in the coupled-numerical analysis of tunnelling

  • Kim, Kang-Hyun;Kim, Ho-Jong;Jeong, Jae-Ho;Shin, Jong-Ho
    • Geomechanics and Engineering
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    • 제21권2호
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    • pp.103-109
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    • 2020
  • The inflow rate is of interest in the design of underground structures such as tunnels and buried pipes below the groundwater table. Soil permeability governing the inflow rate significantly affects the hydro-geological behavior of soils but is difficult to estimate due to its wide range of distribution, nonlinearity and anisotropy. Volume changes induced by stress can cause nonlinear stress-strain behavior, resulting in corresponding permeability changes. In this paper, the nonlinearity and anisotropy of permeability are investigated by conducting Rowe cell tests, and a nonlinear permeability model considering anisotropy was proposed. Model modification and parameter evaluation for field application were also addressed. Significance of nonlinear permeability was illustrated by carrying out numerical analysis of a tunnel. It is highlighted that the effect of nonlinear permeability is significant in soils of which volume change is considerable, and particularly appears in the short-term flow behavior.

스퍼터링으로 증착한 바나듐 텅스텐 산화물 박막의 전기화학적 거동 (Electrochemical Behavior of Vanadium Trungsten Oxide Thin Films Deposited by Sputtering)

  • 박영신;이병일;주승기
    • 한국표면공학회지
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    • 제30권2호
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    • pp.121-127
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    • 1997
  • Vanadium tungsten oxide thin films were formed by RF magnetron sputtering and the effects of tungsten addition on the crystallinity and on the electrochemical behavior were investigated. X-ray analysis revealed that amorphized films could be obtained by tungase addition. In order to investigate the electrochemical behavior of the vanadium tungsten oxide films, electrochemical insertion and extraction of lithium were out in 1m $LiCIO_4$-PC-DME electrolyte using litium metal as a counter electrode. When the tungsten was added to the $V_2O_5$ films, cycling reversibility was considerably improved. Electrochemical test showed the cell capacity of about $70\mu\;Ah/\textrm{cm}^2-\mu\textrm{m}$ when the amount of additive tungseten reached 30 atomic percent. No appreciable degradation of the cell capacity could be observed after hundred cycles of insertion and extration od Li.

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Studies of Electric Double Layer Capacitors Used For a Storage Battery of Dye Sensitized Solar Cell Energy

  • Kim Hee-Je;Jeon Jin-An;Sung Youl-Moon;Yun Mun-Soo;Choi Jin-Young
    • Journal of Electrical Engineering and Technology
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    • 제1권2호
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    • pp.251-256
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    • 2006
  • To design the effective usage of electric double layer capacitors (EDLCs) used for a storage device of dye sensitized solar cell (DSC) energy, we first investigated the accumulation state of electrical charges and the charge behavior in the EDLCs. Based on the results, the voltage characteristics of EDLCs connected to DSC energy were evaluated. The results showed that the charge accumulation region concentrated on the central part of the carbonaceous electrode in EDLCs and the required times for charging and discharging were almost the same.

염료감응형 태양전지의 축전지로 사용되는 전기이중층콘덴서에 대한 연구 (Studies of electric double layer capacitors used for a storage battery of dye sensitized solar cell energy)

  • 최진영;이임근;홍지태;김희제
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2005년도 제17회 워크샵 및 추계학술대회
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    • pp.673-676
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    • 2005
  • To design the effective usage of electric double layer capacitors (EDLCs) used for a storage device of dye sensitized solar cell(DSC) energy, we first investigated the accumulation state of electrical charges and the charge behavior in the EDLCs. Based on the results. the voltage characteristics of EDLCs connected to DSC energy were evaluated. The results showed that the charge accumulation region concentrated on central part of the carbonaceous electrode in EDLCs and the required times for charging and discharging were almost the same.

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개질 가스특성에 따른 고체산화물 연료전지의 성능 변화 (Performance behavior of solid oxide fuel cell with various anode gas)

  • 박광진;배중면
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.59-62
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    • 2008
  • The performance behavior of solid oxide fuel cell using reformate gas as fuels was investigated. When the pre-reformate gas was used without steam, the maximum power density was 50% lower than that using H2. This may be due to carbon deposition caused by the pyrolysis of remaining hydrocarbons. However, when the steam was added, the maximum power density showed a relatively small variation according to reformate gas. When pre-reformate gas with steam was fed into anode, the SOFC showed the stable performance without sharp voltage drop during 10h operation.

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중.저온형 고체산화물 연료전지에서 연료로 공급되는 CO 와 H2 가 성능에 미치는 영향 (Performance Behavior by H2 and CO as a Fuel in Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC))

  • 박광진;배중면
    • 대한기계학회논문집B
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    • 제32권12호
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    • pp.963-969
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    • 2008
  • The performance behavior of solid oxide fuel cell using $H_2$ and CO as fuels was investigated. The power densities and impedance results showed a little variation as the ratio of $H_2$ and CO changed. However, when the pure CO was used as a fuel, area specific resistance (ASR), especially low frequency region, was increased. This might be due to carbon deposition on anode. The maximum power density was 60% lower using CO than using $H_2$. Carbon deposition reduced after constant current was applied. The SOFC performance was recovered from the carbon deposition after applying constant current during 100h.