• Journal of Environmental Health Sciences
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• v.26 no.4
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• pp.1-8
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• 2000

The objective of this study was to identify the sources and to estimate the source contributions to the atmospheric TSP(total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less than 10$\mu\textrm{m}$) concentration in Taegu area. A total of 84 samples was collected during the January to December 1999. TSP and PM-10 were collected on filters by portable air sampler, and heavy metals in TSP and PM-배 were analyzed by ICO(Inductively Coupled Plasma Spectrometery) after preliminary treatment. The results were follow as : First, annual average of TSP and PM-10 concentration was 123 and 69$\mu\textrm{g}$/㎥ respectively. The concentration of TSP and PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these heavy metals are generally associate with natural contributions. Third, metal combinations showed that a high correlation among concentrations of heavy metals were follows: As Al, Fe and Mn in TSP ; Ni, Cr, Cd and Pb in PM-10. Finally, Statistical analysis was performed using Principal Components Analysis(PCA) in order to find possible sources of the pollutants. The factor analysis was permitted to identify four major sources(soil/road dust resuspension, waste incineration, furl combustion, vehicular emission) in each fraction. These source accounted for at least 83, 85% of variance of TSP and PM-10 concentration in Taegu area.

• 연구논문집
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• s.31
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• pp.5-14
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• 2001

These days, interest in the leaching of hazardous heavy metals to consist of incinerator fly ash is increasing, because the heavy metals that leach from the incinerator fly ash pollute the soil and ground water. Therefore this study was undertaken to crystallize the fly ash and prevent the leaching of hazardous heavy metals from fly ash. The concentrations and the leaching concentration of hazardous heavy metals(Cd, Cr, Hg, Pb, Zn) in the law incinerator fly ash have been measured. The fly ash was melted with two kinds of flux($Na_2CO_3, CaCO_3$) and its add quantity(0, 1, 2, 3 wt%). The crystal structure of melting materials was analyzed by SEM(Scaning Electron Microscope) and X-RD(X-Ray Diffractometer). The leaching test of melting materials was undertaken. And the relation between crystallization of melting materials and flux and leaching concentration. These experiments indicate that the concentration and leaching concentration of heavy metals in incinerator fly ash was much higher than the regulatory standard for leachates in Korea and U.S.A and average concentration of heavy metals in soil. And the crystal structure was better.

• Journal of the Korean institute of surface engineering
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• v.40 no.2
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• pp.77-81
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• 2007

To investigate the characteristics of green light-emitting OLED device, C545T material with $Alq_3$ was doped in the OLED device of $ITO(1500)/2-TNATA(400{\AA})/NPB(80{\AA})/Alq_3:C545T(160{\AA})/Alq_3(240{\AA})/LiF(3{\AA})/Al(2400{\AA})$ structure, which was used as a activator at the respective concentration of 0.5 vol.%, 1 vol.%, 2 vol.% and 3 vol.%. It was observed from the experiments that the device efficiency firstly increased with the increase of C545T concentration and the maximum efficiency of 10.9 cd/A and 4.28 lm/W was obtained at C545T concentration of 1 vol.%, and then the device efficiency decreased as the C545T activator concentration increased above 2 vol.% contents, while the longest lifetime of over 750 hours was obtained at C545T concentration of 1 vol.%.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.6
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• pp.673-680
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• 2013

Phosphorus accumulating microorganisms (PAOs) are influenced by various environmental factors and heavy metals. This study was performed to evaluate the effects of the selected heavy metals on the growth and phosphorus removal capacity of Bacillus sp. 3434 BRRJ, Pseudomonas aerunogisa, and Bacillus Subtilis, well known as PAOs. The heavy metals used in this study included Cu, Cd, As, and Zn. The $IC_{50}$ (median inhibition concentration) values of Bacillus sp. 3434 BRRJ for the Cu, Cd, As, and Zn were 8.07 mg $L^{-1}$, 0.18 mg $L^{-1}$, 73.62 mg $L^{-1}$ and 0.25 mg $L^{-1}$, respectively. The $IC_{50}$ values of Pseudomonas aerunogisa for the Cu, Cd, As, and Zn were 4.45 mg $L^{-1}$, 0.16 mg $L^{-1}$, 18.51 mg $L^{-1}$ and 2.34 mg $L^{-1}$, respectively. The $IC_{50}$ values of Bacillus Subtilis for the Cu, Cd, As, and Zn were 3.81 mg $L^{-1}$, 0.18 mg $L^{-1}$, 11.31 mg $L^{-1}$ and 0.47 mg $L^{-1}$, respectively. The phosphorus removal efficiencies of the three bacteria, Bacillus sp. 3434 BRRJ, Pseudomonas aerunogisa, and Bacillus subtilis were 93.12%, 71.81%, and 65.31%, respectively. Based on the results of the three PAOs obtained from the study, it appears that Bacillus sp. 3434BRRJ may have the best results in terms of their growth rate and P removal efficiencies.

• Environmental Analysis Health and Toxicology
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• v.31
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• pp.21.1-21.7
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• 2016

Objectives The present study analyzes metal contamination in sediment of the East Kolkata Wetlands, a Ramsar site, which is receiving a huge amount of domestic and industrial wastewater from surrounding areas. The subsequent uptake and accumulation of metals in different macrophytes are also examined in regard to their phytoremediation potential. Methods Metals like cadmium (Cd), copper (Cu), manganese (Mn), and lead (Pb) were estimated in sediment, water and different parts of the macrophytes Colocasia esculenta and Scirpus articulatus. Results The concentration of metals in sediment were, from highest to lowest, Mn ($205.0{\pm}65.5mg/kg$)>Cu ($29.9{\pm}10.2mg/kg$)>Pb ($22.7{\pm}10.3mg/kg$)>Cd ($3.7{\pm}2.2mg/kg$). The phytoaccumulation tendency of these metals showed similar trends in both native aquatic macrophyte species. The rate of accumulation of metals in roots was higher than in shoots. There were strong positive correlations (p <0.001) between soil organic carbon (OC) percentage and Mn (r =0.771), and sediment OC percentage and Pb (r=0.832). Cation exchange capacity (CEC) also showed a positive correlation (p <0.001) with Cu (r=0.721), Mn (r=0.713), and Pb (r=0.788), while correlations between sediment OC percentage and Cu (r=0.628), sediment OC percentage and Cd (r=0.559), and CEC and Cd (r=0.625) were significant at the p <0.05 level. Conclusions Bioaccumulation factor and translocation factors of these two plants revealed that S. articulatus was comparatively more efficient for phytoremediation, whereas phytostabilization potential was higher in C. esculenta.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.21 no.4
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• pp.125-133
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• 2016

We investigated the distribution of organic matter and trace metals in surface sediment from Tonyeong coast. To determine the status of trace metal pollution, we also conducted an ecological risk assessment. Relatively high concentration of TN (total nitrogen), TOC (total organic carbon), and AVS (acid volatile sulfide) was found in surface sediment located in the narrow channel (site 35-38). Spatial distribution of Cd, Cr, Ni, Co, Hg, and Zn in surface sediment was similar and high Cu concentrations were found in narrow channel. The assessment of heavy metal pollution was derived using the Enrichment factors (EF). The enrichment factor indicated that Cd was no enrichment (EF<1), Pb, Cr, Ni, Co, Zn, and Hg were minor enrichment (1

• Journal of Environmental Science International
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• v.24 no.12
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• pp.1583-1590
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• 2015

The aim of this study was to examine the morphological responses of Hosta longipes, an ornamental plants for heavy metal contaminated soils in urban landscaping, to heavy metals Cd, Pb, and Zn. Plants were grown in artificial soil amended with Cd, Pb, and Zn at concentation of 0, 100, 250, and 500 mg/kg. Plant height, leaf length, leaf width, total leaf number, deaf leaf number, new leaf number, chlorophyll contents, and ornamental value were monitored from May to August. At 4 months after planting, the survival and morphological responses of H. longipes grown in soil amended with Cd at concentrations ${\geq}100mg/kg$ were severely affected compared to those grown in the control soil. Relative leaf length rate and relative leaf width rate were significantly decreased when the concentration of Pb was increased. Total leaf number, chlorophyll contents, and ornamental value were the lowest value in plants grown in soil amended with Pb at level of 500 mg/kg. Relative leaf length rate and relative leaf width rate, total leaf number, dead leaf number, new leaf number, and ornamental values had a tendency of decrease when plants were grown in soils amended with Zn. However, no significant difference was found among treatments except for plants were grown in soils amended with 500 mg/kg Zn. Therefore, Hosta longipes might be useful for phytoremediation of Zn contaminated sites as herbaceous ornamental plants.

• Journal of Society of Preventive Korean Medicine
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• v.6 no.1
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• pp.129-139
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• 2002

This research purpose was to get urine and hair metal correlation by Spearman methods in subjects with long term intake of herbal medicine. And that result can help research for metal absorption mechanism in body. Subjects have been intake 1-124 months(7.55 months mean) in decoction and 1-60 months (1.27 months means) for some disease treatment in sampling point. 1) Metal concentrations in urine and hair of study subjects showed higher than WHO reference limits, especially 0.32-6.17% in urine and 11.69-26.95% in hair. 2) Metal concentration in urine correlated 0.37(p〈0.001) Cu to Cd, 0.37(p〈0.001) Pb to Cu, 0.29(p〈0.001) Pb to Cu, 0.29(p〈0.001) Pb to Cd, and 0.36(p〈0.001) Pb to Cu, -0.13(p〈0.05) Hg to Cu in hair. Also between urine and hair correlated 0.21(p〈0.001) Cd to Cd. 0.17(p〈0.01) Pb to Pb, -0.06 Cu to Hg, -0.01 Hg to Cu. These results showed that occur physical and chemical reaction among many metals in body, respectively. However, further study related this subjects will be need.

• Journal of Pharmaceutical Investigation
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• v.27 no.1
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• pp.29-38
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• 1997

Precipitation was formed during the preparation of decoction from a mixture of Scutellariae Radix and Coptidis Rhizoma. Baicalin and berberine were identified in this coprecipitated product (CPP) and these components were the active ingredients of two herbal medicine. We extracted respectively crude baicalin and berberine in Scutellariae Radix and Coptidis Rhizoma and prepared coprecipitate of crude baicalin-berberine. To increase the stability and bioavailability of coprecipitate of crude baicalin-berberine(CBB), which is slightly soluble drug, its inclusion complex was prepared and studied in this experiment. Inclusion complex of CBB with ${\beta}-cyclodextrin(CBB-{\beta}-CD)$ was prepared by freeze drying method and its characteristics were ascertained by means of solubility test, differential thermal analysis(DTA) and scanning electron microscope(SEM). The type of $CBB-{\beta}-CD$ is classified as $A_L-type$ on phase solubility diagram, and the stoichiometric ratio of CBB(baicalin in CBB) : ${\beta}-CD$ complex is 1:1 and formation constant is 151 $M^-1$. The solubility, dissolution, in situ absorption and serum concentration of $CBB-{\beta}-CD$ were significantly increased when compared to CBB. Therefore enhanced bioavailability of CBB by inclusion complexation with ${\beta}-cyclodextrin$ might be useful for dosage form design of active ingredients of two herbal medicine.

• Journal of Korean Society on Water Environment
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• v.34 no.2
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• pp.157-163
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• 2018

This study aims to determine the pollution levels of nine kinds of heavy metals (As, Cd, Cu, Cr, Hg, Mn, Ni, Pb, and Zn) in Lake Shihwa, which is susceptible to the inflow of pollutants, and the levels of heavy metal exposure in its fish and shellfish. Shihwa Lake's water quality did not exceed the short-term standard for protection of marine ecosystems, but concentrations of As, Cu, Cr, Hg, Ni, and Zn exceeded the long-term standard for protection of a marine ecosystem. In comparison to findings in prior research, performed in 2010, levels of Cr, Ni, As, and Zn are now 4.1 times lower. However, when compared to Saemangeum Lake, the environment is similar to that of Lake Shihwa, Cu, Ni, Hg, Mn, and Zn were 244.4 times higher. The levels of Pb, Cd, and Hg in fish's muscles did not exceed the average values set by the marine safety standard. However, when compared to the fish from the Korean coast, the levels of heavy metals were 9.7 times higher, on average. The levels of heavy metals in fish's livers were on average 26.8 times higher than in the muscles. In the case of shellfish, the levels of Pb, Cd, and Hg did not exceed the standard values, but in comparison to the shellfish from the south coast, the levels of heavy metals were 6.2 times higher on average. In particular, Mn (153.5 times higher) from fish and Cd (14.7 times higher) from shellfish were found in high amounts, indicating a concerning level of these specific heavy metals.