• Title/Summary/Keyword: Cd concentration

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Pollutant Release from Crushed Reclaimed Concrete (폐콘크리트 재생골재로부터의 오염물질 용출에 대한 실험적 고찰)

  • Hong, Seong-Gu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.47 no.1
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    • pp.71-77
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    • 2005
  • Recycling of reclaimed concrete (RC) is very important in the management of construction and demolition wastes. Most of RC is utilized for land-filling after crushing in this country. In this study, a series of elution experiments were conducted to investigate the type and amount of pollutants released from the crushed RC. Most water quality parameters including heavy metals and some organic compounds were below standards for drinking water. Some of heavy metals such as As, Cd, Pb, Hg were detected in 0.5 N H2S04 solution after 24-hour immersing RC, which was conducted for evaluating a long term release effect. The concentration of the heavy metals were higher than the drinking water standards. The results also showed significant adsorption of heavy metals by crushed Re. Potential risks, based on the result of this study were not high in using crushed RC for land-filling. Appropriate management of RC would reduce the risk, for example the separation of hazardous materials from construction wastes. Long term evaluations for the sites of land filled with RC would be required to assess the environmental impacts.

A Study on the High-Efficiency Red OLEDs using Phosphorescent Materials (인광재료를 이용한 고효율 적색 유기발광 다이오드에 관한 연구)

  • Shim, Ju-Yong;Jeon, Hyeon-Seong;Cho, Jae-Young;Jung, Jin-Ha;Yoon, Seok-Beom;Kang, Myung-Goo;Oh, Hwan-Sool
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.428-429
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    • 2006
  • In this thesis, verifies electrical-optical characteristics of phosphorescent materials. basic structure of fabricating devices is glass/ITO/$\alpha$-NPD($300{\AA}$)/CBP:Guest($300{\AA}$)/BCP($80{\AA}$)/$Alq_3(100{\AA})$/Al($1000{\AA}$). In efficiency, fabrication of organic light emitting diodes using $Ir(btp)_2acac$ phosphorescent material is external quantum efficiency 0.268% as doping concentration 3%. At CIE coordinates, phosphorescent material $Ir(btp)_2acac$ following materials moves high purity red color(x=0.6686, y=0.3243). The brightness shows $285cd/cm^2$.

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Effect of Temperature on Persistence of Recombinant Plasmid pCU103 in Different Waters

  • Kwak, Myong-Ja;Kim, Chi-Kyung;Kim, Young-Chang;Lim, Jai-Yun;Kim, Young-Soo;Lee, Ki-Sung;Min, Kyung-Hee
    • Journal of Microbiology
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    • v.33 no.3
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    • pp.178-183
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    • 1995
  • The recombinant plasmid of pCU103 constructed by cloning pcbCD genes in pBluescript SK(+) was studied for the effect of temperature on its persistence in different waters by the methods of electrophoresis, Southern hybridization, quantification, and transformation. The plasmid was very rapidly degraded out in non-sterile FW water without regards to water temperature, probably due to the effect of biochemical factor such as nucleases. The pCU103 was most persistent at 4$^{\circ}C$ in any water environments, moderately persistant at 15$^{\circ}C$ but least stable at 3$0^{\circ}C$ such results could be explained by the facts that hydrogen bonds in double-stranded plasmid DNAs become unstable and that nucleases are activated by increasing temperature. The intact structure of pCU1-3 was generally observed by gel electrophoresis under the conditions which the plasmid should be 2.0 ng/$\mu\textrm{l}$ or higher in concentration and that about 10$^2$ CFU/ml or more transformant cells should be recovered.

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Inhibitory Effects of the Methanolic Fraction from Pueraria Radix on Hydrogen Peroxide-induced Lipid Peroxidation and Cadmium-induced Cytotoxicity (III) (갈근 메탄올분획의 과산화수소에 의해 유도된 지질과산화와 카드뮴에 대한 독성억제효과 (III))

  • Lim, Jin-A;Kim, Yun-Ha;Baek, Seung-Hwa
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.6
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    • pp.1556-1560
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    • 2006
  • The effects of the methanol subfraction from Pueraria Radix on hydrogen peroxide-induced lipid peroxidation and cadmium-induced cytotoxicity were investigated in NIH 3T3 fibroblast cells. After the methanol subfraction treatment, the content of MDA induced by 600 ${\mu}g$ $H_2O_2$ significantly decreased in proportion to the subfraction concentrations as well as 50 ${\mu}M$ $CdCl_2$-induced cytotoxicity. Especially, 200 ${\mu}g/mL$ concentration of methanol subfraction was strongly shown inhibition of lipid peroxidation and detoxification of cadmium. These results suggest that the methanol subfraction from Pueraria Radix retains a potential antioxidant and protective effect against cadmium.

Fabrication and Characterization of Orange Polymer Light Emitting Diodes by Concentration of MEH-PPV (MEH-PPV의 농도에 따른 황색 고분자 유기발광다이오드의 제작과 특성평가)

  • Jeon, Chang-Duk;Shin, Sang-Baie;Gong, Su-Choel;Park, Hyung-Ho;Jeon, Hyeong-Tag;Chang, Ho-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2008.05a
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    • pp.184-185
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    • 2008
  • 본 연구에서는 ITO/PEDOT:PSS//PFO:MEH-PPV/LiF/Al 구조를 갖는 고분자 유기발광다이오드를 제작하여 발광 도펀트인 MEH-PPV의 농도에 따른 황색 PLED 소자의 전기 광학적 특성에 대하여 조사하였다. MEH-PPV의 농도를 각각 6, 7, 8, 9, 10 wt% 로 변화시켜 소자를 평가한 결과 9 wt%의 농도에서 가장 우수한 전기 및 광학적 특성을 보였으며, 16 V의 인가전압에서 약 630 cd/$m^2$의 휘도 특성과 256 mA/$cm^2$의 전류밀도 특성이 관찰되었다. 또한 10 wt%의 소자에서는 오히려 낮은 광학적 특성이 관찰되어 9 wt%에서 도펀트의 농도가 포화됨이 관찰되었고, 제작된 소자의 색좌표 (CIE coordiante)는 모든 소자에서 (x, y = 0,49, 0.49)로 거의 동일하게 나타났다.

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Supramolecular Hydrogels Instantaneously Formed by Inclusion Complexation between Amphiphilic Oligomers and $\alpha$-Cyclodextrins

  • Zhao, Sanping;Lee, Jong-Hwi
    • Macromolecular Research
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    • v.17 no.3
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    • pp.156-162
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    • 2009
  • Supramolecular hydrogels were instantaneously fabricated by mixing aqueous solutions of $\alpha$-cyclodextrins ($\alpha$-CDs) and amphiphilic methoxy (polyethylene glycol) (MPEG)-$\varepsilon$-caprolactone (CL) oligomer, which was synthesized via the ring-opening polymerization of the CL monomer using low-molecular-weight MPEG ($M_n$ of MPEG=2,000 g/mol) as an initiator. The supramolecular structure of the hydrogels was revealed by X-ray diffraction (XRD) analyses. Rheological studies of the hydrogels revealed an elastic character when the number of CL units in the oligomer was more than 2, and the obtained hydrogels showed high storage modulus but relatively low shearing viscosity due to the low-molecular-weight character of the oligomer, which was more preferable for use as an injectable delivery system. The physical properties of the hydrogels could be modulated by controlling the chain morphology and concentration of the oligomers, as well as the feed molar ratio of the oligomer to $\alpha$-CD. The components of the supramolecular hydrogels are biocompatible and can readily be eliminated from the body. These features render the supramolecular hydro gels suitable as drug delivery systems and tissue engineering scaffolds.

Analysis of Cu in Mezcal Commercial Samples using Square Wave Anodic Stripping Voltammetry

  • Salinas, Gerardo;Ibanez, Jorge G.;Vasquez-Medrano, Ruben;Frontana-Uribe, Bernardo A.
    • Journal of Electrochemical Science and Technology
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    • v.9 no.4
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    • pp.276-281
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    • 2018
  • High concentration of copper in mezcal, a representative Mexican spirituous alcoholic beverage, is a serious problem due to the damage that it may cause to human health. A cyclic voltammetry and square wave anodic stripping voltammetry study of copper (II) in three commercial mezcal samples based on glassy carbon electrode response was undertaken. The analysis was developed using a simulated matrix solution ($EtOH/H_2O$ (1:1), 0.1 M $LiClO_4$ and AcOH/AcONa 0.05 M/0.008 M), with Cu (II) concentrations in the range 0 - 1 ppm. Direct electrochemical analysis of mezcal samples was complicated by the presence of different organic compounds in the matrix. The analytical signal of Cu (II) in the spirituous was notably improved and the interferences caused by organic compounds were minimized, by diluting the mezcal samples 10% with $EtOH/H_2O$ (1:1) solution. An efficient quantification of Cu (II) was obtained from the calibration curve by the SWASV and using the internal standard method (Cd (II)) in commercial samples (1.2-6.7 ppm); the results were correlated satisfactorily with the values obtained by AAS.

Studies on the Macrocycle mediated Transport in a Bulk Liquid Membrane System of Transition Metal Ions

  • Cho, Moon-Hwan;Seon-Woo, Kie-Hwa;Heo, Moon-Young;Lee, In-Chong;Yoon, Chang-Ju;Kim, Si-Joong
    • Bulletin of the Korean Chemical Society
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    • v.9 no.5
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    • pp.292-295
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    • 1988
  • Macrocyclic ligands have been studies as cation carriers in a bulk liquid membrane system. $Cu^{2+}$ has been transported using nitrogen substituted macrocycles as carriers and several transition metal ions($M^{n+}\;=\;Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cd^{2+},\;Pb^{2+}\;and\;Ag^{+}$) have been transported using $DBN_3O_2,\;DBN_2O_2,\;Me_6N_414C4$ and DA18C6 as carriers in a bulk liquid membrane system. Competitive $Cu^{2+}-M2^+$ transport studies have also been carried out for the same system. In single cation transport experiments, the best macrocyclic ligand for transport is a ligand that gives a moderately stable rather than very stable complex in the extraction. However, when both cations are present in the source phase, the cation which forms the most stable complex with carrier is favored in transport over other cations. Generally, the nitrogen substiituted macrocycles transport $Cu^{2+}$ selectively over $Mn^+$. Ligand structure, equilibrium constant (or stability constant) for complex formation, source phase pH and carrier concentration are also important parameters in transport experiments.

Neutronic design of pulsed neutron facility (PNF) for PGNAA studies of biological samples

  • Oh, Kyuhak
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.262-268
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    • 2022
  • This paper introduces a novel concept of the pulsed neutron facility (PNF) for maximizing the production of the thermal neutrons and its application to medical use based on prompt gamma neutron activation analysis (PGNAA) using Monte Carlo simulations. The PNF consists of a compact D-T neutron generator, a graphite pile, and a detection system using Cadmium telluride (CdTe) detector arrays. The configuration of fuel pins in the graphite monolith and the design and materials for the moderating layer were studied to optimize the thermal neutron yields. Biological samples - normal and cancerous breast tissues - including chlorine, a trace element, were used to investigate the sensitivity of the characteristic γ-rays by neutron-trace material interactions and the detector responses of multiple particles. Around 90 % of neutrons emitted from a deuterium-tritium (D-T) neutron generator thermalized as they passed through the graphite stockpile. The thermal neutrons captured the chlorines in the samples, then the characteristic γ-rays with specific energy levels of 6.12, 7.80 and 8.58 MeV were emitted. Since the concentration of chlorine in the cancerous tissue is twice that in the normal tissue, the count ratio of the characteristic g-rays of the cancerous tissue over the normal tissue is approximately 2.

Characterization of neutron spectra for NAA irradiation holes in H-LPRR through Monte Carlo simulation

  • Kyung-O Kim;Gyuhong Roh;Byungchul Lee
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4226-4230
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    • 2022
  • The Korea Atomic Energy Research Institute (KAERI) has designed a Hybrid-Low Power Research Reactor (H-LPRR) which can be used for critical assembly and conventional research reactor as well. It is an open tank-in-pool type research reactor (Thermal Power: 50 kWth) of which the most important applications are Neutron Activation Analysis (NAA), Radioisotope (RI) production, education and training. There are eight irradiation holes on the edge of the reactor core: IR (6 holes for RI production) and NA (2 holes for NAA) holes. In order to quantify the elemental concentration in target samples through the Instrumental Neutron Activation Analysis (INAA), it is necessary to measure neutron spectrum parameters such as thermal neutron flux, the deviation from the ideal 1/E epithermal neutron flux distribution (α), and the thermal-to-epithermal neutron flux ratio (f) for the irradiation holes. In this study, the MCNP6.1 code and FORTRAN 90 language are applied to determine the parameters for the two irradiation holes (NA-SW and NA-NW) in H-LPRR, and in particular its α and f parameters are compared to values of other research reactors. The results confirmed that the neutron irradiation holes in H-LPRR are designed to be sufficiently applied to neutron activation analysis, and its performance is comparable to that of foreign research reactors including the TRIGA MARK II.