• Title/Summary/Keyword: Cd concentration

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Removal of Heavy Metals from Acid Mine Drainage Using Sulfate Reducing Bacteria (황산염환원균을 이용한 폐광폐수의 중금속 제거)

  • Paik, Byeong Cheon;Kim, Kwang Bok
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.2
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    • pp.47-54
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    • 1999
  • SRB(Sulfate Reducing Bacteria) converts sulfate into sulfide using an organic carbon source as the electron donor. The sulfide formed precipitates the various metals present in the AMD (Acid Mine Drainage). This study is the fundamental research on heavy metal removal from AMD using SRB. Two completely mixed anaerobic reactors were operated for cultivation of SRB at the temperature of $30^{\circ}C$ and anaerobic batch reactors were used to evaluate the effects of carbon source, COD/sulfate($SO_4^=$) ratio and alkalinity on sulfate reduction rate and heavy metal removal efficiency. AMD used in this study was characterized by low pH 3.0 and 1000mg/l of sulfate and dissolved high concentration of heavy metals such as iron, cadmium, copper, zinc and lead. It was found that glucose was an organic carbon source better than acetate as the electron donor of SRB for sulfate reduction in AMD. Amount of sulfate reduction maximized at the COD(glucose)/sulfate ratio of 0.5 in the influent and then removal efficiencies of heavy metals were 97.5% of Cu, 100% of Pb, 100% of Cr, 49% of Mn, 98% of Zn, 100% Cd and 92.4% of Fe. Although sulfate reduction results in an increase in the alkalinity of the reactor, alkalinity of 1000mg/1 (as $CaCo_3$) should be should be added continuously to the anaerobic reactor in order to remove heavy metals from AMD.

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The Study on the Concentrations of Lead and Cadmium in of the Inhabitants of Jeon-Ju Indurstrial Area (전주공업단지 주변 주민들의 모발내 Pb 및 Cd함량에 관한 연구)

  • 이종섭;유일수;이기남
    • Journal of Environmental Health Sciences
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    • v.14 no.2
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    • pp.89-96
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    • 1988
  • This study was carried out to evaluate the concentrations of heavy metal in hair of the inhabitants of Jeon-Ju industrial area. The major findings of this study are as follows 1. The average content of lead in hair of the inhabitants of Jeon-Ju industrial area was 15.06$\pm$ 4.06 ppm and the content of lead of driver's hair showed higher than that of house wives and students, and showed significance statistically ( P < 0.05). 2. The average content of cadmium by occupation in hair of inhabitants of Jeon-Ju industrial area was 0.76$\pm$ 0.21 ~ 0.52$\pm$ 0.16 ppm and the cadmium concentration in hair of driver's showed the highest level among occupations and showed significance statistically (P < 0.05). 3. Lead and cadmium contents in the hair of the inhabitants of Jeon-Ju industrial area showed higher than that of control area residents and showed significance statistically ( P < 0.05 ). 4. The contents between lead and codmium in hair of Jeon-Ju industrial area residents revealed high degree of correlation ( r = 0.7938).

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Microbiological Characteristics of Heavy Metal Ion-Tolerant Microorganisms. (중금속 내성균주의 미생물학적 성질)

  • 유대식
    • Microbiology and Biotechnology Letters
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    • v.7 no.4
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    • pp.183-190
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    • 1979
  • Cadmium ion-tolerant microorganisms were isolated from the sludge and soil of a cadmium ion-polluted area, a zinc mineralized area, in Kyung Sang Pook Do, Korea. A strain, C-7, which showed tile highest tolerance to cadmium ion was selected by screening from 18 cadmium tolerant microorganisms. By the taxonomical characteristics of this strain, it was identified as a variant of Erwinia sp.. The strain grew in a medium cadmium ion up to a concentration of 2, 800 $\mu\textrm{g}$/ml and the maximum intercellular accumulation of Cd$^{2+}$ was measured to be 28.60 mg/g dried cells (57.2%) during incubation in medium containing 50 $\mu\textrm{g}$/ml under aerobic condition at 28$^{\circ}C$ for 24 hour.r.

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Ecological study on effects of heavy metal accumulation on pillbugs (토양 내 서식하는 공벌레의 중금속 축적에 따른 생태적 연구)

  • Lee, Sang-Don
    • Journal of Environmental Impact Assessment
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    • v.20 no.5
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    • pp.675-684
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    • 2011
  • In nature, the overall effect of heavy metals on the biota can be influenced by a number of environmental factors like soil characteristics and air pollution by elevated $CO_2$. Pillbugs (Isopoda, Armadillium vulgare) take up heavy metals with their food and store them mainly in the vesicles of hepatopancreas. They accumulate certain metals, occur in relatively large numbers, are easily collected and identified, and provide sufficient material for analysis. The species are decomposing litter well and soil impurities into N and P. Therefore, it has been suggested that total body concentration of metals in pillbugs could be positively correlated to the levels of environmental exposure and that pillbugs could be used as biological indicators of metal pollution and global change by $CO_2$. The aim of the study is to determine effects of heavy metal concentrations in soil and elevated $CO_2$ on pillbugs' body accumulation of heavy metal and growth rate. In this study, the concentrations of six metals (Fe, Mg Cu, Zn, Pb, Cd) have been determined. Pillbugs (N=287) were collected at five sites during Jul-Aug, 2006. Cu and Zn concentrations in the body were much higher than in the soils(1.39-41.70 times). This indicated that bioaccumulation of some of the heavy metals were increasing in the food-chain. The high bioconcentration of lead in Sangam may be partly associated with reclaimed land uses.

Data intercomparison and determination of toxic and trace elements in Algae using Instrumental Neutron Activation Analysis (중성자방사화분석에 의한 Algae중의 독성미량원소의 정량 및 실험실간 비교검증)

  • Chung, Yong-Sam;Moon, Jong-Hwa;Park, Kwang-Won;Lee, KiI-Yong;Yoon, Yoon-Yeol
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.346-353
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    • 1999
  • For the non-destructive multi-elemental analysis of environmental and biological materials, instrumental neutron activation analysis (INAA) was applied for the determination of toxic and trace elements in a set of three Algae samples provided by the International Atomic Energy Agency (IAEA). The analytical quality control was evaluated by comparing the analytical results of two standard reference materials of the National Institute of Standards and Technology (NIST); Oyster Tissue (SRM 1566a) and Citrus Leaves (SRM 1572). According to given analytical procedure, the concentration of 15-25 elements including spiked elements such as As, Cd, Cr and Hg in Algae samples were determined. To identify and validate these results, a data intercomparison program using more than 35 analytical methods in 150 laboratories was carried out and the estimated statistical data are summarized. Result of INAA is favorable, therefore, it is illustrated that can be applied for routine analysis of essential and toxic elements in algae samples as well as analytical quality assurance.

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A Case Study of Health Impact Assessment on Incinerator Construction Project - Human Risk Assessment due to Inhalation Exposure to Heavy Metals - (소각로 건설사업에 대한 건강영향평가 사례연구 - 중금속 흡입에 따른 인체 위해성 평가 -)

  • Kim, Youngha;Choi, Sangki;Lee, Youngsoo
    • Journal of Environmental Impact Assessment
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    • v.18 no.1
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    • pp.11-19
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    • 2009
  • We conducted human risk assessment due to inhalation exposure to heavy metals emitted from incinerator. The process of health impact assessment(HIA) on incinerator is as follows: The first step is to presume and calculate the amount of heavy metals emitted using emission factor. The second step is to conduct an exposure assessment using the K-SCREEN model which is used for predicting the concentration in a conservative method. The last step is to carry out a risk assessment on carcinogenic and non-carcinogenic substances. This study revealed that rank of carcinogenic human risk was $Cr^{+6}$ > As > Ni > Cd, and values of human risk assessment on carcinogenic and non-carcinogenic substances is lower than the US criteria for risk assessment except $Cr^{+6}$. It is expected that the technique of HIA, especially human risk assessment on heavy metals, would be applied to the incinerator construction project. In addition, more systematic studies are needed to overcome some weak points and limits found in this study.

Separation of Th(IV) and U(VI) Using Arsenazo I-XAD-16 Chelating Resin (Arsenazo I-XAD-16 킬레이트 수지를 이용한 Th(IV)과 U(VI)의 분리)

  • Suh, Jung-Min;Kim, Min-Kyun;Lim, Jae-Hee;Lee, Chang-Hun;Lee, Won
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.397-404
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    • 1995
  • Three Arsenazo I-XAD Chelating resins, with different surface areas and pore sizes were synthesized and characterized. The total sorption capacities of these chelating resins for Cu(II) at pH 5.0 by batch method decreased as follows, Arsenazo I-XAD-16(0.59mmol/g)>Arsenazo I-XAD-4(0.56mmol/g)>Arsenazo I-XAD-2(0.38mmol/g). The sorption and desorption properties of Arsenazo I-XAD-16 chelating resins for U(VI), Th(IV), Hf(IV), Zr(IV), Ni(II), Mn(II), Cd(II). and Cu(II) were studied by both batch and elution method. The Arsenazo I-XAD-16 chelating resin was successfully applied to the separation and concentration of trace U(VI) and Th(IV) in sea and waste waters.

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Solution-Processed Anti Reflective Transparent Conducting Electrode for Cu(In,Ga)Se2 Thin Film Solar Cells (CIGS 박막태양전지를 위한 반사방지특성을 가진 용액공정 투명전극)

  • Park, Sewoong;Park, Taejun;Lee, Sangyeob;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.131-135
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    • 2020
  • Silver nanowire (AgNW) networks have been adopted as a front electrode in Cu(In,Ga)Se2 (CIGS) thin film solar cells due to their low cost and compatibility with the solution process. When an AgNW network is applied to a CIGS thin film solar cell, reflection loss can increase because the CdS layer, with a relatively high refractive index (n ~ 2.5 at 550 nm), is exposed to air. To resolve the issue, we apply solution-processed ZnO nanorods to the AgNW network as an anti-reflective coating. To obtain high performance of the optical and electrical properties of the ZnO nanorod and AgNW network composite, we optimize the process parameters - the spin coating of AgNWs and the concentration of zinc nitrate and hexamethylene tetramine (HMT - to fabricate ZnO nanorods. We verify that 10 mM of zinc nitrate and HMT show the lowest reflectance and 10% cell efficiency increase when applied to CIGS thin film solar cells.

Removal of Heavy Metal in Wastewater with Coffee Grounds (커피 찌꺼기를 이용한 폐수중의 중금속 제거)

  • Shin, Hyun-Gon;Kim, Choong-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.2
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    • pp.44-49
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    • 2014
  • In order to remove the heavy metals from synthetic wastewater containing Pb, Cr, and Cd, the experiment was conducted with a variety of concentration and pH by using the washed and dried coffee grounds as adsorbent. Almost of the heavy metals were removed in thirty minutes and the removal efficiency was maximized to the 80 percents following the different pH conditions. Furthermore, in the case of Cr, the removal efficiency was declined with the increasing of pH. As a result of this study, coffee grounds is proved to be a very good adsorbent to remove the heavy metals.

Carcinogenic risk assessment of heavy metals in suspended particulates of Seoul (서울시 대기 부유 분진중 중금속에 대한 발암 위해성 평가)

  • Shin, Dong-Chun;Chung, Yong;Kim, Jong-Man;Lim, Young-Wook
    • Journal of Korean Society for Atmospheric Environment
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    • v.10 no.2
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    • pp.105-115
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    • 1994
  • This study was conducted to assess the health risk of carcinogenic heavy metals such as arsenic, nickel, chromium and cadmium Ambient concentrations of these metals were measured bimonthly, during May 1987 to March 1988. Respirable Particle concentrations of As, Ni, Cr, Cd in traffic area(Shinchon) were 16ng/㎥, 43ng/㎥, 4.2ng/㎥, 6.6ng/㎥, respectively, and in residential area(Bulkwang) were 25ng/㎥, 32ng/㎥, 4.7ng/㎥, 8.9ng/㎥, respectively. Carcinogenic risk of each metal was calculated by multiplication of ambient concentration and unit risk of the metal which was referred to recent version of Integrated Risk Information System(IRIS). Sum of the risk from these for metals was 9.8$\times$10$^{-5}$ as individual risk in traffic area and 13.9$\times$10$^{-5}$ in residential area.

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