• Bulletin of the Korean Chemical Society
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• 제35권4호
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• pp.1029-1035
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• 2014

The protolytic dissociation process of hydrochloric acid (HCl) and hydrofluoric acid (HF) is studied using the B3LYP and MP2 methods with the 6-311+G(d,p) basis set in the gas phase and in aqueous solution. To study the phenomena in detail, discrete and discrete/continuum models were applied by placing water molecules in various positions around the acid. The dissociation process was studied using the thermodynamic cycle involving the structures optimized both in the gas phase and in aqueous solution and was analyzed with two key energy factors, relaxation free energy (${\Delta}G_{Rex(g)}$) and solvation free energy (${\Delta}G_s$). Based on the results, we could understand the dissociation mechanism and wish to propose the best way to study acid dissociation process using the CPCM methodology in aqueous solution.

• 자연, 터널 그리고 지하공간
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• 제1권2호
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• pp.59-71
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• 1999

Recently, many deformations in tunnel such as crack and leakage were occulted. Specially, the defects of tunnel lining have been a serious problem in safety and stability many repair works for maintenance in tunnel have been carried out. Therefore, it is necessary to estimate the structural cracking for countermeasure in deformed tunnel and to investigate on the characteristics of lining system and the soundness of tunnel. In this study model tests for tunnel lining were carried out using test apparatus and centrifuge, In the direct loading test, the prototype was Kyungbu high-speed railway tunnel and the scale is 1/10, and lining models were made of concrete. Test conditions included load conditions such as direction, shape and type, lining conditions such as single and double lining, thickness, and reinforcement. In centrifuge model test, the prototype was Seoul subway tunnel and the scale is 1/100, and lining models were made of aluminum and hydrostone. Test conditions included tunnel defects such as thickness shortage. behind cavity and longitudinal cracks, reinforcement methods such as epoxy, grouting and carbon sheet. From these model tests , the characteristics of deformation and failure for tunnel lining were estimated, and the structural behaviors of deformed lining and the effects of repair and reinforcement for tunnel lining were researched.

• 한국CDE학회논문집
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• 제6권1호
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• pp.9-16
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• 2001

Electrical discharge machining(EDM) is an important process of machining the injection mold. This paper includes efficient design processes of electrodes for EDM. Based on the solid modeler, electrodes can be created by boolean and offset operations with core/cavity models. The built-in offset operations of the solid modeler may occur unexpected results due to the limitations of the solid modeler. We proposed the multi-step and moving-face offset processes in order to apply the EDM clearances. The proposed design processes are implemented with Unigraphics Vl5 API functions and C language and tested on Windows NT 4.0.

• 천문학회보
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• 제38권2호
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• pp.67.2-67.2
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• 2013

Part of mid-J CO emission detected by the Herschel/PACS observations of embedded young stellar objects (YSOs) has been attributed to the UV-heated outflow walls. We have applied our newly developed self-consistent models of Photon Dominated Region (PDR) and Non-LTE line Radiative transfer In general Grid (RIG) to the Herschel FIR CO observations. If the black body radiation of T = 15,000 K is used, the observed mid-J CO line fluxes can be produced in inner dense regions (n ${\geq}$ 106 cm-3) with -4.5 ${\leq}$ log Gdust/n ${\leq}$ -2.5, where gas temperatures are larger than 300 K and CO abundances are ${\geq}$ 10-5, along the UV-heated outflow walls. The contribution of the UV heated outflow cavity wall in Class I seems to be larger than that in Class 0.

• 소성∙가공
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• 제7권1호
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• pp.3-11
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• 1998

During the forming process of sheet metals, the drawbead in the die face controls a restraining force so that the sheet flows into the die cavity with tension. In order to investigate a drawgbead restraining force and a pre-strain just after drawbeads which are essential in the finite element analysis of form-ing processes, the friction test and drawing test are employed. The experiments performed with a cir-cular bead stepped bead double circular bead and circular-and-stepped bead in the various forming conditions and bead sizes show that the restraining force varies linearly with the blank holding force. bead radius blank thickness and friction but the pre-strain nonlinearly does with them.

• 한국전산유체공학회지
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• 제3권1호
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• pp.22-29
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• 1998

Parallel implementation is conducted for a SIMPLER finite volume model. The present parallelism is based on domain decomposition and explicit message passing using MPI and SHMEM. Two parallel solvers to tridiagonal matrix equation are employed. The implementation is verified on the Cray T3E system for a benchmark problem of natural convection in a sidewall-heated cavity. The test results illustrate good scalability of the present parallel models. Performance issues are elaborated in view of convergence as well as conventional parallel overheads and single processor performance. The effectiveness of a localized matrix solution algorithm is demonstrated.

• Advances in aircraft and spacecraft science
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• 제2권1호
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• pp.77-94
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• 2015

The paper focuses on the integration of a non-linear one-dimensional model of Synthetic Jet (SJ) actuator in a well-assessed numerical simulation method for turbulent compressible flows. The computational approach is intended to the implementation of a numerical tool suited for flow control simulations with affordable CPU resources. A strong compromise is sought between the use of boundary conditions or zero-dimensional models and the full simulation of the actuator cavity, in view of long-term simulation with multiple synthetic jet actuators. The model is integrated in a multi-domain numerical procedure where the controlled flow field is simulated by a standard CFD method for compressible RANS equations, while flow inside the actuator is reduced to a one-dimensional duct flow with a moving piston. The non-linear matching between the two systems, which ensures conservation of the mass, momentum and energy is explained. The numerical method is successfully tested against three typical test cases: the jet in quiescent air, the SJ in cross flow and the flow control on the NACA0015 airfoil.

• Interaction and multiscale mechanics
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• 제1권1호
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• pp.83-101
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• 2008

A derivation is given of two-scale models that are able to describe deformation and flow in a fluid-saturated and progressively fracturing porous medium. From the micromechanics of the flow in the cavity, identities are derived that couple the local momentum and the mass balances to the governing equations for a fluid-saturated porous medium, which are assumed to hold on the macroscopic scale. By exploiting the partition-of-unity property of the finite element shape functions, the position and direction of the fractures are independent from the underlying discretization. The finite element equations are derived for this two-scale approach and integrated over time. The resulting discrete equations are nonlinear due to the cohesive crack model and the nonlinearity of the coupling terms. A consistent linearization is given for use within a Newton-Raphson iterative procedure. Finally, examples are given to show the versatility and the efficiency of the approach.

• Wind and Structures
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• 제5권2_3_4호
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• pp.317-328
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• 2002

A numerical investigation on the turbulent flows over a three-dimensional steep hill is presented. The numerical model developed for the present work is based on the finite volume method and the SIMPLE algorithm with a non-staggered grid system. Standard $k-{\varepsilon}$ model and Shih's non-linear model are tested for the validation of the prediction accuracy in the 3D separated flow. Comparisons of the mean velocity and turbulence profiles between the numerical predictions and the measurements show good agreement. The Shih's non-linear model is found to predict mean flow and turbulence better than the Standard $k-{\varepsilon}$. Flow patterns have also been examined to explain the difference in the cavity zone between 2D and 3D hills.

• International Journal of Fluid Machinery and Systems
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• 제10권3호
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• pp.197-208
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• 2017

When Francis turbines operate at partial load, residual swirl in the draft tube causes low-frequency pulsation of pressure and power output. Scale effects and system response may bias the prediction of prototype behavior based on laboratory tests, but could be overcome by means of a 1D analytical model. This paper deals with the two most important features of such a model, the compliance and the source of excitation. In a distributed-parameter version, compliance should be represented as an exponential function of local pressure. Lack of similarity due to different Froude number can thus be compensated. The normally unknown gas content in the vortex cavity has significant influence on the pulsation, and should therefore be measured and considered as a test parameter.