• Title/Summary/Keyword: Caustic

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The Clinical Characteristics and Risk Factors of Upper Digestive Lesions that are due to Ingestion of Caustic Material (부식제에 의한 상부 위장관 손상의 임상양상과 위험인자)

  • Kim, Young-Sin;Choi, Se-Min;Kim, Hyung-Min;Youn, Chun-Song;Park, Kyu-Nam
    • Journal of The Korean Society of Clinical Toxicology
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    • v.7 no.2
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    • pp.113-120
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    • 2009
  • Purpose: Though caustic injury of the upper digestive tract can lead to severe sequelae, there are few clinical studies on this subject. This study was undertaken to evaluate the clinical characteristics, the endoscopic findings and the risk factors of the upper digestive lesions in patient with caustic ingestion injury. Methods: We retrospectively reviewed the medical records of 137 patients who ingested caustic materials and who visited to our emergency room from January, 2000 to June, 2009. Results: The most common ingested agent was sodium hypochlorite (44.5%), followed by acetic acid (19.7%), hydrochloric acid (11.7%) and lye (8.0%). Ingestion for suicidal attempt (62.0%) was more frequent than accidental ingestion (30.7%). Grade IIa injury was the most frequent finding on endoscopy of the esophagus and Grade 1 injury was the most frequent finding on endoscopy of the stomach. For the late sequelae, there were 9 cases (6.6%) of esophageal stricture and 2 cases (1.5%) of gastric outlet obstruction. The initial signs and symptoms did not correlate with the development of stricture, but leukocytosis, and grade III injury were related to the risk of developing stricture. Conclusion: Caustic injury of the upper gastrointestinal tract is frequently observed on early endoscopy and it can cause significant late sequelae such as stricture. Therefore, it is necessary to evaluate these patients with regular follow up endoscopic examinations for the management of late sequelae.

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Study on Autotrophic Denitrification by the Injection of Spent Sulfidic Caustic in a Hybrid Bardenpho Process (Hybrid Bardenpho 공정에서 Spent Sulfidic Caustic의 주입을 통한 독립영양 탈질에 관한 연구)

  • Lee, Jae-Ho;Park, So-Ra;Park, Jeung-Jin;Byun, Im-Gyu;Park, Tae-Joo
    • Journal of Korean Society on Water Environment
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    • v.24 no.5
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    • pp.563-568
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    • 2008
  • In petroleum refining industry, caustic (NaOH) solution is used to remove $H_2S$ from hydrocarbon streams in naphtha cracking process. Once $H_2S$ is absorbed in caustic solution, the solution becomes known as spent sulfidic caustic (SSC), which contains high concentrations of hydrogen sulfide and alkalinity. This study was focused on the evaluation of autotrophic denitrification by SSC in a hybrid Bardenpho process. SSC was injected to the anoxic (1) and anoxic (2) tank at different S/N ratio. In a previous lab-scale study, as we operated a modified Ludzack-Ettinger process, it was observed that the COD increment of effluent and nitrification failure happened because of non-biodegradable matters in SSC and high pH, respectively. Thus cilia media was packed at 2.4%(v/v) in all aerobic tanks and the pH of SSC was neutralized from 13.3 to 11.5 with addition of sulphuric acid ($H_2SO_4$). Consequently, these strategies were successful because no COD increment of effluent was observed and nitrification failure did not happen. The maximum TN removal efficiency was 77.5% when SSC was injected to both the anoxic (1) and anoxic (2) tanks. The mean TN concentration of effluent in this condition was 5.8 mg/L.

Intercontinental comparison of caustic ingestion in children

  • Rafeey, Mandana;Ghojazadeh, Morteza;Mehdizadeh, Amir;Hazrati, Hakimeh;Vahedi, Leila
    • Clinical and Experimental Pediatrics
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    • v.58 no.12
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    • pp.491-500
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    • 2015
  • Purpose: To investigate the caustic ingestion in children among different continents according to demographic characteristics (core purpose), main symptoms, common caustic agents, signs and symptoms, management, treatment and complications. Methods: This systematic review was performed by searching the databases Science Direct, ProQuest, Google Scholar, and PubMed, electronically and manually. We included studies that were published from 1980 to 2013, at University of Medical Sciences of Tabriz, Iran. A strategic search was performed with keywords including caustic, corrosive, ingestion and children, and was limited to articles in English and Persian. Statistical analysis was performed by SPSS ver. 18. Results: Of 63 selected articles of caustic ingestion with 9,888 samples, the proportion of Africa was 3 articles (4.8%) and 95 samples (1%), America 9 articles (14.3%) and 305 sample (3%), Asia 29 articles (46%) and 2,780 samples (28.1%), Europe 17 articles (27%) and 3,002 samples (30.4%), and Oceania 5 articles (7.9%) and 3,706 samples (37.5%). The average age was in the Africa $3.07{\pm}2.02years$, America $3.17{\pm}1.83years$, Asia $3.34{\pm}1.58years$, Europe $3.58{\pm}2.09years$ and Oceania $3.52{\pm}2.02years$. Sex distribution was in Africa 76 males (0.91%) and 19 females (0.23%), America 49 males (0.58%) and 41 females (0.49%), Asia 1,575 males (18.76%) and 1,087 females (12.95%), Europe 1,018 males (12.13%) and 823 females (9.8%), and Oceania 1,918 males (22.85%) and 1,788 females (21.3%). Statistical analysis of the data indicated higher consumption in Europe and Oceania in the boys with higher average age of years. Conclusion: The comparison of caustic ingestion indicated that the cause substances of caustic ingestion in children are different among continents, therefore prevention strategy and different treatment guidelines among continents will be needed.

Recovery of Caustic Soda in Textile Mercerization by Combined Membrane Filtration (복합 막분리 공정에 의한 섬유가공 공정에서의 가성소다 회수)

  • Yang, Jeong-Mok;Park, Chul-Hwan;Cho, Jin-Ku;Kim, Sang-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1273-1280
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    • 2008
  • This study sought to establish the optimum operating condition for the recovery of caustic (NaOH) solution from mercerization in textile process. As main factors, the silt density index (SDI) evaluation of ceramic membrane for the application of nanofiltration/reverse osmosis (NF/RO) membrane, the recovery yield measurement of caustic solution for the application of polymeric membrane, the optimum condition of chemical cleaning for the membrane regeneration, the optimum removal condition of total organic carbon (TOC), turbidity, color, and the permeate flux of ceramic membrane/polymeric membrane combined process were investigated. As results, ceramic ultrafiltration (UF) in the first step and nanofiltration (NF) in the second step were found to be suitable for the removal of total suspended solid (TSS), residual organics, turbidity including color, and the recovery of caustic solution from caustic wastewater stream in mercerization process. When only the ceramic UF membrane was used, the rejection efficiency of both of TSS and turbidity was more than 99.0%, and the color and TOC were rejected about 74.7% and 49.2%, respectively. Meanwhile, the combined membrane precess of UF and NF membranes showed even more efficient removal abilities and thus more than 99.9% of TSS and turbidity, 87.7% of color, and 78.2% of TOC were removed. In particular, 91.3% of NaOH was successfully recovered with 83.7% of total volume in the combined membrane process. With this regard, a clean caustic solution was obtained in a high purity, which can be reused for mercerization process, expecting to offer economical benefits.

The Physical Property of the Structural Color Yarn and Fabric for Emotional Garment Using Biomimetic Technology (생체모방기술을 응용한 감성의류용 구조발색사와 직물의 물성)

  • Kim, Hyun-Ah;Kim, Seung-Jin
    • Science of Emotion and Sensibility
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    • v.15 no.1
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    • pp.141-148
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    • 2012
  • This study investigated the structural coloration and fabric hand of the caustic reduced fabrics for emotional garment using structural color yarns, which was spun by 37 alternating nylon and polyester layers capable of producing basic colors using biomimetic technology. The colorations of the three kinds of structural color yarns were confirmed using multi angle spectro-photometer, and their triangular cross sections composed with 37 alternating nylon and polyester layers were measured using SEM and were discussed with layer length in relation with coloration and spinning conditions were also set up. The apparent color difference and reflectance of the three kinds of fabrics with different density and weave pattern were analysed as ranging from 400nm to 700nm. The optimum fabric structural design which is made by warp and weft densities(194ends/in ${\times}$ 105picks/in) and caustic reduction condition by $100^{\circ}C$ temperature and 60minutes with NaOH, 20g/l solution were decided through analysis of the mechanical properties and fabric hands of these three kinds of fabrics treated with 3 kinds of the caustic reduction conditions. And it was shown that the rate of caustic reduction was increased from 13% to 23% with increasing temperature and time of caustic reduction. The extensibility, bending rigidity and shear modulus of caustic reduction treated fabrics were decreased by treatment of caustic reduction, on the other hand fabric compressibility was increased. And it was shown that the hand value of specimen number one which was treated with temperature $100^{\circ}C$ and time 60minute was the best and the hand of this fabric was better than that of Morpho $fabric^{(R)}$ made by Teijin co. Japan.

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PLANETARY CAUSTIC PERTURBATIONS OF A CLOSE-SEPARATION PLANET ON MICROLENSING

  • Ryu, Yoon-Hyun;Kim, Han-Seek;Chung, Sun-Ju;Kim, Dong-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.77.1-77.1
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    • 2016
  • We investigate the properties and detection conditions for the planetary caustic perturbation of close-separation planets. To find the properties of the planetary caustic perturbation, we construct deviation maps by subtracting the single-lensing magnification of the lens star from the planetary lensing magnification for various lensing parameters. We find that each deviation area of the positive and negative perturbations disappears at the same normalized source radius according to a given deviation threshold regardless of mass ratio but disappears at a different normalized source radius according to the separation. We also estimate the upper limit of the normalized source radius to detect the planetary caustic perturbation. We find simple relations between the upper limit of the normalized source radius and the lensing parameters. From the relations, we obtain an analytic condition for the detection limit of the planet, and which show that we can sufficiently discover a planet with the mass of sub-Earth for typical microlensing events. Therefore, we expect to add the number of low-mass planets in the next-generation microlensing experiments and conclude that our detection condition of the planet can be used as a important criteria for maximal planet detections considering the source type and the photometric accuracy.

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A planetary lensing feature in caustic-crossing high-magnification microlensing events

  • Chung, Sun-Ju;Hwang, Kyu-Ha;Ryu, Yoon-Hyun;Lee, Chung-Uk
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.2
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    • pp.109.2-109.2
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    • 2012
  • Current microlensing follow-up observations focus on high-magnification events because of the high efficiency of planet detection. However, central perturbations of high-magnification events caused by a planet can also be produced by a very close or a very wide binary companion, and the two kinds of central perturbations are not generally distinguished without time consuming detailed modeling (a planet-binary degeneracy). Hence, it is important to resolve the planet-binary degeneracy that occurs in high-magnification events. In this paper, we investigate caustic-crossing high-magnification events caused by a planet and a wide binary companion. From this study, we find that because of the different magnification excess patterns inside the central caustics induced by the planet and the binary companion, the light curves of the caustic-crossing planetary-lensing events exhibit a feature that is discriminated from those of the caustic-crossing binary-lensing events, and the feature can be used to immediately distinguish between the planetary and binary companions.

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A Case of Pyloric Obstruction Developed after Upper GI Barium Study in Patients with Caustic Injury on Gastrointestinal Tract (부식제에 의한 위장관 손상 환자에서 상부 위장관 조영술 후 발생한 위유문부 폐쇄 1례)

  • Kim, Jeong-Goo;Cho, Hye-Jin;Lee, Seung-Hee;Kim, Pum-Soo;Roh, Hyung-Keun
    • Journal of The Korean Society of Clinical Toxicology
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    • v.1 no.1
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    • pp.51-55
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    • 2003
  • Caustic ingestion can produce a progressive and devastating injury to the esophagus and stomach, In the acute stage, perforation and necrosis may occur. Long-term complications include esophageal stricture, antral stenosis and the development of esophageal cancer. Endoscopy should be performed as soon as possible in all cases to evaluate the extent and severity of damage, unless there is evidence of perforation. Endoscopy is the diagnostic procedure of choice. However, when the endoscopy cannot be passed through due to esophageal stricture, upper GI barium studies may be useful as a follow-up measure and in the evaluation of complications. A 44-year-old man visited our hospital complaining frequent vomiting 1 hour after ingestion of unknown amount of hydrochloric acid. At the time of arrival, the patient's oral cavity was slightly swollen and erythematous. On the endoscopic examination fourteen hour after the caustic ingestion, marked swelling of the arytenoids and circumferential ulceration with brown and black pigmentation at the upper esophagus were observed. Four weeks after the caustic injury, upper esophageal narrowing was observed and then the scope could not be advanced to the stomach. Upper GI barium study performed at that time revealed diffuse luminal narrowing of the esophagus and concentric luminal narrowing from prepyloric antrum to pylorus with disturbance of barium passage. At a week after the Upper GI study, through endoscopic examination after bougie dilatation of the esophagus, barium impaction in the stomach and the pylorus was noticed.

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Study on the Optimization of Spent Sulfidic Caustic Applied for BNR Process (Spent Sulfidic Casutic의 BNR 공정 적용을 위한 최적화 연구)

  • Lee, Jae-Ho;Ju, Dong-Jin;Park, Jeung-Jin;Shin, Choon-Hwan
    • Journal of Environmental Science International
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    • v.20 no.12
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    • pp.1617-1624
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    • 2011
  • Caustic (NaOH) solution is used to remove $H_2S$ from hydrocarbon streams in petroleum refining industry, gradually being, so called, spent sulfidic caustic (SSC) which has high levels of $H_2S$ and alkalinity. Thus, SSC can be used as an electron donor and a buffering agent for autotrophic denitrification. As SSC, however, contains some non-biodegradable organics, air stripping was conducted to remove the non-biodegradable organics. As a result, over 93 % of the non-biodegradable organics was removed within 30 min of aeration. Then, $Na_2S_2O_3{\cdot}5H_2O$, methanol and organic matters, which are produced from a biodiesel production plant, were added to reform the air-stripped SSC and their products being referred to new sulfidic caustics (NSCs) I, II and III, respectively. Thereafter, to investigate the effect of these products on the removal of COD and TN, these products were injected to a biological nitrogen removal (BNR) process, resulting in additional 44 % TN removal without noticeable increase in the effluent COD level. Therefore, it can be said that the BNR process is a promising option to treat NSC as demonstrated in this study whose results can be useful for developing resource recovery technologies.

Influence of Blended Activators on the Physical Properties of Alkali-activated Slag Mortar (알칼리 활성화 슬래그 모르타르의 특성에 미치는 혼합 활성화제의 영향)

  • Kim, Tae Wan;Park, Hyun Jae;Seo, Ki Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.26-33
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    • 2012
  • This paper reported on the effect of blended activator on the physical properties of alkali-activated slag mortar. Five different activators(caustic alkalis) were used: sodium hydroxide(NaOH, A Case), calsium hydroxide($Ca(OH)_2$, B Case), magnesium hydroxide($Mg(OH)_2$, C Case), aluminum hydroxide($Al(OH)_3$, D Case), and potassium hydroxide(KOH, E Case). We blended five caustic alkalis with sodium carbonate($Na_2CO_3$). The dosage of five caustic alkalis was 3M and sodium carbonate was 1M, 2M and 3M. The result of flow and setting time was decrease as the dosage of sodium carbonate increase. But the compressive strength was increase as the dosage of sodium carbonate increase. It was shown that there is a good effect of blended caustic alkalis with sodium carbonate in alkali-activated slag mortar.