• Title/Summary/Keyword: Cation distribution

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A Study on the Correlation between Plant Community and Environmental Factors of Tongdosa(Temple) Area, Gajisan(Mt.) Provincial Park (가지산도립공원 통도사지구의 식물군락과 환경요인의 상관관계)

  • Lee, Sang-Cheol;Kang, Hyun-Mi;Kim, Ji-Suk;Yu, Chan-Yeol;Choi, Song-Hyun
    • Korean Journal of Environment and Ecology
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    • v.28 no.6
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    • pp.715-724
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    • 2014
  • Tongdosa, which is located in Gajisan(Mt.) Provincial Park of Yangsan City, is one of three representative temple in Korea. The purpose of this study was to investigate a relation between plants community and environmental factors in Tongdosa(Temple) District of Gajisan(Mt.) Provincial Park. In order to find out vegetation structure of Gajisan(Mt.) Provincial Park, thirty one plots(unit size: $200{\sim}300m^2$) were set up and surveyed. For environmental factors, it were surveyed and analyzed physical factors such as altitude, aspect etc. and soil characteristics such pH, organic content, total nitrogen content, exchangeable cation and so on. Using DCCA technique, a relation between plants community and environmental factors were analyzed. The surveyed plots were divided into five groups which are Pinus densiflora - Quercus aliena, Carpinus tschonoskii - Q. spp., P. densiflora - C. tschonoskii, P. densiflora - Q. variabilis, and Q. variabilis - Q. mongolica community. Vegetation succession was progressed from Pinus densiflora toward Carpinus tschonoskii and Quercus spp. It was found out that the distribution of vegetation was affected by altitude. Pinus densiflora - Quercus aliena community is located lower altitude and Q. variabilis - Q. mongolica community is located higher area.

The Study of Magnetic Structure of Ni1-xMgxFe2O4 Ferrite System by Mössbauer Spectroscopy (Mössbauer 분광법에 의한 Ni1-xMgxFe2O4 Ferrite의 자기구조 연구)

  • Yoon, In-Seop;Baek, Seung-Do
    • Journal of the Korean Magnetics Society
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    • v.19 no.3
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    • pp.106-112
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    • 2009
  • $Ni_{1-x}Mg_xFe_2O_4$ ferrite system was studied by using X-ray diffraction and $M{\ddot{o}}ssbauer$ spectroscopy. The samples were prepared by ceramic sintering method with Mg content x. The X-ray diffraction patterns of samples show phase of cubic spinel structure. There are no remarkable changes of lattice constants in $Ni_{1-x}Mg_xFe_2O_4$ ferrite system. The $M{\ddot{o}}ssbauer$ spectra were consisted of two sets of six lines, respectively, corresponding to $Fe^{3+}$ at tetrahedral and octahedral sites. The magnetic hyperfine field of samples was decreased as increasing Mg contents x in both sites and it was shown Yafet-Kittel magnetic structure. $NiFe_2O_4$ was shown complete inverse spinel, but $NiFe_2O_4$ was shown partial inverse spinel which absorption area ratio (oct/tet) was 1.449 in $M{\ddot{o}}ssbauer$ spectrum.

Mössbauer Study of Crystallographic and Magnetic Properties in Vanadium Ferrite(VxFe3-xO4) Thin Films (바나듐 페라이트 박막의 결정구조 및 자기적 성질에 관한 뫼스바우어 분광학적 연구)

  • Park, Jae-Yun;Kim, Kwang-Joo
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.19-23
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    • 2008
  • The mixed ferrite $V_xFe_{3-x}O_4$(x=0.0, 0.15, 0.5, 1.0) thin films were prepared by sol-gel method. Their crystallographic and magnetic hyperfine properties have been studied using X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS) and conversion electron $M\"{o}ssbauer$ spectroscopy(CEMS). The crystal structure is found to be cubic spinel throughout the series($x{\leq}1.0$), and the lattice parameter $a_0$ increases linearly with increasing V content. XRD, XSP and CEMS indicate that $V^{3+}$ substitution for $Fe^{3+}$ in B-site is superior to $V^{2+}$ substitution for $Fe^{2+}$ in B-site. It is noticeable that both quadrupole shift and hyperfine field decreases with increasing V composition, suggesting the change of local symmetry and accompanying line-broadening. The line-broadening on CEMS spectra can be explained by the distribution of magnetic hyperfine fields.

The Morphology and Physical and Chemical Characteristics of the Changpyeong Series Derived from Old Alluvium (홍적층(洪積層)에 기인(基因)된 적황색토(赤黃色土)의 형태(形態) 및 물리적(物理的) 화학적(化學的) 특성(特性)에 관(關)한 연구(硏究) - 창평통(昌平統)에 관(關)하여 -)

  • Shin, Y.H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.3 no.1
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    • pp.61-66
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    • 1970
  • This study examined the morphology and physical and chemical characteristics of the Changpyeong series developed on gently sloping to rolling relief on dissected old paddiplains and terraces. This soil has dark brown silty clay loam A horizons, very thick dark red to red silty clay or clay Bt horizons, and C horizons of old alluvial materials frequently with strongly weathered round cobbles and pebbles. It is strongly acid with a low organic matter content, relatively low in cation exchange capacity, but with relatively high base-status based on amount of extractable cations. There is no obvious changes in particle size distribution with depth and textural B horizons probably have not been formed by podzolization but formed by mechanical movement of clay. This soil is classified as Typic Hapludalfs in USDA 7th approximation and Brunic Luvisols in FAO classification system.

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Clay Mineral Composition of the Soils Derived from Residuum and Colluvium (잔적 및 붕적모재 토양의 점토광물 특성구명)

  • Zhang, Yong-Seon;Sonn, Yeon-Kyu;Jung, Sug-Jae;Lee, Gye-Jun;Kim, Myung-Sook;Kim, Sun-Kwan;Lee, Ju-Young;Pyun, In-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.5
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    • pp.245-252
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    • 2006
  • This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group

Distribution of Soil Fertility in Paddy Fields as Affected by Cultivation Methods and Topographical Regions (경작지대 및 재배방법에 따른 논토양의 비옥도 분포)

  • Kim, Dong-Jin;Kang, Da-Seul;Ahn, Byung-Koo;Lee, Jin-Ho
    • Korean Journal of Organic Agriculture
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    • v.23 no.3
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    • pp.595-604
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    • 2015
  • Soil chemical properties in paddy fields were found to be varied depending upon different cultivation methods such as environmentally-friendly, conventional, and two-crop farming systems and different topographical regions, namely plain, middle mountainous, and reclaimed land regions. Overall soil pH was found to be in optimal range (pH 5.5~6.5) for rice cultivation, except with conventional cultivation fields of the reclaimed lands in Jeonnam province. Electrical conductivity (EC) was relatively higher in the two-crop cultivation fields than in others. However, the concentrations of available phosphate as $P_2O_5$ were exceptionally higher in the two-crop farming fields, thus in submerged paddy condition the phosphate could be released into streams and rivers. Soil organic matter (SOM) contents were mostly in optimal range ($25{\sim}30g\;kg^{-1}$) for paddy field in Jeonbuk province, but in Jeonnam province they were slightly higher values of the range. The concentrations of available silicate ($SiO_2$) were mostly depended on the cultivation methods and the region, but some of paddy fields contained extremely high $SiO_2$ concentration. Statistical relationships among the soil chemical properties showed as follows: Correlations between EC values and exchangeable cation concentrations, between SOM contents and CEC values, and between available $SiO_2$ concentrations and pH, EC, exchangeable cations, and CEC values were positively significant, whereas total nitrogen concentrations were significantly negatively correlated with the concentrations of exchangeable K and Mg. These results might be very useful to establish benchmark paddy fields contained with certain levels of soil fertility.

Natural Dyeing of Rayon Fabric using Loess (황토를 이용한 인견직물의 천연염색)

  • Jung, Yang-Sook;Bae, Do-Gyu
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.3
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    • pp.193-199
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    • 2013
  • This study dyed rayon fabric using loess as a natural colorant. To obtain the optimal dyeing conditions, various dyeing conditions were examined (temperature, pH, time, and concentration). The color fastness was evaluated using standard washing and rubbing fastness tests. The results were as follows: The loess powder particle size ranged from 0.4 to $1.7{\mu}m$ with a distribution range of 1.1 to $1.4{\mu}m$, representing a fine and uniform manufactured loess powder. The loess component analysis showed a large amount of silicon dioxide and aluminum oxide. TheFT-IR spectra showed that the ammonium group in the rayon fabric produced N-H banding at $1,540cm^{-1}$. The highest K/S value for the rayon fabric was obtained when the pH was 8.0, and this value increased rapidly with a longer dyeing time and when increasing the loess concentration to 30% (w/v). Pre-treatment with a soybean solution produced the highest K/S value for the rayon fabric with a loess concentration of 30% (w/v). The SEM analysis showed a higher amount of loess adhered to the rayon fabric surface when increasing the loess concentration. However, pre-treatment with a cationic agent and soybean solution resulted in a much higher attachment of loess to the fabric surface. Thus, the experimental results showed that using a cationized fabric and pre-treatment with a soybean solution are more effective when dyeing rayon fabric with loess than when using only loess.

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Characteristics and Parameters for Adsorption of Carbol Fuchsin Dye by Coal-based Activated Carbon: Kinetic and Thermodynamic (석탄계 활성탄에 의한 Carbol Fuchsin의 흡착 특성과 파라미터: 동력학 및 열역학)

  • Lee, Jong Jib
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.283-289
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    • 2021
  • Adsorption characteristics of carbol fuchsin (CF) dye by coal-based activated carbon (CAC) were investigated using pH, initial concentration, temperature and contact time as adsorption variables. CF dissociates in water to have a cation, NH2+, which is bonded to the negatively charged surface of the activated carbon in the basic region by electrostatic attraction. Under the optimum condition of pH 11, 96.6% of the initial concentration was adsorbed. Isothermal adsorption behavior was analyzed using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich models. Langmuir's equation was the best fit for the experimental results. Therefore, the adsorption mechanism was expected to be adsorbed as a monolayer on the surface of activated carbon with a uniform energy distribution. From the evaluated Langmuir's dimensionless separation coefficients (RL = 0.503~0.672), it was found that CF can be effectively treated by activated carbon. The adsorption energies determined by Temkin and Dubinin-Radushkevich models were E = 15.31~7.12 J/mol and B = 0.223~0.365 kJ/mol, respectively. Therefore, the adsorption process was physical (E < 20 J/mol, B < 8 kJ/mol). The experimental result of adsorption kinetics fit better the pseudo second order model. In the adsorption reaction of CF dye to CAC, the negative free energy change increased as the temperature increased. It was found that the spontaneity also increased with increasing temperature. The positive enthalpy change (40.09 kJ/mol) indicated an endothermic reaction.

A Study on Analysis of Freshwater-saltwater Interface in the Aquifer around Hwajinpo Lagoon on the Eastern Coast of Korea (동해안 화진포 석호 주변 대수층 내 담수-염수 경계면 분석에 관한 연구)

  • Kim, Minji;Kim, Dongjin;Jun, Seong-Chun;Lee, Jeonghoon
    • Economic and Environmental Geology
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    • v.54 no.6
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    • pp.699-707
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    • 2021
  • Hwajinpo Lagoon, located on the eastern coast of Korea, is a unique environment where freshwater and saltwater are mixed. Systematic management of the lagoon is required because it is a biodiversity-rich and area of high conservation value. The existing environment of the lagoon was evaluated by identifying the distribution of the groundwater level and groundwater flow characteristics. In addition, hydrogeochemical fluctuations were analyzed to determine the effect of seawater intrusion into the aquifer. The results demonstrate that the freshwater-saltwater interface is distributed throughout the aquifer and rises when water of the lagoon evaporates due to prolonged periods of low rainfall and high temperature, thereby increasing the possibility of seawater inflow through groundwater. As for the ionic delta properties (difference between the measured and theoretical concentration of mixed waters), it was estimated that the cation-exchange and precipitation reactions occurred in the aquifer due to seawater intrusion. The ratio of seawater mixed at each point was calculated, using oxygen isotopes and chloride as tracers, resulting in an average of 0.3 and a maximum of 0.87. The overall seawater mixing ratio appears to be distributed according to the distance from the coast. However, some of the results were deviated from the theoretical expectations and reflected the characteristics of the nearby aquifers. Further research on seasonal changes and simulation of seawater intrusion mechanisms is required for specific analysis.

Genesis and Characteristics of the Soil Clay Minerals Derived from Major Parent Rocks in Korea II. Physical and Chemical Properties of the Whole Soils (한국(韓國)의 주요(主要) 모암(母岩)에서 발달(發達)된 토양점토광물(土壤粘土鑛物)의 특성(特性)과 생성학적(生成學的) 연구(硏究) II. 토양(土壤)의 이화학적(理化學的) 특성(特性))

  • Um, Myung-Ho;Kim, Tai-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.2
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    • pp.79-85
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    • 1991
  • This study reports on the physical and chemical properties of the whole soils (<2mm) derived from five major rocks of granite, granite-gneiss, limestone, shale, and basalt in Korea. The properties were considered from the kind and frequency distribution of rock-forming minerals in the parent rocks. In particle size distribution, sand fractions were high in the soils from granite-gneiss, silt fractions mainly, in the residual soils from limestone, shale, and basalt. And clay fractions were particularly high in the colluvial soil from limestone and the old alluvial soil from basalt. pH, extractable Ca and Mg, and cation exchange capacity of the soils derived from limestone might be considered to be high due to the presence of sand and/or silt-sized calcite and dolomite inherited from the parent rocks. However, the soils derived from granite and granite-gneiss, being abundant in feldspars, quartz, and micas, showed a tendency to the contrary. A soil from shale composing of high quartz tended to have pH. extractable Ca, base saturation, and low exchangeable Al. In total element analysis, the soils derived from parent rocks with high contents of (i) orthoclase and micas, (ii) biotite, primary chlorite, and augite, and (iii) carbonate minerals and plagioclase as a rock-forming mineral showed a tendency to decrease the contents of $K_2O$, $Fe_2O_3$ and MgO, and CaO in comparison with those of their parent rocks.

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