• Title/Summary/Keyword: Cation content

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Cation Leaching from Soils Percolated with Simulated Sulfuric Acid Rainn (人工酸性 빗물에 의한 여러 土壤으로부터의 이온 洗脫)

  • Rhyu, Tae-Cheol;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.16 no.2
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    • pp.169-180
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    • 1993
  • Soils of four combinations, sand with high content of organic matter(SL), sand with low content of OM(SS), siltyl loam with high content of OM(LL) and silty loam with low content OM (LS), were filled on column and then percolated with simulated sulfuric acid rain with pH 5.6, 4.0, 3.5, 3.0 and 2.5. From soil leachates, pH and concentrations of basic cations and Al were determined. Cation concentrations in the leachates increased as pH of the rain decreased. The orders of buffering capacity of soil, leachability of cation from soil, leaching sensitivity of ion andbase saturation sensitivity of soil to acidity of the rain water were SS$\leq$K <$\leq$LL

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Antioxidant Enzyme Activities and Soil Properties of Healthy and Declining Abies koreana (Wils.) in Mt. Halla (한라산 구상나무 건전개체와 쇠약개체의 항산화효소활성 및 토양특성)

  • Lim, Jong-Hwan;Woo, Su-Young;Kwon, Mi Jeong;Kim, Young Kul
    • Journal of Korean Society of Forest Science
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    • v.96 no.1
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    • pp.14-20
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    • 2007
  • In order to examine the differences in antioxidant enzyme activities which represent defence mechanism to stressful environments, and soil properties between healthy and declining (or unhealthy) trees, we selected three sites, Witseorum, Youngsil and Sungpanak (Jindallebat). Antioxidant enzymes including Ascorbate peroxidase (APX) and Glutathione Reductase (GR), forest soil properties including soil texture, soil pH, organic matter, total nitrogen, available phosphate, cation exchange capacity, exchangeable cation content and nutrient contents in leaves of Abies koreana (Korean fir) trees were analyzed. There were no significant differences between healthy and declining trees in GR activity. However, seasonal difference in antioxidant enzyme activity was observed. GR activity was lower in June and August than that of September. Soil chemical and physical properties of each site showed a tendency that organic content, total nitrogen content, available phosphorus, cation exchange capacity and cation content were lower at the site of declining trees than the site of healthy trees.

Preparation of Highly Tough Ethylene Vinyl Acetate (EVA) Heterogeneous Cation Exchange Membranes and Their Properties of Desalination

  • Kim, In Sik;Ko, Dae Young;Canlier, Ali;Hwang, Taek Sung
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.361-369
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    • 2018
  • A manufacturing method has been devised to prepare novel heterogeneous cation exchange membranes by mixing ethylene vinyl acetate (EVA) copolymers with a commercial cation exchange resin. Optimum material characteristics, mixture ratios and manufacturing conditions have been worked out for achieving favorable membrane performance. Ion exchange capacity, electrical resistance, water uptake, swelling ratio and tensile strength properties were measured. SEM analysis was used to monitor morphology. Effects of vinyl acetate (VA) content, melt index (MI) and ion exchange resin content on properties of heterogeneous cation exchange membranes have been discussed. An application test was carried out by mounting a selected membrane in a membrane capacitive deionization (MCDI) system to investigate its desalination capability. 0.92 meq/g of ion exchange capacity, $8.7{\Omega}.cm^2$ of electrical resistance, $40kgf/cm^2$ of tensile strength, 19% of swelling ratio, 42% of water uptake, and 56.4% salt removal rate were achieved at best. VA content plays a leading role on the extent of physical properties and performance; however, MI is important for having uniform distribution of resin grains and achieving better ionic conductivity. Overall, manufacturing cost has been suppressed to 5-10% of that of homogeneous ion exchange membranes.

Contribution of Soil Pysico-chemical Properties to Fruit Quality of 'Campbell Early' Grapes in the Vineyards (포도 '캠벨얼리' 품질에 미치는 토양이화학성의 상대적 기여도)

  • Kim, Seung-Heui;Choi, In-Myung;Yun, Seok-Kyu;Cho, Jung-Gun;Lim, Tae-Jun;Yun, Hae-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.3
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    • pp.187-191
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    • 2009
  • 'Campbell Early', a major grape cultivar, occupies more than 70% of cultivated vineyard areas, however, recommendable standard management system of soil environmental conditions has not been developed yet in Korea. The consideration for the correlation between fruit quality and soil condition in the vineyard is required in the efficient management system of soil. This study was carried out to investigate the optimum soil environmental conditions for 'Campbell Early' grape production with high quality. The results from analyses of correlation between them were used to develop soil management guideline for promoting efficiency in grape production. Soil properties were analyzed from 120 vineyards in Hawsung, Sangju, Yeongdong, Gimcheon, Yeongju, and Yeongwol, major grape production regions. Because there is neither coloring disorder nor delayed coloration in grape production of 'Campbell Early', relative contribution of soil hardness and solid phase to fruit quality and fruit weight was analyzed. Among the soil properties, while cation and soil hardness affected sugar content at the level of 39.3% and 36.8%, respectively, saturated hydraulic conductivity, solid phase, and cation exchange capacity (CEC) showed relatively low contribution to sugar content in the vineyard. The sugar content in grapes was influenced more critically by the chemical properties than the physical ones in the soil of vineyards. While soil hardness and solid phase affected grape weight at the level of 27.8% and 26.0%, respectively, phosphate content, organic matter content, and cation showed low contribution to grape weight. Grape guality such as sugar content and grape weight was affected highly by cation and organic matters. Therefore, cation and organic matter content of soil contributed to fruit quality at the level of 33.8% and 15.5%, respectively, in the vineyard.

Study on the of the Correlation between Soil Chemical Properties and Bioactive Compounds of Acer tegmentosum Maxim.

  • Lee, Dong Hwan;Park, Youngki;Hong, Seong Su;Park, Gwang Hun;Kim, Hyun-Jun
    • Korean Journal of Plant Resources
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    • v.34 no.6
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    • pp.566-574
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    • 2021
  • This research was carried out to investigate the correlation between soil chemical properties and bioactive compounds of Acer tegmentosum Maxim. The methods of determining bioactive compounds were determined by high performance liquid chromatography, that contained (-)-gallocatechin (0.04±0.01 ~ 0.43±0.28%), salidroside (0.90±0.06 ~ 3.86±0.59%), tyrosol (0.03±0.00 ~ 0.43±0.00%), (-)-catechin (0.05±0.01 ~ 0.37±0.14%), 6'-O-galloylsalidroside (0.02± 0.01 ~ 0.31±0.06%), (-)-epicatechin-gallate (0.01±0.00 ~ 0.04±0.01%). The soil chemical properties analysis such as soil pH, electric conductivity (EC), organic matter (OM), total nitrogen (TN), available phosphate (Avail. P2O5), exchangeable cation and cation exchange capacity (CEC) were performed following the standard manual. The correlation analysis between soil chemical properties and bioactive compounds of A. tegmentosum, soil pH, available phosphate and exchangeable cation (Ca2+ and Mg2+) were negatively correlated with content of salidroside. On the other hand, soil exchangeable cation (Na+) showed positive correlation with content of salidroside. The results of this study was able to investigate the correlation between soil chemical properties and bioactive compounds of A. tegmentosum.

Contribution Rate on Soil Pysico-Chemical Properties Related to Fruit Quality of 'Kyoho' Grapevines (포도 '거봉' 품질에 미치는 토양이화학성의 상대적 기여도)

  • Kim, Seung-Heui;Choi, In-Myung;Han, Jeom-Wha;Cho, Jung-Gun;Park, Seo-Jun;Lim, Tae-Jun;Yun, Hea-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.782-788
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    • 2010
  • Detail management standard on soil conditions in 'Kyoho' grapes were not yet made. Therefore, this study was carried out to investigate the optimum soil environmental conditions on production of high fruit quality in 'Kyoho' grapes. We established using correlation between fruit quality and soil condition. These results were used to develop soil management guideline with promoting efficiency and minuteness in grape vineyard. Soil conditions were analyzed at total 80 vineyards in major grape producing areas such as Ansung, and Cheonan (40 orchards an area). The soil environmental factors affected fruit weight were soil pH of 36.6%, cultivation layer depth of 23.3%, and cation of 17.8%. The soil condition factors affected sugar content were soil hardness of 24.4%, cation of 24.1% and organic matter content of 22.1%. Cultivation layer depth, soil texture, and phosphate content were low as relative contribution. Coloring was involved with organic matter content, CEC (cation exchange capacity), and saturated hydraulic conductivity. while soil pH, cultivation layer depth, and phosphate content showed low contribution. Finally, relative contribution on fruit quality related with sugar content, fruit weight, and coloring were soil hardness of 28.0%, organic matter content of 25.0%, soil pH of 12.9%.

Study on precipitate formation and the change of cations and anions in domestic bottled water (국내 시판 먹는샘물의 물성에 따른 이온성분의 변화 및 침전물 생성)

  • Lee, Eun-Kyeong;Jang, Seong-Il;Jung, Yeon-Wook;Jeon, Seong-Sook;Ju, Myeong-Hui;Lee, Soon-Ae;Park, Jong-Sook
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.561-569
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    • 2008
  • We analyzed contents of cations and anions for the domestic bottled drinking water. Results showed that total cation content was 45.81 mg/L and contained 40% of Ca. The content of cations were decreased in the order of Ca>Si>Na>Mg>K. Total anion content was 12.20 mg/L and contained 90% of ${SO_4}^{2-}$ and $Cl^-$. $F^-$ and $NO_{3-}N$ were a little contained. While Si content was reduced 2.3~75.7%(mean value:38.5%) after freezing, Ca content was reduced 45.2% after boiling. It showed that water containing higher Ca content was significantly decreased after boiling. Precipitates formed by freezing and boiling is composed of minerals such as Si and Ca. Compared to minerals from food intake, concentrations of minerals from water intake are expected to be less influenced. It is recommended Bottled Water that contains more than 20 mg/L of Ca(exceeding water-quality standard for turbidity) is safe to drink without thawing and boiling.

A Study on the Characteristic and Preparation of PEM for DMFC using EPS, SAN, HIPS (EPS, SAN, HIPS를 이용한 직접 메탄올 연료전지용 고분자 전해질 막의 제조 및 그 특성에 관한 연구)

  • Song, Ju-Yeong;Kim, Hi-Youl;Kim, Jong-Hwa;Lee, Soo
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.45-53
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    • 2006
  • In this study, we prepared porous cation exchange membrane using polystyrene such as, EPS (expanded polystyrene), SAN (styrene acrylonitrile copolymer) and HIPS (high impactive polystyrene). These polystyrenes were sulfonated by acetyl sulfate to make porous cation exchange membrane such as, SEPS, SSAN, SHIPS. SEM was employed to confirm porous structure of membrane, and IR spectroscopy was used to confirm sulfonation rate of ion exchange membrane. Water and methanol content were also increased with amount of sulfuric acid in reactants. SSAN-20 showed the highest value in water and methanol content. Fixed ion concentration and conductivity was also increased with an amount of sulfuric acid in reactants. Methanol permeability for SEPS-20, SSAN-20, SHIPS-20 was found to be $1.326\;{\times}\;10^{-5}\;cm^2/s$, $1.527\;{\times}\;10^{-5}\;cm^2/s$ and $1.096\;{\times}\;10^{-5}\;cm^2/s$ respectively. From the result of electrodialysis experiment in 0.03 M $Pb(NO_3)_2$ aqueous solution, anion exclusion and cation selection effects were confirmed.

The Bio-Softning Finish of Tencel Fabric(II) - Change of Mechanical Properties - (텐셀직물(織物)의 바이오-유연가공(柔軟加工)에 의한 물성변화(物性變化) (II) - 역학적(力學的) 특성(特性)의 변화(變化) -)

  • Song, Wha-Soon;Kim, In-Young;Oh, Soo-Min
    • Journal of Fashion Business
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    • v.5 no.2
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    • pp.67-72
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    • 2001
  • Tencel fabric was treated with cellulase and softener. And then Mechanical properties were investigated. Basic characteristic values of clothing wearing were calculated. With the treatment of cellulase and softener treatment, WT, RT, LC, WC, RC of mechanical characteristics were increased, and G, 2HG, 2HG5, B, 2HB were decreased. B/W, $\sqrt[3]{B/W}$, $\sqrt{2HB/W}$, 2HB/B, W/T of Basic characteristic values of clothing wearing were decreased. WC/W, WC/T were increased, Therefore, drapability, crease resistance, pressing softness, air content were improved. In consideration of mechanical characteristics and basic characteristic values of clothing wearing depending on the softener, values of WT, WC/W, WC/T were bigger with the treatment of epoxy and snow softener than with the treatment of cation and blend softener. LC, WC, RC, B/W, $\sqrt[3]{B/W}$, $\sqrt{2HB/W}$, 2HB/B, W/T were bigger with the treatment of cation and blend softener than with the treatment of epoxy and snow softener. Thereofre, with the treatment of epoxy and snow softener, drapability, crease resistance, air content were improved. With the treatment of cation and blend softener, pressing softness were improved.

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Conductance Study on the Characteristics of Solution Containing Crown Ethers and Univalent Cation Perchlorates

  • Lee, Shim-Sung;Park, Sung-Oh;Jung, Jong-Hwa;Lee, Bu-Yong;Kim, Si-Joong
    • Bulletin of the Korean Chemical Society
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    • v.11 no.4
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    • pp.276-281
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    • 1990
  • The equivalent conductance of univalent cation (potassium, silver, thallium and ammonium) perchlorates in methanol containing 18-membered crown ethers, 18-crown-6 (18C6) and 1,10-dithia-18-crown-6 (DT18C6) were measured at different temperatures. The equivalent conductances of ammonium perchlorate were increased by increasing content of DT18C6 exceptionally, due to more favorable solvations than complexations. From the equivalent conductance changes, the formation constants for 1:1 compmlexes have been determined, and the values of enthalpy and entropy changes have been calculated. The complexations of 18C6 and DT18C6 with the univalent cations under investigation are all exothermic and the ${\Delta}$S values are all negative and no considerable differences around 50 J/ (k mol). The selectivity order of 18C6 is $K^+ > Tl^+ > Ag^+ > NH_4^+$, while that of DT18C6 is $Ag^+ > Tl^+ > NH_4^+ > K^+$. By sulfur substitutions in 18C6 result in significant decrease in stability, but the stability of $Ag^+$-DT18C6 complex are $10^4$ times larger than those of $K^+$. This increase of stabilities for $Ag^+$-DT18C6 complex are primary due to the result of favorable exothermic heat of reaction between the polarizable soft cation and soft sulfur centers. In NMR experiment, the stepwise additions of cation perchlorates into crown ether solutions induced two major spectral changes. First, the resonance all shift down field and the cation induced shifts were linear up to 1:1 cation/crown ratio, above which no further changes were observed. On the basis of these results, it could be concluded that 1:1 complex is formed. Second, the magnitudes of cation induced shifts were different each other in same ligand. By addition of silver ion to the solution of DT18C6, the largest shift of proton peak near the sulfur atom was observed. These effects are also arisen from the results of covalent bonding between "soft-soft" interactions.